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公开(公告)号:AT382593T
公开(公告)日:2008-01-15
申请号:AT03725100
申请日:2003-04-25
Applicant: BASF AG
Inventor: WULFF CHRISTIAN , STOESSER MICHAEL , GROSCH GEORG , BALDENIUS KAI-UWE , BOHRES EDWARD
IPC: C07C41/03 , C09K23/42 , B01J27/26 , C07B61/00 , C07C43/11 , C08G65/26 , C09K23/00 , C11D1/72 , C11D1/722
Abstract: Producing alkoxylates involves contacting one or more alkylene oxides selected from ethylene, propylene, butylene, pentylene and decene oxides with a starter compound in the presence of a binary metal cyanide compound (I) and performing the reaction at 130-155 degreesC. Producing alkoxylates involves contacting one or more alkylene oxides selected from ethylene, propylene, butylene, pentylene and decene oxides with a starter compound in the presence of a binary metal cyanide compound M1a(M2(CN)b(A)c)d.fM1gXn.h(H2O).eL.kP' (I) and performing the reaction at 130-155 degreesC. M1 = Zn2+, Fe2+, Fe3+, Co3+, Ni2+, Mn2+, Co2+, Sn2+, Pb2+, Mo4+, Mo6+, Al3+, V4+, V5+, Sr2+, W4+, W6+, Cr2+, Cr3+, Cd2+, Hg2+, Pd2+, Pt2+, V2+, Mg2+, Ca2+, Ba2+, Cu2+, La3+, Ce3+, Ce4+, Eu3+, Ti3+, Ti4+, Ag+, Rh2+, Rh3+, Ru2+ or Ru3+; M2 = Fe2+, Fe3+, Co3+, Mn2+, Mn3+, V4+, V5+, Cr2+, Cr3+, Rh3+, Ru2+ or Ir3+; A, X = halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate, nitrosyl, bisulfate, phosphate, (di)hydrogen phosphate or bicarbonate; L = a water-soluble alcohol, aldehyde, ketone, ether, polyether, ester, polyester, polycarbonate, urea, amide, amine, pyridine, nitrile, sulfide, phosphide, phosphite, phosphine, phosphonate or phosphate ligand; k, e, f, h = 0 or more; P' = an organic additive; and a, b, c, d, g, n = numbers so that (I) is electrically neutral and c can be zero. An Independent claim is also included for an alkoxylate produced by the novel method.
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公开(公告)号:ES2271616T3
公开(公告)日:2007-04-16
申请号:ES03743859
申请日:2003-03-10
Applicant: BASF AG
Inventor: STOSSER MICHAEL , BOHRES EDWARD , GROSCH GEORG HEINRICH , SAGER WILFRIED , WALTER MARC
IPC: C08G65/26 , C10L1/192 , C08G65/28 , C08L71/08 , C10L1/14 , C10L1/18 , C10L1/198 , C10L1/22 , C10L10/04
Abstract: Poliéteres, obtenibles a partir del óxido de 1-buteno y de un alcohol con empleo de un compuesto de cianuro bimetálico como catalizador, caracterizados porque el contenido en componentes insaturados está comprendido entre el 15 y el 30 % en moles.
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公开(公告)号:PT1485424E
公开(公告)日:2006-12-29
申请号:PT03743859
申请日:2003-03-10
Applicant: BASF AG
Inventor: WALTER MARC , GROSCH GEORG HEINRICH , STOESSER MICHAEL , BOHRES EDWARD , SAGER WILFRIED
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公开(公告)号:DE102004048735A1
公开(公告)日:2006-04-27
申请号:DE102004048735
申请日:2004-10-05
Applicant: BASF AG
Inventor: BOHRES EDWARD , TRILLER MICHAEL , BECHTLOFF BERND , RUPPEL RAIMUND
Abstract: The invention provides a continuous process for preparing DMC catalysts, which comprises continuously feeding the solutions of a metal salt and of a hexacyanometallate compound and, if appropriate, organic ligands and/or organic additives into a continuous reactor, and continuously withdrawing the resulting suspension of the DMC compound from the reactor.
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25.
公开(公告)号:ES2250719T3
公开(公告)日:2006-04-16
申请号:ES02776928
申请日:2002-08-10
Applicant: BASF AG
Inventor: BAUM EVA , GROSCH GEORG HEINRICH , BECHTEL SIEGFRIED , RUPPEL RAIMUND , HARRE KATHRIN , BOHRES EDWARD
Abstract: Procedimiento para el aumento de la actividad catalítica de compuestos de cianuro multimetálico para el empleo en la adición de óxidos de alquileno en substancias iniciadoras con H funcionales, caracterizado porque los compuestos de cianuro multimetálico se someten a una desaglomeración con ultrasonido inmediatamente antes de su mezcla con las substancias iniciadoras H funcionales.
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公开(公告)号:NO20044115L
公开(公告)日:2004-09-28
申请号:NO20044115
申请日:2004-09-28
Applicant: BASF AG
Inventor: SAGER WILFRIED , WALTER MARC , STOSSER MICHAEL , BOHRES EDWARD , GROSCH GEORG HEINRICH
IPC: C10L1/192 , C08G65/26 , C08G65/28 , C08L71/08 , C10L1/14 , C10L1/18 , C10L1/198 , C10L1/22 , C10L10/04 , C08G65/12
Abstract: The present invention relates to polyethers which are obtainable from 1 -butene oxide and an alcohol using a double metal cyanide compound as a catalyst and have a content of unsaturated components of 6 mol% or more, to a process for preparing such a polyether and also to the use of a polyether according to the invention as a carrier oil or in a carrier oil formulation, in particular in additive packages for gasoline fuels, and furthermore also to carrier oil formulations and also to fuels comprising a polyether according to the invention.
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公开(公告)号:AU2003227679A1
公开(公告)日:2004-05-04
申请号:AU2003227679
申请日:2003-04-25
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH , BALDENIUS KAI-UWE , BOHRES EDWARD , WULFF CHRISTIAN , STOSSER MICHAEL
IPC: C09K23/42 , B01J27/26 , C07B61/00 , C07C41/03 , C07C43/11 , C08G65/26 , C09K23/00 , C11D1/72 , C11D1/722
Abstract: Producing alkoxylates involves contacting one or more alkylene oxides selected from ethylene, propylene, butylene, pentylene and decene oxides with a starter compound in the presence of a binary metal cyanide compound (I) and performing the reaction at 130-155 degreesC. Producing alkoxylates involves contacting one or more alkylene oxides selected from ethylene, propylene, butylene, pentylene and decene oxides with a starter compound in the presence of a binary metal cyanide compound M1a(M2(CN)b(A)c)d.fM1gXn.h(H2O).eL.kP' (I) and performing the reaction at 130-155 degreesC. M1 = Zn2+, Fe2+, Fe3+, Co3+, Ni2+, Mn2+, Co2+, Sn2+, Pb2+, Mo4+, Mo6+, Al3+, V4+, V5+, Sr2+, W4+, W6+, Cr2+, Cr3+, Cd2+, Hg2+, Pd2+, Pt2+, V2+, Mg2+, Ca2+, Ba2+, Cu2+, La3+, Ce3+, Ce4+, Eu3+, Ti3+, Ti4+, Ag+, Rh2+, Rh3+, Ru2+ or Ru3+; M2 = Fe2+, Fe3+, Co3+, Mn2+, Mn3+, V4+, V5+, Cr2+, Cr3+, Rh3+, Ru2+ or Ir3+; A, X = halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate, nitrosyl, bisulfate, phosphate, (di)hydrogen phosphate or bicarbonate; L = a water-soluble alcohol, aldehyde, ketone, ether, polyether, ester, polyester, polycarbonate, urea, amide, amine, pyridine, nitrile, sulfide, phosphide, phosphite, phosphine, phosphonate or phosphate ligand; k, e, f, h = 0 or more; P' = an organic additive; and a, b, c, d, g, n = numbers so that (I) is electrically neutral and c can be zero. An Independent claim is also included for an alkoxylate produced by the novel method.
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公开(公告)号:AU2003227678A1
公开(公告)日:2004-05-04
申请号:AU2003227678
申请日:2003-04-25
Applicant: BASF AG
Inventor: WAGNER NORBERT , BOHRES EDWARD , WULFF CHRISTIAN , BALDENIUS KAI-UWE , SCHOLTISSEK MARTIN , STOSSER MICHAEL
Abstract: Composition (A) contains at least one alkoxylated 6-18C alkanol (I). Composition (A) contains at least one alkoxylated 6-18C alkanol of formula RO-(A)n-(B)m-H (I). R = 6-18C linear or branched alkyl; A = propyleneoxy (PO); B = ethyleneoxy (EO) or a mixture of EO and PO; n = integer or fractional number of 0-5; and m = integer or fractional number of 0-20. When R is C5H11CH(C3H7)CH2-, n is less than 1, provided that R is a mixture where 70-99 %, by weight of C5H11 is linear and 1-30 %, by weight is EtCH(Me)CH2 and/or MeCH(Me)CH-2CH2. An Independent claim is also included for a method for preparing (I) by reacting ROH with propylene and ethylene oxides.
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公开(公告)号:AU2003273863A1
公开(公告)日:2004-04-19
申请号:AU2003273863
申请日:2003-09-12
Applicant: BASF AG
Inventor: MERTEN ANNE-KATHRIN , WINKLER JURGEN , HARRE KATHRIN , LORENZ REINHARD , RUPPEL RAIMUND , OSTROWSKI THOMAS , BOHRES EDWARD , HOPPNER GERD , HOPPE ANDREAS
Abstract: The invention relates to a method for producing polyether alcohols by means of catalytic polymerisation of alkylene oxides. Said method is characterised in that the alkylene oxide contains propylene oxide, at least one multimetal cyanide compound is used as a catalyst, and the free alkylene oxide content in the reactor is lower than or equal to 8 wt. %, in relation to the total amount of educts and reaction products in the reactor.
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公开(公告)号:DE10243362A1
公开(公告)日:2004-04-01
申请号:DE10243362
申请日:2002-09-18
Applicant: BASF AG
Inventor: WULFF CHRISTIAN , STOESER MICHAEL , GROSCH GEORG HEINRICH , BALDENIUS KAI-UWE , BOHRES EDWARD
IPC: B01J27/26 , C07B61/00 , C07C41/03 , C07C43/11 , C09K23/42 , C08G65/26 , C09K23/00 , C11D1/72 , C08G65/10 , C11D1/825
Abstract: Producing alkoxylates involves contacting one or more alkylene oxides selected from ethylene, propylene, butylene, pentylene and decene oxides with a starter compound in the presence of a binary metal cyanide compound (I) and performing the reaction at 130-155 degreesC. Producing alkoxylates involves contacting one or more alkylene oxides selected from ethylene, propylene, butylene, pentylene and decene oxides with a starter compound in the presence of a binary metal cyanide compound M1a(M2(CN)b(A)c)d.fM1gXn.h(H2O).eL.kP' (I) and performing the reaction at 130-155 degreesC. M1 = Zn2+, Fe2+, Fe3+, Co3+, Ni2+, Mn2+, Co2+, Sn2+, Pb2+, Mo4+, Mo6+, Al3+, V4+, V5+, Sr2+, W4+, W6+, Cr2+, Cr3+, Cd2+, Hg2+, Pd2+, Pt2+, V2+, Mg2+, Ca2+, Ba2+, Cu2+, La3+, Ce3+, Ce4+, Eu3+, Ti3+, Ti4+, Ag+, Rh2+, Rh3+, Ru2+ or Ru3+; M2 = Fe2+, Fe3+, Co3+, Mn2+, Mn3+, V4+, V5+, Cr2+, Cr3+, Rh3+, Ru2+ or Ir3+; A, X = halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate, nitrosyl, bisulfate, phosphate, (di)hydrogen phosphate or bicarbonate; L = a water-soluble alcohol, aldehyde, ketone, ether, polyether, ester, polyester, polycarbonate, urea, amide, amine, pyridine, nitrile, sulfide, phosphide, phosphite, phosphine, phosphonate or phosphate ligand; k, e, f, h = 0 or more; P' = an organic additive; and a, b, c, d, g, n = numbers so that (I) is electrically neutral and c can be zero. An Independent claim is also included for an alkoxylate produced by the novel method.
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