公开(公告)号：DE10349343A1

公开(公告)日：2005-06-02

申请号：DE10349343

申请日：2003-10-23

Applicant: BASF AG

Inventor： PAPP RAINER ,  AHLERS WOLFGANG ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  VOLLAND MARTIN

IPC: C07C45/50 ,  C07B41/06 ,  C07B63/04 ,  B01J31/24

Abstract: The present invention relates to a process for the hydroformylation of ethylenically unsaturated compounds by reaction with carbon monoxide and hydrogen in the presence of a catalytically active fluid which comprises a dissolved metal complex of a metal of transition group VIII of the Periodic Table of the Elements with at least one phosphoramidite compound as ligand, wherein the fluid is brought into contact with a base.

公开(公告)号：BR0307813A

公开(公告)日：2004-12-21

申请号：BR0307813

申请日：2003-02-28

Applicant: BASF AG

Inventor： PESCHEL WERNER ,  ADRIAN TILL ,  RUST HARALD ,  TTCHER ARND B ,  HILLMER THOMAS ,  LLER ULRICH M ,  PAPP RAINER

IPC: C07C5/11 ,  C07B61/00 ,  C07C29/04 ,  C07C35/08 ,  C07C13/20

Abstract: A process for preparing cyclohexanol from benzene by: a) preparing cyclohexene by hydrogenating benzene in the presence of a catalyst, and b) preparing cyclohexanol by hydrating the cyclohexene in the presence of a catalyst, comprises: carrying out steps a) and b) in a reaction facility which has a bottom region at the lower end, a top region at the upper end, and a reaction zone between the top region and the bottom region which contains the catalyst according to steps a) and b), evaporating a portion of the benzene using the heat of reaction in the reaction zone, condensing it in the top region and returning it to the reaction zone, and withdrawing a reaction mixture containing cyclohexanol in the bottom region.

公开(公告)号：DE10296000D2

公开(公告)日：2004-10-28

申请号：DE10296000

申请日：2002-12-20

Applicant: BASF AG

Inventor： MACKEWITZ THOMAS ,  KNOLL KONRAD ,  VOSS HARTWIG ,  PAPP RAINER ,  PACIELLO ROCCO

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  B01J31/28 ,  C08F8/04 ,  C08F8/40 ,  C08G79/04 ,  C07C45/50 ,  C08F30/02

公开(公告)号：DE102005060784A1

公开(公告)日：2007-06-28

申请号：DE102005060784

申请日：2005-12-16

Applicant: BASF AG

Inventor： PAPP RAINER ,  VANDENMERSCH HUGUES ,  BEY OLIVER ,  ZEHNER PETER ,  VOS HARTWIG ,  MACKEWITZ THOMAS ,  PACIELLO ROCCO ,  ZELLER EDGAR

IPC: B01J31/40

Abstract: Extraction of a metal-complex catalyst enriched stream comprises dissolving e.g. reaction products and by-products, in a reaction medium by an agent containing phosphorous and/or nitrogen atoms, modified organic metal complex catalyst; distillating the catalyst free stream of the reaction discharge; separating high boiling and non-distilled components of the reaction discharge and the sump product of the distillation into a permeate- and retentate- stream and recycling the retentate stream enriched, completely or partially into the metal-complex-catalyst. Extraction of a metal-complex catalyst enriched streams, obtained from the liquid discharge of a metal complex catalyst reaction comprises dissolving reaction products, by-products, non-converted educt, solvent, homogeneous or colloid in a reaction medium by an agent containing one or more phosphorous and/or nitrogen atoms, modified organic metal complex catalyst with a molecular weight of greater than 200 D and free ligands; distillating the catalyst free stream containing low boiling components of the reaction discharge at atmospheric pressure or low pressure; separating high boiling and non-distilled components of the reaction discharge and the sump product of the distillation into a permeate- and retentate- stream, by a membrane-separator device and recycling the retentate stream enriched with the metal-complex catalyst, completely or partially into the metal-complex-catalyst.

公开(公告)号：DE10163347A1

公开(公告)日：2003-07-10

申请号：DE10163347

申请日：2001-12-21

Applicant: BASF AG

Inventor： MACKEWITZ THOMAS ,  KNOLL KONRAD ,  VOS HARTWIG ,  PAPP RAINER ,  PACIELLO ROCCO

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/24 ,  B01J31/28 ,  C08F8/04 ,  C08F8/40 ,  C08G79/04 ,  C07C45/50 ,  C07B41/06 ,  C07B43/08 ,  C07C253/10

Abstract: The invention relates to a method for the hydroformylation of compounds, comprising at least one ethylenically-unsaturated double bond, by reaction with carbon monoxide and hydrogen in the presence of a catalyst system comprising at least one metal of the VIII. sub-group of the periodic system and at least one polymeric ligand. The invention further relates to novel catalysts and the use thereof.

公开(公告)号：AU8188601A

公开(公告)日：2002-01-08

申请号：AU8188601

申请日：2001-06-25

Applicant: BASF AG

Inventor： MACKEWITZ THOMAS ,  AHLERS WOLFGANG ,  ZELLER EDGAR ,  ROPER MICHAEL ,  PACIELLO ROCCO ,  KNOLL KONRAD ,  PAPP RAINER

IPC: B01J31/24 ,  B01J31/28 ,  C07C45/50 ,  C07F9/6568 ,  C07F15/00 ,  C07F15/04 ,  C07F15/06

Abstract: The invention relates to phosphacyclohexanes of general formulae I and II, wherein the following designations, among others, apply: R can represent hydrogen, C 1-100 -alkyl, C 7-20 -aralkyl, C 7-20 -alkaryl, and C 6-12 -aryl: R 1 to R 10 can independently represent hydrogen, C 1-20 -alkyl, C 7-20 -aralkyl, C 7-20 -alkaryl, and C 6-12 -aryl: W, W' can independently represent single bonds or bridges comprising 1 to 20 carbon atoms, which can form part of a cyclic or aromatic group and can be interrupted by heteroatoms. Said phosphacyclohexanes are used as ligands in transition metal complexes of transition metals belonging to groups VIII to X of the periodic table.