公开(公告)号：AU2613399A

公开(公告)日：1999-07-12

申请号：AU2613399

申请日：1998-12-18

Applicant: BASF AG

Inventor： BRUNNER MELANIE ,  BOTTCHER ARND ,  BREITSCHEIDEL BORIS ,  HALBRITTER KLAUS ,  HENKELMANN JOCHEM ,  THIL LUCIEN ,  PINKOS ROLF

IPC: B01J23/46 ,  C07B61/00 ,  C07C51/36 ,  C07C61/08 ,  C07C61/09 ,  C07C67/303 ,  C07C69/75 ,  C08K5/12

Abstract: The hydrogenation of esters of benzene-dicarboxylic acids is carried out on supported catalysts containing a Sub-Group VIIII metal on a macroporous support. A process for the hydrogenation of benzene-dicarboxylic acid ester(s) with hydrogen in presence of a supported catalyst containing Sub-Group VIII metal(s) on a macroporous support. If the ester is dimethyl terephthalate, this excludes hydrogenation on a catalyst containing ruthenium, with or without Sub-Group I, VII or VIII metal(s), on a support with an average pore diameter (APD) of at least 50 nm and a BET surface of not more than 30 m /g, with an active metal content of 0.01-30 wt.% and a ratio of (active metal surface):(support surface) of less than 0.05, and/or on a catalyst containing 0.01-30 wt.% active metal(s) as above on a support in which 10-50 vol.% of the pores consist of macropores with a diameter of 50-10,000 nm and 50-90 vol.% consist of mesopores with a diameter of 2-50 nm.

公开(公告)号：CA2297724A1

公开(公告)日：1999-05-27

申请号：CA2297724

申请日：1998-10-16

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF HARTMUTH ,  STEIN FRANK

IPC: C07B61/00 ,  C07C29/149 ,  C07C29/80 ,  C07C31/20 ,  C07C51/367 ,  C07C62/02 ,  C07C67/31 ,  C07C69/675

Abstract: The invention relates to a method for producing 1,6-hexanediol and 6hydroxycaproic acid or their esters by the catalytic hydrogenation of adipic acid, adipic acid monoesters or adipic acid diesters or educt flows containing adipic acid or its esters as essential constituents. The bottom product obtained when the hydrogenation discharge is distilled after the hexanediol and the hydroxycaproic acid or its esters have been separated off is reintroduced into the hydrogenation process, said bottom product essentially containing oligomeric esters of the 6-hydroxycaproic acid. The resulting mixture of the educt and the return flow is reacted at temperatures of 100 to 300 ~C and at pressures of 10 to 300 bar in the liquid phase and with a molar ratio of carboxyl groups to be hydrogenated to hydrogen in the reactor of 1:5 to 1:100, on hydrogenating catalysts.

公开(公告)号：DE59407851D1

公开(公告)日：1999-04-01

申请号：DE59407851

申请日：1994-11-09

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF

IPC: C07D307/33 ,  B01J23/36 ,  B01J23/656 ,  B01J23/72 ,  B01J23/86 ,  C07B61/00 ,  C07D307/32 ,  C07D315/00

Abstract: PCT No. PCT/EP94/03683 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 9, 1994 PCT Pub. No. WO95/14010 PCT Pub. Date May 26, 1995A process for the preparation of gamma -butyrolactone, in which 2,5-dihydrofuran or 2,3-dihydrofuran or a mixture of these two dihydrofurans is caused to react in the gas phase in the presence of water and in the presence or absence of additional hydrogen at elevated temperature over a hydrogenating catalyst.

公开(公告)号：BR9612108A

公开(公告)日：1999-02-23

申请号：BR9612108

申请日：1996-11-18

Applicant: BASF AG

Inventor： KAIBEL GERD ,  PINKOS ROLF ,  BROCKER FRANZ JOSEF ,  FISCHER ROLF

IPC: B01J37/02 ,  C07D307/08 ,  C23C14/16

Abstract: PCT No. PCT/EP96/05071 Sec. 371 Date May 22, 1998 Sec. 102(e) Date May 22, 1998 PCT Filed Nov. 18, 1996 PCT Pub. No. WO97/19939 PCT Pub. Date Jun. 5, 1997In a process for the catalytic hydrogenation of 2,5- and 2,3-dihydrofuran with hydrogen to give tetrahydrofuran, use is made of a catalyst in which a metal or a plurality of metals have been deposited by vapor deposition or sputtering on a metal wire mesh or a metal foil as support.

公开(公告)号：ES2122538T3

公开(公告)日：1998-12-16

申请号：ES95906933

申请日：1995-01-12

Applicant: BASF AG

Inventor： KANAND JURGEN ,  ROEPER MICHAEL ,  PINKOS ROLF ,  PACIELLO ROCCO ,  THOME ALFRED

IPC: B01J21/16 ,  B01J27/18 ,  B01J29/06 ,  C07B61/00 ,  C07C27/00 ,  C07C29/17 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C43/15 ,  C07C45/51 ,  C07C47/02

Abstract: PCT No. PCT/EP94/00114 Sec. 371 Date Jul. 12, 1996 Sec. 102(e) Date Jul. 12, 1996 PCT Filed Jan. 12, 1995 PCT Pub. No. WO95/19334 PCT Pub. Date Jul. 20, 1995A process for the preparation of n-butyraldehyde and/or n-butanol, wherein a) 1,3-butadiene is caused to react with an alcohol of the formula IROHI, to form a mixture of adducts of the formulas II II and III III b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst to form the enol ether of the formula IV IV and d) n-butyraldehyde and/or n-butanol is/are produced from this ether IV by the reaction thereof with hydrogen and water or water only in the presence of a homogeneous or heterogeneous catalyst.

公开(公告)号：FI960429A0

公开(公告)日：1996-01-30

申请号：FI960429

申请日：1996-01-30

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF HARTHMUTH ,  BREITSCHEIDEL BORIS ,  POLANEK PETER

IPC: B01J23/36 ,  B01J23/46 ,  B01J23/72 ,  B01J23/889 ,  B01J31/22 ,  C07B61/00 ,  C07C29/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/17 ,  C07C31/20 ,  C07D307/20 ,  C07D307/28 ,  C07C

Abstract: In the proposed process for producing 1,4 butane diol, 2,5 dihydrofurane is reacted in a single step in the presence of water and hydrogen at a temperature of 20 to 300 DEG C and a pressure of 1 to 300 bar with the aid of a hydrogenating catalyst.

公开(公告)号：AU2793095A

公开(公告)日：1996-01-19

申请号：AU2793095

申请日：1995-06-16

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF ,  BREITSCHEIDEL BORIS ,  POLANEK PETER

IPC: B01J23/36 ,  B01J23/46 ,  B01J23/72 ,  C07B61/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/14 ,  C07C29/141 ,  C07C31/20 ,  C07C45/59 ,  C07C47/19 ,  C07D307/20

Abstract: PCT No. PCT/EP95/02335 Sec. 371 Date Dec. 27, 1996 Sec. 102(e) Date Dec. 27, 1996 PCT Filed Jun. 16, 1995 PCT Pub. No. WO96/00203 PCT Pub. Date Jan. 4, 1996Described is a method of producing 1,4-butanediol, the method calling for 2,3-dihydrofuran to be decomposed in a single stage over a hydrogenation catalyst in the presence of water and hydrogen at a temperature of 20 to 300 DEG C. and a pressure of 1 to 300 bar and in neutral or acid conditions.

公开(公告)号：AU8141294A

公开(公告)日：1995-06-06

申请号：AU8141294

申请日：1994-11-09

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF

IPC: C07D307/33 ,  B01J23/36 ,  B01J23/656 ,  B01J23/72 ,  B01J23/86 ,  C07B61/00 ,  C07D307/32 ,  C07D315/00

Abstract: PCT No. PCT/EP94/03683 Sec. 371 Date May 16, 1996 Sec. 102(e) Date May 16, 1996 PCT Filed Nov. 9, 1994 PCT Pub. No. WO95/14010 PCT Pub. Date May 26, 1995A process for the preparation of gamma -butyrolactone, in which 2,5-dihydrofuran or 2,3-dihydrofuran or a mixture of these two dihydrofurans is caused to react in the gas phase in the presence of water and in the presence or absence of additional hydrogen at elevated temperature over a hydrogenating catalyst.

公开(公告)号：AU7384794A

公开(公告)日：1995-02-28

申请号：AU7384794

申请日：1994-07-07

Applicant: BASF AG

Inventor： PINKOS ROLF ,  FISCHER ROLF HARTHMUTH ,  BREITSCHEIDEL BORIS ,  POLANEK PETER

IPC: B01J23/36 ,  B01J23/46 ,  B01J23/72 ,  B01J23/889 ,  B01J31/22 ,  C07B61/00 ,  C07C29/00 ,  C07C29/10 ,  C07C29/132 ,  C07C29/17 ,  C07C31/20 ,  C07D307/20 ,  C07D307/28

Abstract: In the proposed process for producing 1,4 butane diol, 2,5 dihydrofurane is reacted in a single step in the presence of water and hydrogen at a temperature of 20 to 300 DEG C and a pressure of 1 to 300 bar with the aid of a hydrogenating catalyst.

公开(公告)号：NZ564408A

公开(公告)日：2009-12-24

申请号：NZ56440806

申请日：2006-06-26

Applicant: BASF AG

Inventor： TEBBEN GERD-DIETER ,  SCHELLING HEINER ,  STROFER ECKHARD ,  PINKOS ROLF ,  HAUNERT ANDREA ,  EIERMANN MATTHIAS ,  KARL JORN

IPC: C10L1/02 ,  C10L1/14 ,  C10L1/185 ,  C10L1/198 ,  C10L10/02 ,  C10L10/12

Abstract: Disclosed is a biodiesel fuel mixture having a cetane number of> 40, comprising a) from 5 to 90% by weight of biodiesel, b) from 0 to 94% by weight of diesel oil of fossil origin, c) from 1 to 20% by weight of a polyoxyalkylene dialkyl ether of the formula RO(CH2O)nR, in which R is an alkyl group having from 1 to 10 carbon atoms and n is from 2 to 10, and d) from 0 to 5% by weight of further additives. Also disclosed is the use of polyoxymethylene dialkyl ethers as defined above as an additive in biodiesel fuel mixtures with at least 1% by weight of biodiesel for increasing the cetane number.