公开(公告)号：DE19839338A1

公开(公告)日：2000-03-02

申请号：DE19839338

申请日：1998-08-28

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  OHLBACH FRANK ,  ANSMANN ANDREAS ,  BASLER PETER ,  FISCHER ROLF ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  REHFINGER ALWIN ,  VOIT GUIDO ,  ACHHAMMER GUENTHER

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for simultaneous preparation of 6-aminocapronitrile and hexamethylene diamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the eight subgroup as catalytically active component to obtain a mixture containing 6-aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers; b) separating by distillation hexamethylene diamine from the mixture containing 6-aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers and c1) separating by distillation 6-aminocapronitrile and subsequently d1) separating by distillation adipodinitrile or c2) simultaneously separating by distillation 6-aminocapronitrile and adipodinitrile into separate fractions. The method is characterized in that the temperature of the bottom in steps d1) or c2) is below 185 DEG C.

公开(公告)号：DE19835907A1

公开(公告)日：2000-02-17

申请号：DE19835907

申请日：1998-08-07

Applicant: BASF AG

Inventor： BASLER PETER ,  HARDER WOLFGANG ,  RESCH PETER ,  RIEBER NORBERT ,  RUPPEL WILHELM ,  TELES JOAQUIM HENRIQUE ,  WALCH ANDREAS ,  WENZEL ANNE ,  ZEHNER PETER

IPC: C07D301/19 ,  B01J20060101 ,  B01J8/04 ,  C07B20060101 ,  C07B33/00 ,  C07B41/00 ,  C07B61/00 ,  C07D20060101 ,  C07D301/03 ,  C07D301/12 ,  C07D303/04

Abstract: The invention relates to a method for reacting an organic compound with a hydroperoxide, comprising at least the following steps (i) to (iii): (i) reacting the hydroperoxide with the organic compound to obtain a mixture composed of a reacted organic compound and a non-reacted hydroperoxide; (ii) separating the non-reacted hydroperoxide from the mixture resulting in step (i); (iii) reacting the hydroperoxide separated in step (ii) with the organic compound.

公开(公告)号：DE10328715A1

公开(公告)日：2005-01-13

申请号：DE10328715

申请日：2003-06-25

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  VOS HARTWIG ,  BASLER PETER ,  ROEPER MICHAEL

IPC: C07C51/353 ,  C07C51/36 ,  C07C51/47 ,  C07C67/303 ,  C07C67/347 ,  C07C67/56 ,  C07B41/00 ,  C07B41/08 ,  C07B41/12 ,  C07B43/06 ,  C07B43/08 ,  C07F15/00 ,  B01J31/12 ,  B01D61/00 ,  B01D3/00 ,  C07B35/02 ,  B01D71/02 ,  B01D71/06

Abstract: A process for continuously preparing a compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group and carboxamide group.

公开(公告)号：DE10320634A1

公开(公告)日：2004-11-18

申请号：DE10320634

申请日：2003-05-08

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  BASLER PETER ,  TELES JOAQUIM HENRIQUE ,  RIEBER NORBERT

IPC: B01J8/04 ,  B01J8/20 ,  B01J19/24 ,  B01J29/40 ,  B01J29/70 ,  B01J29/89 ,  B01J35/00 ,  C07D301/12 ,  C07D301/19 ,  C07B33/00 ,  C07C27/22

Abstract: Process for the catalyzed reaction of an organic compound with a hydroperoxide in at least one reactor using at least two different zeolite catalysts, wherein at least two of the different zeolite catalysts are used physically separately from one another.

公开(公告)号：DE10233387A1

公开(公告)日：2004-02-12

申请号：DE10233387

申请日：2002-07-23

Applicant: BASF AG

Inventor： BASLER PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  RUDOLF PETER

IPC: B01D3/14 ,  B01D3/42 ,  C07D301/32

Abstract: The invention relates to a continuously operated process for the purification by distillation of the oxirane formed in the oxirane synthesis by reaction of a hydroperoxide with an organic compound, wherein the crude oxirane is separated in a dividing wall column into low-, intermediate- and high-boiling fractions and the oxirane is taken off as intermediate boiler at the side offtake in a concentration of at least 99.9%.

公开(公告)号：DE10233383A1

公开(公告)日：2004-02-12

申请号：DE10233383

申请日：2002-07-23

Applicant: BASF AG

Inventor： BASLER PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  RUDOLF PETER

IPC: C07D301/12 ,  C07D301/32

Abstract: Continuously operated process for the intermediate isolation of the oxirane formed by reaction of a hydroperoxide with an organic compound in the oxirane synthesis, wherein the product mixture formed in the synthesis is fractionated in a dividing wall column to give a low-boiling fraction, an intermediate-boiling fraction and a high-boiling fraction and the oxirane is taken off in the intermediate-boiling fraction at the side offtake and the hydroperoxide is taken off in the high-boiling fraction at the bottom of the column.

公开(公告)号：DE10233381A1

公开(公告)日：2004-01-29

申请号：DE10233381

申请日：2002-07-23

Applicant: BASF AG

Inventor： BASLER PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  RUDOLF PETER

IPC: B01D3/14 ,  B01D3/42 ,  C07D301/32

Abstract: Process for the continuously operated distillation of the solvent used in the synthesis of an oxirane by reaction of a hydroperoxide with an organic compound, wherein the mixture comprising the solvent which is obtained in the synthesis and subsequent work-up is separated in a dividing wall column into a low-boiling fraction, an intermediate-boiling fraction and a high-boiling fraction and the solvent is taken off as intermediate-boiling fraction from the side offtake of the column.

公开(公告)号：DE10151558A1

公开(公告)日：2003-04-30

申请号：DE10151558

申请日：2001-10-23

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J37/18 ,  B01J23/745 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C01G49/02

Abstract: The oxidic material suitable for use as a hydrogenation catalyst contains a) bivalent and trivalent iron, the atomic ratio of bivalent iron to trivalent iron ranging from more than 0.5 to 5.5, and b) oxygen as a counter ion to the bivalent and trivalent iron.

公开(公告)号：DE10049265A1

公开(公告)日：2002-04-11

申请号：DE10049265

申请日：2000-09-28

Applicant: BASF AG

Inventor： JUNGKAMP TIM ,  KUNSMANN-KEITEL DAGMAR PASCAL ,  BAUMANN ROBERT ,  BASLER PETER ,  SIEGEL WOLFGANG

IPC: C07C253/34 ,  C07C255/07 ,  C07C253/32

Abstract: The invention relates to a method for separating pentenenitrile isomers having a relative volatility alpha in the region 1.0 - 1.3 in a pressure range of 1 - 500 kPa by means of separation. According to said method, the distillation is carried out in the presence of a liquid diluent which forms azeotropes with the pentenenitrile isomers in the same pressure conditions, whose relative volatility alpha is higher than the pentenenitrile isomers which are to be separated.

公开(公告)号：DE10047703A1

公开(公告)日：2002-04-11

申请号：DE10047703

申请日：2000-09-25

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  FISCHER ROLF ,  MELDER JOHANN-PETER ,  BASLER PETER

IPC: B01J23/86 ,  B01J23/94 ,  B01J38/52 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  B01J38/50 ,  C07C253/30 ,  C07C255/24

Abstract: A process is provided for the regeneration of a heterogeneous catalyst used for the preparation of compounds containing NH 2 groups by the hydrogenation, with hydrogen, of compounds containing at least one unsaturated carbon-nitrogen bond, wherein a) the feed of the compound to be hydrogenated is stopped and b) the heterogeneous catalyst is treated with a compound of the formula R 1 R 2 N-CO-R 3 (I), in which R 1 is hydrogen or C 1 -C 4 alkyl and R 2 , R 3 independently of one another are each hydrogen or C 1 -C 4 alkyl or together are a C 3 -C 6 alkylene group, or mixtures of such compounds, at a pressure ranging from 0.1 to 30 MPa and a temperature ranging from 100 to 300° C., with the proviso that the compound of formula (I) is in liquid form during the treatment.