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公开(公告)号：CA2604647A1
公开(公告)日：2006-11-09
申请号：CA2604647
申请日：2005-09-09
Applicant: CLOROX CO
Inventor： KAARET THOMAS W , FRITTER DANIELA N , PETRIN MICHAEL J , VAN BUSKIRK GREGORY
Abstract: Disclosed herein is a viscoelastic oxidizing formulation comprising, in aqueous solution: an effective amount of an oxidizing compound; a thickening system which comprises (i) at least one alkali metal soap and (ii) a hydrotrope selected from the group consisting of amine oxides, betaines and mixtures thereof, each in amounts appropriate to create a viscoelastic composition having a Zero-shear viscosity in the range of 140-265 cP; a Stre ss ~ value greater than 10 Pa and a Relaxation constant greater than 0.05 secon d; and a buffer/electrolyte in an amount effective to stabilize the oxidizing compound. The oxidizing formulations may further be formulated to have an oxidant stable opacifier or colorant.
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公开(公告)号：HU9800642A2
公开(公告)日：1998-07-28
申请号：HU9800642
申请日：1996-06-03
Applicant: CLOROX CO
Inventor： ARBOGAST JAMES W , DELINE JAMES E , FOLAND LAFAYETTE , KAARET THOMAS W , KLOTTER KEVIN A , PETRIN MICHAEL J , SMITH WILLIAM L , ZIELSKE ALRED G
IPC: C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C07D295/14 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C11D1/58 , C11D1/62
Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.
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公开(公告)号：ZA9710682B
公开(公告)日：1998-07-17
申请号：ZA9710682
申请日：1997-11-27
Applicant: CLOROX CO
Inventor： ALVAREZ VINCENT E , DELINE JAMES E , FOLAND LAFAYETTE D , KAARET THOMAS W , PETRIN MICHAEL J , SMITH WILLIAM L , SUDBURY BARRY A , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C11D , C07D
Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
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公开(公告)号：AU5686998A
公开(公告)日：1998-06-22
申请号：AU5686998
申请日：1997-11-18
Applicant: CLOROX CO
Inventor： ALVAREZ VICENT E , ARBOGAST JAMES W , DELINE JAMES E , FOLAND LAFAYETTE D , KAARET THOMAS W , KLOTTER KEVIN A , PETRIN MICHAEL J , SMITH WILLIAM L , ZIELSKE ALFRED G , MITCHELL JAMES D
IPC: C07D295/14 , C01B13/02 , C07D295/02 , C07D295/15 , C11D1/62 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/00 , D06L3/02 , H04B7/06 , C01B3/00 , C11D7/38 , C07D265/12 , C07D211/26 , C07D211/34
Abstract: Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butyl morpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is contacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.
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公开(公告)号：CA2273093A1
公开(公告)日：1998-06-04
申请号：CA2273093
申请日：1997-11-18
Inventor： CASELLA VICTOR M , CHOY CLEMENT K , PERKINS SARAH A , SMITH WILLIAM L , KLOTTER KEVIN A , PETERSON DAVID , BROCKEL ULRICH , ZIELSKE ALFRED G , PETRIN MICHAEL J , PHILLIPPI MARTIN A , FOLAND LAFAYETTE D , HUESTIS SUSAN P , SCHONHERR MICHAEL , DELINE JAMES E , KAARET THOMAS W , SEELMANN-EGGEBERT HANS PETER , SIBERT WILLIAM P
IPC: C07D295/14 , C07D295/15 , C11D3/12 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/06 , D06L3/02 , H04B7/06 , C01B3/00 , B29C59/00 , B29C67/00 , C07D265/12 , C07D295/12 , C07D211/26 , C07D295/26 , C07D211/34 , C11D7/38 , D04H1/64
Abstract: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of formula (I), wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, aluminum silicate, or mixtures thereof.
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Patent Agency Ranking
公开(公告)号：CZ9700622A3
公开(公告)日：1997-07-16
申请号：CZ62297
申请日：1996-06-03
Applicant: CLOROX CO
Inventor： ARBOGAST JAMES W , DELINE JAMES E , FOLAND LAFAYETTE , KAARET THOMAS W , KLOTTER KEVIN A , PETRIN MICHAEL J , SMITH WILLIAM L , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C11D1/58 , C11D1/62
CPC classification number: C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L4/12 , D06L4/17 , H04B7/0619
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公开(公告)号：TR9600485A2
公开(公告)日：1996-12-21
申请号：TR9600485
申请日：1996-06-07
Applicant: CLOROX CO
Inventor： ARBOGAST JAMES W , DELINE JAMES E , FOLAND LAFAYETTE , KAARET THOMAS W , KLOTTER KEVIN A , PETRIN MICHAEL J , SMITH WILLIAM L , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06
CPC classification number: C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L4/12 , D06L4/17 , H04B7/0619
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公开(公告)号：MX2007013453A
公开(公告)日：2008-01-21
申请号：MX2007013453
申请日：2005-09-09
Applicant: CLOROX CO
Inventor： KAARET THOMAS W , FRITTER DANIELA N , BRUSKIRK GREGORY VAN , PETRIN MICHAEL J
Abstract: Se describe en la presente una formulacion viscoelastica oxidante que comprende, en una solucion acuosa: una cantidad efectiva de un compuestos oxidante; un sistema espesante que comprende (i) al menos un jabon de metal alcalino y (ii) un hidrotropo seleccionado del grupo que consiste de oxido de aminas, betainas y mezclas de los mismos, cada uno en cantidades apropiadas para crear una composicion viscoelastica que tiene una viscosidad de cizallamiento Cero en el intervalo de 140-265 cP; un valor de Esfuerzo 1/2 mayor que 10 Pa y una constante de Relajacion mayor que 0.05 segundos; y un amortiguador/electrolito en una cantidad efectiva para estabilizar el compuesto oxidante; las formulaciones oxidantes pueden formularse ademas para tener un opacificante o colorante estable al oxidante.
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公开(公告)号：CO5021162A1
公开(公告)日：2001-03-27
申请号：CO97025082
申请日：1997-05-09
Applicant: CLOROX CO
Inventor： KAARET THOMAS W , SMITH WILLIAM L
Abstract: Una composición acuosa de blanqueo de hipoclorito, adecuadapara el uso en licores de lavado que contienen por lo menos uno de cationes de hierro o manganeso consistiendo dicha posición esencialmente en un compuesto de hipoclorito y una cantidad efectiva de un secuestrante de policarboxilato que atenúa el ataque de dichos cationes en los géneros. Un licor de lavado que contiene (i) por lo menos 40 ppb de cationes de hierro, ó (ii) por lo menos 10 ppb de cationes de manganeso, ó (iii) los cationes de ambos (i) y (ii), y comprendiendo además dicho licor de lavado: a) un trozo de género que tiene tendencia a ser atacado por dichos cationes en dicho licor de lavado, y b) una composición de hipoclorito que incluye una cantidad efectiva de un secuestrante de policarboxilato para atenuar el ataque de dichos cationes en dicho trozo de género.
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公开(公告)号：ES2110373B1
公开(公告)日：1999-05-16
申请号：ES9602346
申请日：1996-11-07
Applicant: CLOROX CO
Inventor： KAARET THOMAS W , SMITH WILLIAM L
Abstract: Sequestering agents for use as a whitening and fabric strength enhancer for aqueous hypochlorite bleach compositions are provided. It was found that the sequesterants when used with hypochlorite in the presence of soluble heavy metal ions, particularly iron and manganese ions, provide significantly improved whitening and fabric protection. Most preferably, the sequesterants are selected from polyacrylic acid, a polyacrylic acid derivative, a copolymer of acrylic acid or methacrylic acid and a comonomer which is maleic acid or maleic anhydride and mixtures thereof. In one aspect, the sequesterants are employed in a method for laundering fabrics comprising: a) providing, in a wash liquor containing (i) at least about 40 ppb of iron cations or (ii) at least about 10 ppb of manganese cations, or (iii) the cations of both (i) and (ii), and a fabric piece; and b) adding either prior to, contemporaneously with, or after, the step of providing of said fabric piece to said wash liquor a hypochlorite composition which comprises one or more of said sequesterants. Preferably the sequesterant comprises at least 0.1 ppm by weight of said wash liquor and the hypochlorite composition is an alkali metal hypochlorite and said sequesterant has a molecular weight of between about 500 and 500,000 daltons.
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