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公开(公告)号：AT330926T
公开(公告)日：2006-07-15
申请号：AT00121800
申请日：2000-10-05
Applicant: BASF AG
Inventor： KRATZ DETLEF , RUST HARALD , KROKOSZINSKI ROLAND , HELF VOLKER
IPC: C07C29/141 , C07C29/16 , C07C31/20 , C07C45/50 , C07C45/72
Abstract: Preparing at least 6C 1,3-diol comprises thermally treating a prepared at least 3C alkanal in the absence of basic catalysts, hydrating the obtained aldol addition product and recovering the product.
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公开(公告)号：DE50108323D1
公开(公告)日：2006-01-12
申请号：DE50108323
申请日：2001-06-27
Applicant: BASF AG
Inventor： RICHTER WOLFGANG , KROKOSZINSKI ROLAND , MUELLER ROLF , GEISSLER BERNHARD
Abstract: In the hydroformylation of 2-8 carbon (C) olefins (I), (a) a hydrocarbon charge is subjected to thermal and/or catalytic cracking and/or dehydrogenation; (b) the cracked gas containing olefin or a fraction is separated into streams with higher and lower (I) contents; and (c) the (I)-enriched stream, carbon monoxide and hydrogen are reacted in the presence of hydroformylation catalyst. Unreacted (I) and saturated 2-8 C hydrocarbon are separated and recycled to (b). In the production of hydroformylation products from 2-8 carbon (C) olefins (I), (a) a hydrocarbon charge is fed into a cracking/dehydrogenation zone and subjected to thermal and/or catalytic cracking and/or dehydrogenation, giving a cracked gas containing olefin; (b) the cracked gas or a fraction is separated into streams with higher and lower (I) contents; (c) the (I)-enriched stream, carbon monoxide and hydrogen are fed into a hydroformylation zone and reacted in the presence of a hydroformylation catalyst; and (d) a stream of unreacted (I) and saturated 2-8 C hydrocarbon is separated from the product stream and recycled to stage (b).
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公开(公告)号：AT283869T
公开(公告)日：2004-12-15
申请号：AT01967331
申请日：2001-09-11
Applicant: BASF AG
Inventor： ROEPER MICHAEL , BLANKERTZ HEINRICH-JOSEF , GRENACHER ARMIN VOLKER , KROKOSZINSKI ROLAND , SCHOENMANN WILLI
Abstract: Essentially monounsaturated polyalkylenes having from 30 to 700 carbon atoms are continuously hydroformylated by a process in which i) a hydroformylation-active cobalt carbonyl catalyst is prepared from a catalyst precursor dissolved in an aqueous phase in the absence of the polyalkylenes, ii) the polyalkylenes are hydroformylated by means of synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, iii) the cobalt carbonyl catalyst is separated from the output from the reaction zone with at least partial reformation of the catalyst precursor and the catalyst precursor is recirculated to step i).
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公开(公告)号：DE10201676A1
公开(公告)日：2003-07-31
申请号：DE10201676
申请日：2002-01-17
Applicant: BASF AG
Inventor： RICHTER WOLFGANG , MUELLER ROLF , KROKOSZINSKI ROLAND
Abstract: The invention relates to a hydroformylation process in which at least one olefin having from 2 to 6 carbon atoms is reacted continuously with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst in a reaction zone in which a liquid phase is present and a stream S) is taken from the liquid phase, heat is removed from this stream and the stream is subsequently returned to the reaction zone without removal of a material component.
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公开(公告)号：AU2003235702A1
公开(公告)日：2003-07-30
申请号：AU2003235702
申请日：2003-01-16
Applicant: BASF AG
Inventor： RICHTER WOLFGANG , MULLER ROLF , KROKOSZINSKI ROLAND
Abstract: The invention relates to a hydroformylation process in which at least one olefin having from 2 to 6 carbon atoms is reacted continuously with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst in a reaction zone in which a liquid phase is present and a stream S) is taken from the liquid phase, heat is removed from this stream and the stream is subsequently returned to the reaction zone without removal of a material component.
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Patent Agency Ranking
公开(公告)号：DE10128325A1
公开(公告)日：2002-02-28
申请号：DE10128325
申请日：2001-06-12
Applicant: BASF AG
Inventor： BITTERLICH STEFAN , KROKOSZINSKI ROLAND , KRATZ DETLEF , VOS HARTWIG
Abstract: Hydroformylation of 2-8C olefins comprises: (a) catalytically reacting an olefin containing saturated hydrocarbon (SHC) with CO and H2; (b) separating off a stream of unreacted olefin and SHC and contacting it with an olefin-selective membrane to give an olefin-enriched permeate and an olefin-depleted retentate; and (c) recycling at least part of the permeate back to the reaction zone.
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公开(公告)号：DE3660811D1
公开(公告)日：1988-11-03
申请号：DE3660811
申请日：1986-10-27
Applicant: BASF AG
Inventor： ENGELBACH HEINZ , KROKOSZINSKI ROLAND , FRANZISCHKA WOLFGANG , DECKER MARTIN
IPC: C07B61/00 , B01J23/22 , C07C67/00 , C07C253/00 , C07C253/28 , C07C255/50 , C07C255/51 , C07C121/56 , C07C120/14
Abstract: Aromatic nitriles, in particular phthalodinitriles, are prepared from an appropriately alkyl-substituted aromatic hydrocarbon by catalytic oxidation with oxygen or an oxygen-containing gas in the presence of ammonia at elevated temperatures in the vapor phase, in the presence of a catalyst which contains from 2 to 10% by weight of vanadium(V) oxide, from 1 to 10% by weight of antimony(III) oxide, from 0.02 to 2% by weight of an alkali metal oxide and alumina, by a process in which from 0.01 to 1.0% by weight of an alkaline earth metal, or of a compound of an alkaline earth metal, in particular barium or a barium compound, is added to the catalyst.
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公开(公告)号：ES2282631T3
公开(公告)日：2007-10-16
申请号：ES03729477
申请日：2003-01-16
Applicant: BASF AG
Inventor： RICHTER WOLFGANG , MULLER ROLF , KROKOSZINSKI ROLAND
Abstract: Procedimiento para el hidroformilado, en el que se hace reaccionar continuamente al menos una olefina con 2 a 6 átomos de carbono con monóxido de carbono e hidrógeno en presencia de un catalizador de hidroformilado en una zona de reacción, que contiene una fase líquida, y de la fase líquida se extrae una corriente S), de esta corriente se extrae calor, y a continuación se devuelve un componente material a la zona de reacción, continuando la reacción en la corriente S) al menos hasta la extracción de calor, y alimentándose a esta corriente monóxido de carbono y/o hidrógeno, antes de que la misma se empobrezca en éstos en tal medida que los componentes remanentes entren en reacciones secundarias indeseables, y/o el hidroformilado se detenga esencialmente.
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公开(公告)号：DE102005047460A1
公开(公告)日：2007-04-05
申请号：DE102005047460
申请日：2005-09-30
Applicant: BASF AG
Inventor： MAASEN SIEGMAR , KROKOSZINSKI ROLAND , KRATZ DETLEF
IPC: C02F1/26
Abstract: Treatment of wastewater from an aldolization process, containing dissolved and/or dispersed organic impurities, comprises acidifying the wastewater to pH 0-6 and extracting it with an organic liquid produced by stripping the acidified or acidified and extracted wastewater, condensing the stripped compounds and phase-separating the condensate. An independent claim is also included for treatment of wastewater from an aldolization process, containing dissolved and/or dispersed organic impurities, by acidifying the wastewater to pH 0-6, extracting it with an organic liquid and removing volatile organic impurities and a stripping apparatus, where the organic liquid is a low boiler fraction from the distillation of a crude alcohol produced by hydrogenating an aldehyde, the alcohol/aldehyde being n-butanol/n-butyraldehyde, isobutanol/isobutyraldehyde, n-pentanol/n-valeraldehyde, n- and isopentanol/n- and isovaleraldehyde, 2-ethylhexanol/2-ethylhexenal and/or 2-propylheptanol/2-propylheptenal.
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公开(公告)号：ES2254478T3
公开(公告)日：2006-06-16
申请号：ES01967099
申请日：2001-06-27
Applicant: BASF AG
Inventor： RICHTER WOLFGANG , KROKOSZINSKI ROLAND , MULLER ROLF , GEISSLER BERNHARD
Abstract: Procedimiento para la obtención de productos de hidroformilación de olefinas con 2 hasta 8 átomos de carbono, en el que a) se alimenta una materia prima hidrocarbonada en una zona de craqueo/deshidrogenación y se somete a un craqueo térmico y/o catalítico y/o a una deshidrogenación obteniéndose un gas de disociación que contiene olefinas, b) se somete al gas de disociación, o fracciones del mismo, a una separación en, al menos, una corriente hidrocarbonada enriquecida en olefina con i átomos de carbono y, al menos, una corriente hidrocarbonada empobrecida en olefina con i átomos de carbono, c) se alimenta la corriente hidrocarbonada, enriquecida en olefina con i átomos de carbono, con monóxido de carbono e hidrógeno en una zona de hidroformilación y se hace reaccionar en presencia de un catalizador para la hidroformilación, d) se separa, a partir de la descarga procedente de la zona de hidroformilación, una corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por hidrocarburo con i átomos de carbono saturado, e) se recila la corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por el hidrocarburo con i átomos de carbono saturado, al menos en parte hasta la etapa b), significando i un número entero desde 2 hasta 8.
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