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    POLYMERS CONTAINING CARBOXYLATE FOR THE TREATMENT OF METALLIC SURFACES
    23.
    发明专利
    POLYMERS CONTAINING CARBOXYLATE FOR THE TREATMENT OF METALLIC SURFACES 未知

    公开(公告)号：CA2516954A1

    公开(公告)日：2004-09-02

    申请号：CA2516954

    申请日：2004-02-19

    Applicant: BASF AG

    Inventor： KLIPPEL FRANK ,  KLUEGLEIN MATTHIAS ,  DIETSCHE FRANK ,  WITTELER HELMUT

    IPC: B05D7/00 ,  B05D7/14 ,  C08L33/14 ,  C09D133/14 ,  C23C22/53 ,  C23C22/56 ,  C23C22/03

    Abstract: A composition for the treatment of metal surfaces comprises 50-99.9 wt.% (meth)acrylic acid or its salts, 0.1-50 wt.% of a carboxylate containing monomer or corresponding salts, anhydrides or esters and/or 0.1-50 wt.% monomers containing phosphoric and/or phosphoric acid groups or their salts, 0-30 wt.% of other compatible monomers and water or another solvent suitable for the dispersion, suspension or emulsification of monomers. A composition (I) for the treatment of metal surfaces comprises: (a) 50-99.9 wt.% (meth)acrylic acid or its salts, 0.1-50 wt.% of a carboxylate containing monomer of formula (1) or corresponding salts, anhydrides or esters and/or 0.1-50 wt.% monomers containing phosphoric and/or phosphonic acid groups or their salts, 0-30 wt.% of other compatible monomers; (b) water or another solvent suitable for the dispersion, suspension or emulsification of (A) and optionally; (c) other surface active agents, dispersing agents, suspending agents and/or emulsifiers. [Structure 1, p46] (1) n : 0-10; R 1>, R 2>,R 3>H, 1-18C alkyl, 3-6C cycloalkyl, 2-18C alkenyl, 3-6C cycloalkenyl, 6-12C aryl optionally substituted by alkyl or aryl whereby R 1>-R 3> are optionally substituted by a carboxyl group; R 4>,R 5>H, 1-18C alkyl, 3-6C cycloalkyl, 2-18C alkenyl, 3-6C cycloalkenyl, 6-12C aryl optionally substituted by alkyl or aryl Independent claims are included for: (1) a passivating layer on a metal surface prepared by contacting the metal surface with the component (A); (2) the resulting passivated metal surface and: (3) a structure prepared by application of further coating layers onto the passivated metal surface.

    24.
    发明专利
    未知

    公开(公告)号：BRPI0514592A

    公开(公告)日：2008-06-17

    申请号：BRPI0514592

    申请日：2005-08-04

    Applicant: BASF AG

    Inventor： MICHL KATHRIN ,  GERST MATTHIAS ,  KLIPPEL FRANK ,  GOETHLICH ALEXANDER ,  DIETSCHE FRANK ,  WITTELER HELMUT ,  FAUL DIETER

    IPC: C08F220/04 ,  C08F222/02 ,  C09D133/02

    Abstract: Partially neutralized carboxylate-rich copolymers, processes for their preparation and methods of using the same are disclosed, the copolymers comprising: monomers (A), (B), and (C); wherein monomer (A) comprises at least one monoethylenically unsaturated monocarboxylic acid, and is present in an amount of 30% to 79.99% by weight; wherein monomer (B) comprises at least one monoethylenically unsaturated dicarboxylic acid selected from the group consisting of acids corresponding to general formula I, acids corresponding to general formula II, anhydrides thereof, and other hydrolyzable derivatives thereof, and is present in an amount of 20.01% to 70% by weight: (HOOC)R1C-CR2(COOH) (I) R1R2C-C(-(CH2)n-COOH)(COOH) (II) wherein R1 and R2 each independently represent H or a straight-chain or branched, optionally substituted alkyl radical having 1 to 20 carbon atoms, or, in the case of (I), R1 and R2 together being an optionally substituted alkylene radical having 3 to 20 carbon atoms, and n represents an integer from 0 to 5; wherein monomer (C) comprises at least one additional ethylenically unsaturated comonomer, and is present in an amount of 0% to 40% by weight; wherein the carboxylate-rich copolymer is partially neutralized with at least one amine and the carboxylate-rich copolymer has a degree of neutralization of 2 to 18 mol %, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids; and wherein the carboxylate-rich copolymer has an average molecular weight Mw of at least 3000 g/mol.

    POLIMEROS QUE CONTIENEN CARBOXILATO PARA EL TRATAMIENTO DE SUPERFICIES METALICAS.
    27.
    发明专利
    POLIMEROS QUE CONTIENEN CARBOXILATO PARA EL TRATAMIENTO DE SUPERFICIES METALICAS. 未知

    公开(公告)号：ES2271848T3

    公开(公告)日：2007-04-16

    申请号：ES04712509

    申请日：2004-02-19

    Applicant: BASF AG

    Inventor： DIETSCHE FRANK ,  WITTELER HELMUT ,  KLUGLEIN MATTHIAS ,  KLIPPEL FRANK

    IPC: C08L33/14 ,  B05D7/00 ,  B05D7/14 ,  C09D133/14 ,  C23C22/03 ,  C23C22/53 ,  C23C22/56

    Abstract: Composición para el tratamiento de superficies metálicas que contienen a) al menos un copolímero como componente A compuesto aa) del 50 al 99, 9% en peso de ácido (met)acrílico o sus sales, como componente Aa; ab1) del 0, 1 al 50% en peso de un monómero que contiene carboxilato de fórmula I en la que los símbolos tienen los siguientes significados: n de 0 a 10, R1, R2 y R3 independientemente entre sí, hidrógeno, alquilo de C1 a C18, que puede ser ramificado o lineal, cicloalquilo de C3 a C6, alquenilo de C2 a C18, que puede ser ramificado o lineal, cicloalquenilo de C3 a C6, arilo de C6 a C12, que puede estar sustituido con sustituyentes alquilo o arilo adicionales, pudiendo estar sustituidos los restos mencionados R1, R2 y/o R3 dado el caso con al menos un grupo carboxilo, o un grupo carboxilo; R4 y R5 son independientemente entre sí, hidrógeno, alquilo de C1 a C18, que puede ser ramificado o lineal, cicloalquilo de C3 a C6, alquenilo de C2 a C18, que puede ser ramificado o lineal, cicloalquenilo de C3 a C6, arilo de C6 a C12, que puede estar sustituido con sustituyentes alquilo o arilo adicionales; o sales, anhídridos, ésteres de compuestos de fórmula I, con la excepción de ácido (met)acrílico, con la excepción de ácido (met)acrílico o sus sales, como componente Ab1 y ab2) dado el caso del 0, 1 al 50% en peso de monómeros que presentan grupos que contienen ácido fosfórico y/o fosfónico o sus sales, como componente Ab2, que pueden polimerizarse con los monómeros mencionados en aa) y ac) así como el componente Ab1 ac) del 0 al 30% en peso de comonómeros adicionales, que pueden polimerizarse con los monómeros mencionados en aa) y ab), como componente Ac; b) agua u otro disolvente, que sea adecuado para disolver, dispersar, suspender o emulsionar el polímero (componente A), como componente B; c) dado el caso otros aditivos tensioactivos, dispersantes, agentes de suspensión y/o emulsionantes como componente C.

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