公开(公告)号：DE502004004653D1

公开(公告)日：2007-09-27

申请号：DE502004004653

申请日：2004-05-06

Applicant: BASF AG

Inventor： WINTERLING HELMUT ,  DEMETER JUERGEN ,  DEININGER JUERGEN ,  KORY GAD ,  SOETJE OLIVER ,  WILMS AXEL ,  WEISS ROBERT ,  KREMPEL KURT ,  BENISCH CHRISTOPH

IPC: C08G69/02 ,  C08G69/08 ,  C08G69/14 ,  C08G69/26

Abstract: Polyamide, whose main chain contains a chemically bound amine selected from the group consisting of 2-methyl-1,5-diaminopentane and 1-amino-2-R-cyclopent-1-ene, where R is a functional group capable of combining with an amino group to form an amide group, and processes for preparing such a polyamide and fibers, films and moldings comprising such a polyamide.

公开(公告)号：DE50304141D1

公开(公告)日：2006-08-17

申请号：DE50304141

申请日：2003-04-08

Applicant: BASF AG

Inventor： WINTERLING HELMUT ,  BENISCH CHRISTOPH ,  HAHN THILO

IPC: C08G69/00 ,  C08G69/04 ,  C08G69/08 ,  C08G69/16 ,  C08G69/20

Abstract: A process for preparing a polyamide by reacting a mixture which comprises a monomer which has a nitrile group and has at least one other functional group capable of forming a carboxamide group, and comprises water, in the presence of titanium dioxide as catalyst, which comprises using titanium dioxide whose BET surface area, determined to the German standard DIN 66 131 volumetrically by the multipoint method, is in the range from 5 to 35 m2/g.

公开(公告)号：BR0311251A

公开(公告)日：2005-03-15

申请号：BR0311251

申请日：2003-05-21

Applicant: BASF AG

Inventor： MAIXNER STEFAN ,  BENISCH CHRISTOPH ,  LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  ANSMANN ANDREAS

IPC: C07C209/84 ,  C07C211/09 ,  C07C211/12 ,  C07C253/34 ,  C07C255/09 ,  C07C255/24

Abstract: A process for reducing the level of an aliphatic monounsaturated amine (IV) in a mixture (V) containing an aminonitrile (I) or a diamine (II) or a dinitrile (III) or mixtures thereof as well as said mine (IV) by a) reacting said mixture (V) with an anionic nucleophile (VI) which contains a nucleophilic atom selected from the group consisting of oxygen, nitrogen and sulfur, which is capable of taking up an H + ion to form an acid having a pK a value in the range from 7 to 11, as measured in water at 25° C., and which has a relative nucleophilicity, as measured in methyl perchlorate/methanol at 25° C., in the range from 3.4 to 4.7 when said nucleophilic atom is oxygen, in the range from 4.5 to 5.8 when said nucleophilic atom is nitrogen, and in the range from 5.5 to 6.8 when said nucleophilic atom is sulfur, in an amount in the range from 0.01 to 10 mol per mole of said amine (IV) in said mixture (V) at a temperature in the range from 50 to 200° C. to obtain a mixture (VII), b) distilling said aminonitrile (I) or said diamine (II) or said dinitrile (III) or mixtures thereof from said mixture (VII) at a temperature in the range from 50 to 200° C. and at a pressure in the range from 0.1 to 100 kPa to obtain a bottom product (VIII), which comprises c) distilling an aminonitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof from said bottom product (VIII) at a temperature which is lower than that chosen in step b).

公开(公告)号：AU2003247286A1

公开(公告)日：2003-12-12

申请号：AU2003247286

申请日：2003-05-21

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  ANSMANN ANDREAS ,  MAIXNER STEFAN ,  BENISCH CHRISTOPH

IPC: C07C209/84 ,  C07C211/09 ,  C07C211/12 ,  C07C253/34 ,  C07C255/09 ,  C07C255/24

Abstract: A process for reducing the level of an aliphatic monounsaturated amine (IV) in a mixture (V) containing an aminonitrile (I) or a diamine (II) or a dinitrile (III) or mixtures thereof as well as said mine (IV) by a) reacting said mixture (V) with an anionic nucleophile (VI) which contains a nucleophilic atom selected from the group consisting of oxygen, nitrogen and sulfur, which is capable of taking up an H + ion to form an acid having a pK a value in the range from 7 to 11, as measured in water at 25° C., and which has a relative nucleophilicity, as measured in methyl perchlorate/methanol at 25° C., in the range from 3.4 to 4.7 when said nucleophilic atom is oxygen, in the range from 4.5 to 5.8 when said nucleophilic atom is nitrogen, and in the range from 5.5 to 6.8 when said nucleophilic atom is sulfur, in an amount in the range from 0.01 to 10 mol per mole of said amine (IV) in said mixture (V) at a temperature in the range from 50 to 200° C. to obtain a mixture (VII), b) distilling said aminonitrile (I) or said diamine (II) or said dinitrile (III) or mixtures thereof from said mixture (VII) at a temperature in the range from 50 to 200° C. and at a pressure in the range from 0.1 to 100 kPa to obtain a bottom product (VIII), which comprises c) distilling an aminonitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof from said bottom product (VIII) at a temperature which is lower than that chosen in step b).

公开(公告)号：DE10217439A1

公开(公告)日：2003-10-30

申请号：DE10217439

申请日：2002-04-18

Applicant: BASF AG

Inventor： WINTERLING HELMUT ,  BENISCH CHRISTOPH ,  HAHN THILO

IPC: C08G69/00 ,  C08G69/04 ,  C08G69/08 ,  C08G69/16 ,  C08G69/20 ,  C08G69/28 ,  C08G69/38

Abstract: A process for preparing a polyamide by reacting a mixture which comprises a monomer which has a nitrile group and has at least one other functional group capable of forming a carboxamide group, and comprises water, in the presence of titanium dioxide as catalyst, which comprises using titanium dioxide whose BET surface area, determined to the German standard DIN 66 131 volumetrically by the multipoint method, is in the range from 5 to 35 m2/g.

公开(公告)号：CA2481456A1

公开(公告)日：2003-10-30

申请号：CA2481456

申请日：2003-04-08

Applicant: BASF AG

Inventor： HAHN THILO ,  BENISCH CHRISTOPH ,  WINTERLING HELMUT

IPC: C08G69/00 ,  C08G69/04 ,  C08G69/08 ,  C08G69/16 ,  C08G69/20

Abstract: The invention relates to a method for producing a polyamide by converting a mixture containing a monomer that comprises a nitrile group and at least one additional functional group that is capable of forming a carboxamide group, in addition to water in the presence of titanium dioxide, which acts as the catalyst. Said method is characterised in that the titanium dioxide has a BE T surface area ranging between 5 and 35 m2/g, determined by means of a volumetric process according to a multipoint method, as per the German standard DIN 66 131.

公开(公告)号：AU2003218681A1

公开(公告)日：2003-09-16

申请号：AU2003218681

申请日：2003-03-03

Applicant: BASF AG

Inventor： FUNKE FRANK ,  MULLER GUNTER ,  GAUS GUNTER ,  BENISCH CHRISTOPH ,  BOHLING RALF ,  STEINBRENNER ULRICH

IPC: C07B61/00 ,  C07C209/60 ,  C07C211/05 ,  C07C211/08

Abstract: The present invention describes a process for the preparation of ethyldimethylamine and triethylamine with the following steps: (i) reaction of a mixture of diethylamine and dimethylamine with ethylene in the presence of a catalyst from the group of alkali metal dimethylamides, alkali metal diethylamides and alkali metal hydrides (ii) removal of the catalyst (iii) distillation separation of the resulting mixture in triethylamine and ethyldimethylamine and optionally diethylamine and dimethylamine (iv) optional return of the catalyst and of the starting amines to the reaction. The process according to the invention permits the coproduction of ethyldimethylamine and diethylamine in a simple process.

公开(公告)号：DE10151558A1

公开(公告)日：2003-04-30

申请号：DE10151558

申请日：2001-10-23

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J37/18 ,  B01J23/745 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C01G49/02

Abstract: The oxidic material suitable for use as a hydrogenation catalyst contains a) bivalent and trivalent iron, the atomic ratio of bivalent iron to trivalent iron ranging from more than 0.5 to 5.5, and b) oxygen as a counter ion to the bivalent and trivalent iron.

公开(公告)号：AU3321302A

公开(公告)日：2002-06-11

申请号：AU3321302

申请日：2001-11-29

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  BENISCH CHRISTOPH ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  BASSLER PETER ,  MAIXNER STEFAN

IPC: C07C209/84 ,  C07C211/09 ,  C07C253/34 ,  C07C255/24

Abstract: A process is provided for reducing the content of a monounsaturated aliphatic amine (III) in a mixture (IV) containing an aminonitrile (I) or a diamine (II), or mixtures thereof, and the amine (III), whereina) the mixture (IV) is reacted with an anionic nucleophile (V),which contains a nucleophilic atom selected from the group comprising oxygen, nitrogen and sulfur,which is capable of taking up an H ion to form an acid with a pKa ranging from 7 to 11, measured in water at 25° C., andwhich has a relative nucleophilicity, measured in methyl perchlorate/methanol at 25° C.,ranging from 3.4 to 4.7 when oxygen is the nucleophilic atom,ranging from 4.5 to 5.8 when nitrogen is the nucleophilic atom, andranging from 5.5 to 6.8 when sulfur is the nucleophilic atom,in an amount ranging from 0.01 to 10 mol per mole of amine (III) in the mixture (IV), to give a mixture (VI), andb) the aminonitrile (I) or the diamine (II), or mixtures thereof, are distilled from the mixture (VI) at a temperature ranging from 50 to 170° C. and a pressure ranging from 0.5 to 100 kPa.

公开(公告)号：DE10056839A1

公开(公告)日：2002-05-23

申请号：DE10056839

申请日：2000-11-16

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  FUNKE FRANK ,  OHLBACH FRANK ,  MERGER MARTIN

IPC: C07D295/12 ,  B01J25/00 ,  B01J25/02 ,  B01J35/04 ,  B01J35/10 ,  B01J37/00 ,  C07B61/00 ,  C07C209/48 ,  C07C211/14 ,  C07C211/35 ,  C07C211/36 ,  C07D295/13 ,  C07B43/04 ,  C07C211/00 ,  C07C211/09 ,  C07C225/20 ,  C07C221/00 ,  C07D227/04 ,  C07D247/00

Abstract: Nitrite is hydrogenated to primary amine using an activated macroporous Raney catalyst comprising alpha -alumina and transition metal(s), obtained by (i) shaping kneadable composition comprising an alloy, a shaping aid, water and a pore former, (ii) calcining and activating by treating with aqueous alkali metal hydroxide solution and (iii) rinsing with aqueous alkali metal hydroxide solution and water. Hydrogenating nitrite to primary amine involves using activated macroporous Raney catalyst comprising alpha -alumina and transition metal(s), such as iron, cobalt, nickel, titanium, zirconium, chromium and manganese. The Raney catalyst is obtained by preparing a kneadable composition comprising an alloy, a shaping aid, water and a pore former, which is then shaped to form a component. The shaped component is calcined and activated by treating with aqueous alkali metal hydroxide solution. The catalyst obtained is rinsed with aqueous alkali metal hydroxide solution and water. Independent claims are also included for the following: (1) a macroporous Raney catalyst; and (2) the production of a macroporous Raney catalyst.