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公开(公告)号:DK0960723T3
公开(公告)日:2004-06-01
申请号:DK99110033
申请日:1999-05-21
Applicant: BASF AG
Inventor: BIEDERMANN ANJA DR , HEMPEL RENATE , ROTERMUND UDO DR , SCHILLING UDO , SCHLEGEL KARL DR
Abstract: In a composite element comprising layers of (i) polyisocyanate poly-addition product (PU), (ii) optionally at least one plastic, (iii) a gas permeation barrier and (iv) at least one thermoplastic, layers (iii) and (iv) are bonded together by melting a layer (iiia) between them. Independent claims are also included for: (a) sandwich elements with the following layers: (iv) 1-25 mm thermoplastic, (iii) 0.1-200 micro m metal foil coated on the opposite side from (i) and (ii) with 20-500 micro m thermoplastic (iiia) which is melted to bond (iii) with (iv), (ii) optionally 5-1000 micro m plastic, (i) 0.5-80 cm PU and then layers (ii), (iii) and (iv) as above; (b) tubes with the following layers: (iv) as above and/or metal as inner tube, (i), (ii), (iii) as above and (iv) (above) as an outer tube; (c) tubes with the following layers: (iv) plastic as above and/or metal as inner tube, (iii), (ii), (i), (ii), (iii) as above and (iv) plastic (above) as an outer tube; (d) the production of composite elements by reacting isocyanates with NCO-reactive compounds in the presence of blowing agents and optionally catalysts and other additives etc. in a reaction space bounded by layers (ii) (optional), (iii) gas barrier material, (iiia) 20-500 micro m thermoplastic and (iv) 1-25 mm thermoplastic(s), so that layer (iiia) is melted by the heat of reaction and binds layers (iii) and (iv) together after cooling; and (e) composite elements obtained by (d).
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公开(公告)号:DK0832909T3
公开(公告)日:2004-06-01
申请号:DK97116522
申请日:1997-09-23
Applicant: BASF AG
Inventor: ROTERMUND UDO DR , SEIFERT HOLGER DR , HEMPEL RENATE , WIEGMANN WERNER
Abstract: A process for the production of rigid polyurethane foam with improved thermodimensional stability and reduced thermal conductivity comprises reacting (a) polyisocyanates with (b) compounds with isocyanate-reactive hydrogen atoms in presence of (c) water and optionally (d) physical blowing agents and (e) catalysts and other additives etc. 60-100 wt% of component (b) consists of a polyol mixture containing (b1) a polyol obtained by addition of ethylene oxide (EO) and/or propylene oxide (PO) to a hexitol or hexitol mixture and (b2) a polyol obtained by addition of EO and/or PO to one or more aromatic amines, such that the total hexitol content and the total amine content of the polyol mixture is 15-30 wt% and 1-10 wt% respectively.
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公开(公告)号:DE10248307A1
公开(公告)日:2004-04-29
申请号:DE10248307
申请日:2002-10-16
Applicant: BASF AG
Inventor: FALKE PETER , ROTERMUND UDO , HEMPEL RENATE , VIETH SIEGFRIED
Abstract: Ceramic foams are prepared by reaction of organic and/or modified organic polyisocyanates with a polyetherol mixture comprising a mixture of bifunctional polyetherols and up to 60 wt.% of a suitable inorganic solid followed by drying and baking. Ceramic foams (I) are prepared by reaction of organic and/or modified organic polyisocyanates (A) with a polyetherol mixture (B) and optionally other hydrogen atom containing compounds (C) that are reactive with isocyanates in the presence of water and/or other propellants (D), catalysts (E) and processing aids and additiives (F) followed by drying and baking whereby the polyetherol mixture (B) comprises at least 60 wt.% of at least one bifunctional polyetherol (B1) having an OH number of 20-150 mgKOH/g based on propylene oxide and/or butylene oxide and ethylene oxide whereby the ethylene oxide content is greater than 40 wt.% (with respect to the total quantity of alkylene oxide) and up to 40 wt.% of at least one bifunctional polyetherol (B2) having an OH number of greater than 25 mgKOH/g based on propylene oxide and/or butylene oxide and up to 60 wt.% of a suitable inorganic solid (F1) (with respect to all components (B)-(F).
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公开(公告)号:DE10156132A1
公开(公告)日:2003-05-28
申请号:DE10156132
申请日:2001-11-16
Applicant: BASF AG
Inventor: ROTERMUND UDO , HEMPEL RENATE , VOELKEL RUEDIGER , SCHLEGEL KARL , FALKE PETER
Abstract: The invention concerns a foam consisting of at least 70 wt. % of carbon, having an average cell size more than 30 mu m, porosity between 35 % and 99.7 %, a percentage of open cells higher than 90 %, and comprising linking elements between the cells, which, viewed in cross-section, form a triangle with inward-curving sides. Inside the surface of the cross-section, the sum of the surfaces having a cavity constitutes less than 5 % of the total cross-sectional area of the linking elements. The invention also concerns the use of said foams consisting for the major part of carbon in electrical and electrochemical applications, in the form of filtering material, heat insulation material, support material, storage material and as starting material for other transformations. The invention further concerns a method for producing a foam consisting of at least 70 wt. % of carbon, by pyrolizing synthetic foams. Said method is characterized in that the synthetic foams used contain at least 30 wt. % of a polymer material having a nitrogen content higher than 6 wt. %, and having a porosity between 20 and 99 %, as well as a percentage of open cells higher than 1 %.
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公开(公告)号:DE19961973A1
公开(公告)日:2001-06-28
申请号:DE19961973
申请日:1999-12-22
Applicant: BASF AG
Inventor: GASSAN MICHAEL , GUETTES BERND , SANDER MICHAEL , KRAUS RUPERT , PLAUMANN HEINZ , ROTERMUND UDO , BIEDERMANN ANJA , SEITZ CHRISTIAN , REICHELT MICHAEL , HEMPEL RENATE
Abstract: An agent for the surface modification of fillers for polyamide compositions comprises: (A) an amino-functional silane, a bis-aminosilane a tertiary aminosilane or an oligomer of these; (B) a mixture of an amino-functional silane, bis-aminosilane and/or tertiary aminosilane and an alkyl-, alkenyl- or polyether-functional silane and optionally an oligomer of these; or (C) a mixture of an alkyl-functional silane and an alkenyl-functional silane and optionally an oligomer of these. An agent for the surface modification of fillers for polyamide compositions comprises either: (A) an agent comprising: (i) an amino-functional silane of formula (Ia); (ii) a bis-aminosilane (Ib); (iii) a tertiary aminosilane (Ic); or an oligomer of (Ia)-(Ic) with a degree of oligomerization (DO) of 2-20; (B) a mixture of: (i) a component comprising (a) an amino-functional silane of formula (IIa), (b) a secondary aminosilane (IIb) and/or (c) a tertiary aminosilane (IIc); and (ii) a component comprising either (a) an alkyl-functional silane of formula (III), (b) an alkenyl-functional silane of formula (IV), (c) a polyether-functional silane of formula (V); and optionally (iii) an oligomer of (IIa)-(IIc) and (III)-(V) with a DO of 2-20; or (C) a mixture of: (i) an alkyl-functional silane of formula (IIIa); and (ii) an alkyl-functional silane of formula (IV); and optionally (iii) an oligomer of (IIIa) and (IV) with a DO of 2-20. RNH-(CH2)3-Si(Me)x(Z)3-x (Ia) Z = 1-3C alkoxy, OH or Cl; x = 0 or 1; and R = 1-20C alkyl, 5-12C cycloalkyl or 6-12C aryl. R-Si(Me)x(Z)3-x (IIa) Z = 1-3C alkoxy, OH or Cl; x = 0 or 1; R = H2N((CH2)2NH)y(CH2)3; and y = 0-2. R'-Si(Me)x(Z)3-x (IIIa) Z = 1-3C alkoxy, OH or Cl; x = 0-1; and R' = optionally fluorinated 1-16C alkyl or cycloalkyl. CH2=CH(CH2)n-Si(Me)x(Z)3-x (IV) Z = 1-3C alkoxy, OH or Cl; x = 0 or 1; and n = 0-20. R(OCH2CHR')nO(CH2)mSi (Me)x(Z)3-x (V) z = 1-3C alkoxy, OH or Cl; x = 0 or ; R = 1-4C alkyl; R' = H or Me; n = 5-20; and m = 2 or 3. Independent claims are also included for the following: (1) a filler surface-modified with the above agent; (2) an article comprising the surface-modified filler; (3) a filled polyamide composition produced using the surface-modified filler; and (4) an article based on the filled polyamide composition.
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公开(公告)号:EA001373B1
公开(公告)日:2001-02-26
申请号:EA199800595
申请日:1996-12-16
Applicant: BASF AG
Inventor: KRECH RUDIGER , ROTERMUND UDO , BOLLMANN HEINZ , HEMPEL RENATE , SCHOLZ WOLFGANG , GRNZ MANFRED
IPC: C08G18/08 , C08G18/40 , C08G18/76 , C08G101/00 , C08J9/36
Abstract: Объектомизобретенияявляетсямикропористыйполиуретановыйэластомерс улучшеннымидинамически-механическимисвойстваминаосновесостоящегопосуществуиздифенилметан-4,4'-диизоцианатаизоцианатногокомпонента, атакжедругихобычныхсоставныхчастей, которыйпослеотжигапритемпературахот 100 до 120°Св течениевремениотвосьмидодвадцатичетырехчасовимеетобластьплавленияот 130°Св качествеминимальногонижнегопределадо 230°Св качествеминимальноговерхнегопредела, определяемуюпометодудифференциальнойсканирующейкалориметрииприскоростинагрева 20°Св минуту, исодержаниекарбамидав которомсоставляетот 14 до 18 мас.%. Объектамиизобретения, далее, являютсяспособполучениятакогомикропористогополиуретановогоэластомерас улучшеннымидинамически-механическимисвойствами, атакжеприменениемикропористыхполиуретановыхэластомеровдляизготовлениядемпфирующихэлементов.
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公开(公告)号:ES2137027T3
公开(公告)日:1999-12-01
申请号:ES96943967
申请日:1996-12-16
Applicant: BASF AG
Inventor: KRECH RUDIGER , ROTERMUND UDO , BOLLMANN HEINZ , HEMPEL RENATE , SCHOLZ WOLFGANG , GENZ MANFRED
IPC: C08G18/08 , C08G18/40 , C08G18/76 , C08G101/00 , C08J9/36
Abstract: PCT No. PCT/EP96/05639 Sec. 371 Date Nov. 18, 1998 Sec. 102(e) Date Nov. 18, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23534 PCT Pub. Date Jul. 3, 1997A microcellular PU elastomer having improved dynamic-mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and also further customary constituents has, after heating at from 100 to 120 DEG C. for from 8 to 24 hours, a melting range of from 130 DEG C. as the minimum lower limit to 230 DEG C. as a minimum upper limit, measured by differential scanning calorimetry (DSC) at a heating rate of 20 DEG C./min, and a urea content of from 14 to 18% by weight. A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.
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公开(公告)号:NO992527L
公开(公告)日:1999-11-29
申请号:NO992527
申请日:1999-05-26
Applicant: BASF AG
Inventor: BIEDERMANN ANJA , HEMPEL RENATE , ROTERMUND UDO , SCHILLING UDO , SCHLEGEL KARL
IPC: B32B5/18 , C08G18/48 , E04C2/292 , E04C2/296 , F16L9/147 , F16L59/14 , B32B27/40 , B32B27/06 , C08J5/18
Abstract: In a composite element comprising layers of (i) polyisocyanate poly-addition product (PU), (ii) optionally at least one plastic, (iii) a gas permeation barrier and (iv) at least one thermoplastic, layers (iii) and (iv) are bonded together by melting a layer (iiia) between them. Independent claims are also included for: (a) sandwich elements with the following layers: (iv) 1-25 mm thermoplastic, (iii) 0.1-200 micro m metal foil coated on the opposite side from (i) and (ii) with 20-500 micro m thermoplastic (iiia) which is melted to bond (iii) with (iv), (ii) optionally 5-1000 micro m plastic, (i) 0.5-80 cm PU and then layers (ii), (iii) and (iv) as above; (b) tubes with the following layers: (iv) as above and/or metal as inner tube, (i), (ii), (iii) as above and (iv) (above) as an outer tube; (c) tubes with the following layers: (iv) plastic as above and/or metal as inner tube, (iii), (ii), (i), (ii), (iii) as above and (iv) plastic (above) as an outer tube; (d) the production of composite elements by reacting isocyanates with NCO-reactive compounds in the presence of blowing agents and optionally catalysts and other additives etc. in a reaction space bounded by layers (ii) (optional), (iii) gas barrier material, (iiia) 20-500 micro m thermoplastic and (iv) 1-25 mm thermoplastic(s), so that layer (iiia) is melted by the heat of reaction and binds layers (iii) and (iv) together after cooling; and (e) composite elements obtained by (d).
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29.
公开(公告)号:CZ189298A3
公开(公告)日:1999-09-15
申请号:CZ189298
申请日:1996-12-16
Applicant: BASF AG
Inventor: KRECH RUDIGER , ROTERMUND UDO , BOLLMANN HEINZ , HEMPEL RENATE , SCHOLZ WOLFGANG , GENZ MANFRED
Abstract: PCT No. PCT/EP96/05640 Sec. 371 Date Oct. 7, 1998 Sec. 102(e) Date Oct. 7, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23535 PCT Pub. Date Jul. 3, 1997A microcellular PU elastomer having improved dynamic mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and further customary constituents has a physicochemical structure which, in the gel permeation chromatograph (GPC) of a solution of the microcellular polyurethane elastomer prepared at 90 DEG C. in N,N-dimethylformamide containing 1 percent of di-n-butylamine measured against polymethyl methacrylate (PMMA) as standard, displays a signal occurring in addition to low molecular weight main signal and comprising one or more peaks at an (apparent) molar mass of greater than 250,000 g/mol which becomes smaller or disappears on addition of lithium chloride to this solution, and a urea content of from 14 to 18% by weight. A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.
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公开(公告)号:BR9612233A
公开(公告)日:1999-07-13
申请号:BR9612233
申请日:1996-12-16
Applicant: BASF AG
Inventor: KRECH RUEDIGER , ROTERMUND UDO , BOLLMANN HEINZ , HEMPEL RENATE , SCHOLZ WOLFGANG , GENZ MANFRED
IPC: C08J9/36 , C08G18/08 , C08G18/40 , C08G18/76 , C08G101/00
Abstract: PCT No. PCT/EP96/05639 Sec. 371 Date Nov. 18, 1998 Sec. 102(e) Date Nov. 18, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23534 PCT Pub. Date Jul. 3, 1997A microcellular PU elastomer having improved dynamic-mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and also further customary constituents has, after heating at from 100 to 120 DEG C. for from 8 to 24 hours, a melting range of from 130 DEG C. as the minimum lower limit to 230 DEG C. as a minimum upper limit, measured by differential scanning calorimetry (DSC) at a heating rate of 20 DEG C./min, and a urea content of from 14 to 18% by weight. A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.
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