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公开(公告)号:WO2012052386A1
公开(公告)日:2012-04-26
申请号:PCT/EP2011/068077
申请日:2011-10-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , PATER, Joachim, T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , Morini, Giampiero , VITALE, Gianni
Inventor: PATER, Joachim, T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , Morini, Giampiero , VITALE, Gianni
CPC classification number: C08F10/06 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/12 , C08F2/34
Abstract: A process for the (co)polymerization of propylene carried out at a temperature ranging from 77 to 95°C in the presence of a catalyst comprising the product obtained by reacting: -an organo-aluminium compound, with -a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters.
Abstract translation: 在丙烯存在下,在77至95℃的温度下进行丙烯(共)聚合的方法,所述催化剂包含通过以下方法获得的产物: - 有机铝化合物与包含Mg的固体催化剂组分 ,Ti和选自特定二极体的电子给体化合物。
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公开(公告)号:WO2012017038A1
公开(公告)日:2012-02-09
申请号:PCT/EP2011/063447
申请日:2011-08-04
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Jochem T. M.
Inventor: MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Jochem T. M.
CPC classification number: C08F10/06 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of Formula (I) in which R, R 1 and R 4 groups, equal to or different from each other, are C 1 -C 15 hydrocarbon groups and the R groups can be linked to form a cycle, R 2 -R 3 groups, equal to or different from each other, are selected from hydrogen and C 1 -C 15 hydrocarbon groups, the R 1 -R 4 groups can optionally contain an heteroatom selected from halogen, P, S, N,O and Si, n is an integer from 0 to 5 and said electron donor and Ti atoms being present in an amount such that their molar ratio is equal to, or lower than, 0.65.
Abstract translation: 包含Mg,Ti和其中R,R 1和R 4基团彼此相同或不同的R,R 1和R 4基团的式(I)的电子给体的烯烃聚合用催化剂组分是C1-C15烃基,R基团可以连接 为了形成一个循环,相同或不同的R2-R3基团选自氢和C1-C15烃基,R1-R4基团可任选地含有选自卤素,P,S,N,O的杂原子 和Si,n为0至5的整数,并且所述电子给体和Ti原子的存在量使得它们的摩尔比等于或低于0.65。
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公开(公告)号:WO2021052737A1
公开(公告)日:2021-03-25
申请号:PCT/EP2020/074185
申请日:2020-08-31
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PIEMONTESI, Fabrizio , MIGNOGNA, Alessandro , LIGUORI, Dario , MORINI, Giampiero , VITALE, Gianni
Abstract: A polypropylene composition comprising (percentages being referred to the total A+B): A) from 60 to 90wt%, of a fraction insoluble in xylene at 25 °C, comprising more than 90 %wt of propylene units, and B) from 10 to 40wt%; of a fraction soluble in xylene at 25 °C comprising a copolymer of propylene and ethylene containing an average content of ethylene derived units from 30.0 wt% to 50.0wt%, said fraction being characterized by the fact that when subjected to GPC fractionation and continuous IR analysis for determining the ethylene content of the eluted fractions (GPC-IR analysis), it shows that the content of ethylene increases along with the Mw for fractions having Mw higher than the average.
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公开(公告)号:WO2020120227A1
公开(公告)日:2020-06-18
申请号:PCT/EP2019/083487
申请日:2019-12-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , LIGUORI, Dario , MORINI, Giampiero , VITALE, Gianni
IPC: C08F110/06 , C08F4/651
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from specific diphenol derivatives.
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公开(公告)号:WO2018091375A1
公开(公告)日:2018-05-24
申请号:PCT/EP2017/078934
申请日:2017-11-10
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , LIGUORI, Dario , MORINI, Giampiero
IPC: C08F110/06 , C08F4/651 , C08F4/654
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where the R 1 and R 7 groups, equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups, R 2 group is selected from C 1 -C 10 hydrocarbon groups, R 3 to R 6 groups, independently, are selected from hydrogen or C 1 -C 15 hydrocarbon groups which can be fused together to form one or more cycles. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.
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公开(公告)号:WO2016184884A1
公开(公告)日:2016-11-24
申请号:PCT/EP2016/061078
申请日:2016-05-18
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , KASHULIN, Igor , MORINI, Giampiero , NIFANT'EV, Ilya
CPC classification number: C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15
Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where independently, Z is a bridging group, the R 2 groups, equal to or different from each other, are hydrogen or a C 1 -C 20 hydrocarbon radicals, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, R 1 and R 4 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; and R 3 group, is hydrogen or R 4 groups. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.
Abstract translation: 一种用于烯烃聚合的固体催化剂组分,其包含Mg,Ti和式(I)的电子给体,其中独立地Z为桥连基,R2基彼此相同或不同,为氢或C1- C20烃基,m是满足Z的化合价的数,n是1至10的整数,R 1和R 4选自C 1 -C 15烃基,任选地含有选自卤素,P,S,N, O; 和R 3基团,是氢或R 4基团。 基于固体催化剂组分的催化剂体系具有高活性和立体定向性。
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公开(公告)号:WO2014111381A1
公开(公告)日:2014-07-24
申请号:PCT/EP2014/050606
申请日:2014-01-14
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: VITALE, Gianni , ESPOSITO, Simona , GUIDOTTI, Simona , MIGNOGNA, Alessandro , MORINI, Giampiero , PIEMONTESI, Fabrizio
IPC: C08F110/08 , C08F4/651 , C08F10/08
CPC classification number: C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6555 , C08F4/6565 , C08F4/6567 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/17
Abstract: A liquid phase process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups, equal to or different from each other, are C 1 -C 10 hydrocarbon groups; (b) an aluminium alkyl cocatalyst and (c) an external electron donor.
Abstract translation: 在催化剂存在下进行丁烯-1聚合的液相方法,包括(a)包含Mg,Ti的固体催化剂组分和下式(I)的电子给体化合物,其中R基团相等 彼此是或不同的是C 1 -C 10烃基; (b)烷基铝助催化剂和(c)外电子给体。
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公开(公告)号:WO2013174759A1
公开(公告)日:2013-11-28
申请号:PCT/EP2013/060289
申请日:2013-05-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MIGNOGNA, Alessandro , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Joachim T. M.
CPC classification number: C08F10/06 , C08F10/00 , C08F4/6543 , C08F4/651 , C08F110/06 , C08F2500/12
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I), in which R2-R8 groups, equal or different to each other, are selected from hydrogen, halogen and C1 -C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N, and Si and R9 groups are selected from C1 -C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, O, P, S, N, and Si.
Abstract translation: 包含Mg,Ti和下式(I)的电子给体化合物的烯烃聚合用催化剂组分,其中相互相同或不同的R 2 -R 8基团选自氢,卤素和C 1 -C 15烃基 任选地含有选自卤素,O,P,S,N和Si的杂原子,R 9基团选自任选含有选自卤素,O,P,S,N和Si的杂原子的C 1 -C 15烃基。
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公开(公告)号:WO2013092205A1
公开(公告)日:2013-06-27
申请号:PCT/EP2012/074394
申请日:2012-12-05
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GUIDOTTI, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , MORINI, Giampiero
IPC: C08F4/649 , C08F110/06 , C08F4/651
CPC classification number: C08F4/16 , C08F110/06 , C08F4/6494 , C08F2500/04 , C08F2500/12 , C08F4/651
Abstract: A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from phenylene aromatic diesters of a specific formula (b) an alkylaluminum cocatalystand (c) an ester of formula R'OOC-(CR" 2 ) m -COOR' in which m is an integer from 2 to 7, the R' groups, equal to or different from each other, are C 1 -C 10 alkyl groups and the R" groups, independently, are hydrogen or C 1 -C 15 hydrocarbon groups.
Abstract translation: 一种催化剂体系,其包括通过使(a)含有Mg,Ti,卤素和至少一种选自特定式(b)的亚苯基芳族二酯和至少一种电子给体化合物的固体催化剂组分(b)烷基铝助催化剂和(c) 式R'OOC-(CR“2)m-COOR',其中m为2至7的整数,R'基彼此相同或不同,为C 1 -C 10烷基,R”基, 独立地是氢或C 1 -C 15烃基。
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公开(公告)号:WO2012139897A1
公开(公告)日:2012-10-18
申请号:PCT/EP2012/055593
申请日:2012-03-29
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
Inventor: GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
CPC classification number: C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
Abstract: A porous solidcatalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor tothe succinate donor is higher than, or equal to, 0.60.
Abstract translation: 一种多孔固体催化剂组分,其包含卤化镁,至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物,其中一种选自1,3-二醚,另一种选自琥珀酸盐,其特征在于: ID / Ti的摩尔比为0.30〜0.90,其中ID是琥珀酸盐和1,3-二醚的总摩尔量,1,3-二醚供体与琥珀酸盐供体的摩尔比高于或等于 ,0.60。
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