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    Unbranched aldehydes - by hydroformylation of alkylenically unsatd cpds
    29.
    发明专利
    Unbranched aldehydes - by hydroformylation of alkylenically unsatd cpds 未知

    公开(公告)号：DE2139630A1

    公开(公告)日：1973-02-22

    申请号：DE2139630

    申请日：1971-08-07

    Applicant: BASF AG

    Inventor： NIENBURG HANS-JUERGEN DR ,  KUMMER RUDOLF DR ,  HOHENSCHUTZ HEINZ DR ,  STROHMEYER MAX DR ,  TAVS PETER DR

    IPC: C07C45/50 ,  C07C45/10

    Abstract: Unbranched aldehydes are made by hydroformylation of alkylenically unsatd. cpds. with 2-20 C with CO and H2 at elevated temps. and pressures in the pres. of cobalt carbonyl cpds. by (a) treating aq. soln. of cobalt salts with CO and H2 at 50-200 degrees C and 100-400 atm. in thepres. of active carbon, zeolites or basic ion exchangers charged with cobalt carbonyl, (b) in a second stage, without releasing the pressure, extracting the mixture at 20-100 degrees C and 100-400 atm. with a satd. hydrocarbon or with the unsatd. cpd. to be hydroformylated (provided this is insoluble in water and is liquid under the prevailing conditions) or with (hydrogenated) oxo reaction products is water insoluble, (c) removing the aq. phase and (d) subjecting the resulting carbonyl complex-contg. organic phase and the mixture of CO and H2 (after addition of the alkylenically unsatd. cpds. to be hydroformylated if not used in stage (b)) to hydroformylation at 70-170 degrees C and 100-400 atm. Suitable starting materials are 2-20C alkenes with terminal double bonds, alkene mixtures made by cracking waxes and polymers of ethylene, styrene, butyl, acrylate, etc. Process gives good selectivity to prodn. of unbranched aldehydes, useful in the prodn. of alkanols for washing agents and plasticisers, etc.

    Process for preparing amines
    30.
    发明专利
    Process for preparing amines 未知

    公开(公告)号：CZ292265B6

    公开(公告)日：2003-08-13

    申请号：CZ34598

    申请日：1996-08-19

    Applicant: BASF AG

    Inventor： DINGERDISSEN UWE DR ,  KUMMER RUDOLF DR ,  STOPS PETER ,  MULLER ULRICH DR ,  HERRMANN JURGEN ,  ELLER KARSTEN DR

    IPC: B01J29/86 ,  C07B61/00 ,  C07C209/60 ,  C07C211/07 ,  C07C211/35

    Abstract: In the present invention there is disclosed a process for preparing amines of the general formula I, in which the symbols Re1, Re2, Re3, Re4, Re5, and Re6 represent hydrogen, alkyl containing 1 to 20 carbon atoms, alkenyl containing 2 to 20 carbon atoms, alkynyl containing 2 to 20 carbon atoms, cycloalkyl containing 3 to 20 carbon atoms, alkylcycloalkyl containing 4 to 20 carbon atoms in the alkyl moiety, cycloalkylalkyl containing 4 to 20 carbon atoms in the cycloalkyl moiety, aryl, alkylaryl containing 7 to 20 carbon atoms in the alkyl moiety, or aralkyl containing 7 to 20 carbon atoms, or Re1 a Re2 together represent two saturated or unsaturated alkylene chains containing 3 to 9 carbon atoms and Re3 or Re5 represents alkyl containing 21 to 200 carbon atoms, alkenyl containing 21 to 200 carbon atoms, or together they represent two alkylene chains containing 2 to 12 carbon atoms, by reacting olefins of the general formula II, in which Re3, Re4, Re5 a Re6 are as specified above, with ammonia or primary or secondary amines of the general formula III wherein Re1 and Re2 are as specified above at a temperature ranging from 200 degC to 350 degC and pressure in the range of 10 to 30 MPa in the presence of boron-beta-zeolites functioning as a zeolitic catalyst.

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