2,7-Dimethyl-octa-2,4,6-trienedial is prepared by double enolether condensation of a butenedial-bisacetal, hydrolysis, dialdehyde conversion and crystallization with all steps effected in an organic solvent

    公开(公告)号:DE102004006579A1

    公开(公告)日:2005-08-25

    申请号:DE102004006579

    申请日:2004-02-10

    Applicant: BASF AG

    Abstract: All steps for production of 2,7-dimethyl-octa-2,4,6-trienedial (I) are in presence of an inert, water-immiscible organic solvent, the process involving (A) Lewis acid-catalyzed double enolether condensation of a butenedial-bisacetal with an enol ether; (B) hydrolysis of the acetal group of the product by aqueous acid addition; (C) conversion of the resulting dialdehyde to (I) using an aqueous base; and (D) crystallization of (I) from the mixture. All of the steps (a) - (d) in the following process for production of 2,7-dimethyl-octa-2,4,6-trienedial of formula (I) are effected in presence of an inert, water-immiscible organic solvent : (A) double enolether condensation of a butenedial-bisacetal of formula (II) with an enol ether of formula (III) in presence of a Lewis acid catalyst; (B) hydrolysis of the acetal group of the resulting condensation product of formula (IV) by adding an aqueous acid to form a dialdehyde of formula (V); (C) conversion of (V) to (I) by reaction with an aqueous base; and (D) crystallization of (I) from the mixture. R 1 and R 21-6C alkyl. [Image].

    23.
    发明专利
    未知

    公开(公告)号:DE50202425D1

    公开(公告)日:2005-04-14

    申请号:DE50202425

    申请日:2002-04-17

    Applicant: BASF AG

    Abstract: Preparation of an aqueous polymer dispersion by radical emulsion polymerization of an aqueous monomer emulsion where the monomer emulsion is prepared continuously by mixing the components with a mixing unit comprising: at least one nozzle selected from: tapered-, hollow tapered-, flat jet-, polished flat jet-, rebound-, and binary nozzles is new.

    28.
    发明专利
    未知

    公开(公告)号:AT290551T

    公开(公告)日:2005-03-15

    申请号:AT02737966

    申请日:2002-04-17

    Applicant: BASF AG

    Abstract: Preparation of an aqueous polymer dispersion by radical emulsion polymerization of an aqueous monomer emulsion where the monomer emulsion is prepared continuously by mixing the components with a mixing unit comprising: at least one nozzle selected from: tapered-, hollow tapered-, flat jet-, polished flat jet-, rebound-, and binary nozzles is new.

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