公开(公告)号：DE102004008198A1

公开(公告)日：2005-09-01

申请号：DE102004008198

申请日：2004-02-18

Applicant: BASF AG

Inventor： DESBOIS PHILIPPE

IPC: C08F212/00 ,  C08F287/00 ,  C08F297/04 ,  C08L25/10 ,  C08L51/04 ,  C08F236/06 ,  C08F2/06 ,  C08F4/46 ,  C08F4/50 ,  C08F4/52 ,  C08F212/08

公开(公告)号：DE10352105A1

公开(公告)日：2005-06-02

申请号：DE10352105

申请日：2003-11-04

Applicant: BASF AG

Inventor： DESBOIS PHILIPPE ,  DEFFIEUX ALAIN ,  CARLOTTI STEPHANE ,  BILLOUIARD CYRILLE

IPC: C08G65/10 ,  C08G65/12 ,  C08G65/26

Abstract: The invention relates to a process for preparation of homopolymers composed of oxiranes, or of copolymers composed of oxirans and comonomers, via anionic polymerization, which comprises carrying out a polymerization in the presence of a quaternary ammonium and/or phosphonium compound and of a mononuclear organylaluminum compound.

公开(公告)号：AT261457T

公开(公告)日：2004-03-15

申请号：AT00977456

申请日：2000-10-31

Applicant: BASF AG

Inventor： DESBOIS PHILIPPE ,  WARZELHAN VOLKER ,  SCHADE CHRISTIAN ,  FONTANILLE MICHEL ,  DEFFIEUX ALAIN ,  MENORET STEPHANE

IPC: C08F2/38 ,  C08F2/44 ,  C08F4/44 ,  C08F4/48 ,  C08F4/52 ,  C08F4/54 ,  C08F12/00 ,  C08F12/04 ,  C08F36/00 ,  C08F36/04 ,  C08F291/00 ,  C08F297/04

Abstract: In a process for the anionic polymerization of vinylaromatic monomers or dienes in the presence of a lithium organyl or lithium alcoholate and a magnesium and/or an aluminum compound, a sterically hindered phenol or amine is added.

公开(公告)号：DE10158500A1

公开(公告)日：2003-06-12

申请号：DE10158500

申请日：2001-11-28

Applicant: BASF AG

Inventor： KNOLL KONRAD ,  DESBOIS PHILIPPE ,  WALTER HANS-MICHAEL

IPC: C08F279/02 ,  C08F297/04 ,  C08L25/04 ,  C08L53/02

Abstract: The invention relates to mixtures containing linear block copolymers consisting of vinyl aromatic monomers and dienes, of structure (I) S 1 -B 1 -S 2 and (II) S 3 -B 2 -S 4 , wherein S 1 represents a block of vinyl aromatic monomers having a number average molar mass M n of between 40,000 and 100,000 g/mol; S2, S3 and S 4 respectively represent blocks of vinyl aromatic monomers having a number average molar mass M n of between 5,000 and 20,000 g/mol; and B 1 and B 2 respectively represent blocks of dienes or copolymer blocks of dienes and vinyl aromatic monomers having a number average molar mass M n of between 15,000 and 40,000 g/mol. The ratio of the block copolymers (I)/(II) is between 0.6 and 2.

公开(公告)号：AU2002342837A1

公开(公告)日：2003-05-06

申请号：AU2002342837

申请日：2002-10-18

Applicant: BASF AG

Inventor： DEMETER JURGEN ,  SCHADE CHRISTIAN ,  DESBOIS PHILIPPE ,  GAUSEPOHL HERMANN

IPC: C08F2/44 ,  C08F4/00 ,  C08F279/02 ,  C08F287/00 ,  C08F212/08

Abstract: A process for preparing impact-resistant molding compositions by anionic polymerization of vinylaromatic monomers in the presence of a rubber, in a continuous-flow reactor cascade composed of at least two reactors, where the vinylaromatic monomers are fed in substreams to the reactors of the reactor cascade, and an anionic initiator and a rubber are fed at least to the first reactor, and where the reactor cascade is composed of back-mixing reactors.

公开(公告)号：DE10152116A1

公开(公告)日：2003-04-30

申请号：DE10152116

申请日：2001-10-23

Applicant: BASF AG

Inventor： GAUSEPOHL HERMANN ,  DEMETER JUERGEN ,  DESBOIS PHILIPPE ,  SCHADE CHRISTIAN

IPC: C08F4/00 ,  C08F279/02 ,  C08F2/44 ,  C08F287/00 ,  C08F12/00 ,  C08F12/08

Abstract: A method for the production of impact-resistant moulding materials by anionic polymerization of vinyl aromatic monomers in the presence of rubber in a continuously through-flown reactor cascade consisting of at least two reactors. The vinyl aromatic monomers are fed to the reactors of the reactor cascade in partial flows and an anionic initiator and rubber are fed to at least the first reactor. The reactor cascade consists of backmixed reactors.

公开(公告)号：BR0015492A

公开(公告)日：2002-06-25

申请号：BR0015492

申请日：2000-10-31

Applicant: BASF AG

Inventor： DESBOIS PHILIPPE ,  WARZELHAN VOLKER ,  SCHADE CHRISTIAN ,  FONTANILLE MICHEL ,  DEFFIEUX ALAIN ,  MENORET STEPHANE

IPC: C08F2/38 ,  C08F2/44 ,  C08F4/44 ,  C08F4/48 ,  C08F4/52 ,  C08F4/54 ,  C08F12/00 ,  C08F12/04 ,  C08F36/00 ,  C08F36/04 ,  C08F291/00 ,  C08F297/04

Abstract: In a process for the anionic polymerization of vinylaromatic monomers or dienes in the presence of a lithium organyl or lithium alcoholate and a magnesium and/or an aluminum compound, a sterically hindered phenol or amine is added.

公开(公告)号：AU4776199A

公开(公告)日：2000-01-10

申请号：AU4776199

申请日：1999-06-23

Applicant: BASF AG

Inventor： DESBOIS PHILIPPE ,  SCHADE CHRISTIAN ,  GAUSEPOHL HERMANN ,  WARZELHAN VOLKER

IPC: C08J5/00 ,  C08F4/50 ,  C08F279/02 ,  C08F287/00 ,  C08F297/04

Abstract: An anionically polymerized impact-modified polystyrene has a yield stress of at least 24 MPa, measured at 23° C. to DIN 53455 and a hole impact strength of at least 11 kJ/m2, measured at 23° C. to DIN 53753, measured in each case on a specimen produced to ISO 3167. A preparation process is described.

公开(公告)号：DE19806774A1

公开(公告)日：1999-08-19

申请号：DE19806774

申请日：1998-02-18

Applicant: BASF AG

Inventor： SCHADE CHRISTIAN ,  FISCHER WOLFGANG ,  GAUSEPOHL HERMANN ,  KLOSTERMANM RAINER ,  WARZELHAN VOLKER ,  FONTANILLE MICHEL ,  DEFFIEUX ALAIN ,  DESBOIS PHILIPPE

IPC: C08F4/52 ,  C08F4/46 ,  C08F4/50 ,  C08F12/04 ,  C08F236/10 ,  C08F279/02 ,  C08F297/06 ,  C08F12/00 ,  C08F236/00

Abstract: A process for the homopolymerization of vinyl aromatic monomers or copolymerization of vinyl aromatic monomers and dienes comprises polymerization of the monomers in the presence of at least an organoalkali metal, an organomagnesium compound and an organoaluminum compound. Independent claims are included for: (i) an initiator composition comprising an organoalkali metal, an organomagnesium compound and an organoaluminum compound, whereby the molar ratio of magnesium to the alkali metal is 0.2-3.8 and the molar ratio of aluminum to the alkali metal is 0.2-4; (ii) a process for the preparation of an initiator composition by dissolving the organometallic compounds in inert hydrocarbons and allowing the mixture to mature at 0-120 deg C for at least 5 minutes.

公开(公告)号：DE19731419A1

公开(公告)日：1999-01-28

申请号：DE19731419

申请日：1997-07-22

Applicant: BASF AG

Inventor： SCHADE CHRISTIAN DR ,  LAETSCH STEFAN DR ,  LOTH WOLFGANG DR ,  FISCHER WOLFGANG DR ,  GAUSEPOHL HERMANN DR ,  WARZELHAN VOLKER DR ,  FONTANILLE MICHAEL ,  DEFFIEUX ALAIN PROF DR ,  DESBOIS PHILIPPE

IPC: C08F36/04 ,  C08F279/02 ,  C08F297/04 ,  C08F12/08 ,  C08F12/12 ,  C08F12/36

Abstract: Continuous anionic (co)polymerisation of styrene or diene monomers with alkali metal alkyl (I) as initiator is carried out in the presence of an alkyl or aryl of an at least divalent metal as retarder (II). Also claimed are (a) an initiator containing (I) and (II); (b) a solution of the initiator in a (cyclo)aliphatic hydrocarbon; and (c) styrene polymers obtained by this process.