28.
    发明专利
    未知

    公开(公告)号:ES2153822T3

    公开(公告)日:2001-03-16

    申请号:ES91920302

    申请日:1991-11-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP91/02166 Sec. 371 Date Apr. 29, 1993 Sec. 102(e) Date Apr. 29, 1993 PCT Filed Nov. 16, 1991 PCT Pub. No. WO92/09575 PCT Pub. Date Jun. 11, 1992.3-(3,4,5,6-tetrahydrophthalimido)cinnamic esters I I (R1=H, halogen; R2, R3=halogen; R4=C-organic radical, R5=H, CH3) are prepared by reducing 3-nitrocinnamic esters II and condensing the resulting 3-aminocinnamic esters III III with a 3,4,5,6-tetrahydrophthalic anhydride IV IV and are valuable active ingredients in crop protection.

    METHOD OF PREPARING 5-DICHLOROACETYL-3,3,6-TRIMETHYL-9-OXO-1,5-DIAZABICYCLO[4,3,0]NONANE

    公开(公告)号:HUT69060A

    公开(公告)日:1995-08-28

    申请号:HU9403409

    申请日:1993-05-18

    Applicant: BASF AG

    Abstract: The manufacture of 5-dichloroacetyl-3,3,6-trimethyl-9-oxo-1,5-diazabicyclo[4.3.0]-nonane I by the reaction of 3,3,6-trimethyl-9-oxo-1,5-diaza-bicyclo[4.3.0]nonane II with dichloroacetyl chloride in the presence of a solvent and a base, wherein a) this reaction is carried out in a two-phase system comprising a virtually water-insoluble organic solvent and water, and sodium or potassium hydroxide acting as the base is metered in at a rate corresponding to the rate of consumption of the dichloroacetyl chloride such that the aqueous phase exhibits a pH of from 7 to 9, and b) the resulting product is separated.

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