THERMALLY STABLE RIGID FOAMS BASED ON ISOCYANATE AND HAVING LOW BRITTLENESS AND LOW THERMAL CONDUCTIVITY

    公开(公告)号:CA2245291A1

    公开(公告)日:1999-03-24

    申请号:CA2245291

    申请日:1998-09-23

    Applicant: BASF AG

    Abstract: Thermally stable rigid foams based on isocyanate can be produced by reacting a) polyisocyanates with b) compounds containing at least two hydrogen atoms which can react with isocyanate groups, c) water, in the presence of d) physically acting blowing agents, in the presence or absence of e) catalysts and auxiliaries and/or additives, wherein the component b) comprises bi) at least one polyether alcohol having a functionality of at least 1.5 and a hydroxyl number of from 10 to 100 mg KOH/g in an amount of from 0.2 to 80% by mass, based on b), and bii)at least one polyester alcohol in an amount of from 5 to 90% by mass, based on b), the water c) is present in an amount of at most 2% by mass, based on the sum of the components b) to e), and the component d) used comprises hydrocarbons and/or fluorine-containing hydrocarbons in an amount of from 5 to 30% by mass, based on the sum of the components b) to e).

    PROCESS FOR PRODUCING LOW DENSITY RIGID POLYURETHANE FOAMS

    公开(公告)号:HU9800529A2

    公开(公告)日:1998-12-28

    申请号:HU9800529

    申请日:1998-03-10

    Applicant: BASF AG

    Abstract: The production of rigid polyurethane (PUR) foam with a low bulk density (I) comprises reacting (a) polyisocyanates and/or modified polyisocyanates with (b) high-mol. wt. compound(s) with at least two reactive hydrogens and optionally (c) low-mol. wt. chain-extenders and/or crosslinkers in presence of (d) blowing agents, (e) catalysts and optionally (f) other additives etc. Component (d) consists of a mixture of (d-1) cyclopentane, (d-2) at least one 3-4C alkane and/or alkene which forms a homogeneous mixture with cyclopentane and (d-3) the carbon dioxide from the reaction of water and isocyanate. Component (b) comprises aromatic nitrogen-containing polyethers.

    PRODUCCION DE ESPUMAS DE POLIURETANO RIGIDAS.

    公开(公告)号:MX9707293A

    公开(公告)日:1998-08-30

    申请号:MX9707293

    申请日:1997-09-24

    Applicant: BASF AG

    Abstract: En un proceso para producir espuma de poliuretano rígidas, que tienen resistencia mejorada a la distorsion por calor y conductividad térmica reducida, mediante la reaccion de a) poliisocianatos con b)compuestos que contienen átomos de hidrogeno reactivos con disposicion con isocianatos, en la presencia de c) agua, y, si desea, d) agentes espumantes que físicamente y e) catalizadores y auxiliares y/o aditivos conocidos, los compuestos b) que contienen átomos de hidrogeno reactivos a isocianatos, son una mezcla de poliol, que comprende b1) un poliol que se puede preparar mediante la adicion de oxido de etileno y/o oxido de propileno con un hexitol o una mezcla de hexitol, con el contenido de hexitol total de la mezcla de poliol siendo desde 15 hasta 30% en peso, en base a la mezcla de poliol, y b2) un poliol que se puede preparar mediante la adicion de oxido de etileno y/o oxido de etileno y/o oxido de propileno en una o más aminas aromáticas, con el contenido de amina total de la mezcla de poliol, siendo desde 1 hasta 10% en peso, en base a la mezcla de poliol, y la cantidad de la mezcla de poliol en el componente b) es desde 60 hasta 100 partes en masa, por 100 partes en masa del componente b).

    PRODUCTION OF RIGID POLYURETHANE FOAMS

    公开(公告)号:CA2215150A1

    公开(公告)日:1998-03-24

    申请号:CA2215150

    申请日:1997-09-23

    Applicant: BASF AG

    Abstract: In a process for producing rigid polyurethane foams having improved heat distortion resistance and reduced thermal conductivity by reacting a) polyisocyanates with b) compounds containing hydrogen atoms reactive toward isocyanates, in the presence of c) water, and, if desired, d) physically acting blowing agents and e) catalyst and known auxiliaries and/or additives, the compounds b) containing hydrogen atoms reactive toward isocyanates are a polyol mixture comprising b1) a polyol which can be prepared by addition of ethylene oxide and/or propylene oxide onto a hexitol or a hexitol mixture, with the total hexitol content of the polyol mixture being from 15 to 30 % by weight, based on the polyol mixture, and b2) a polyol which can be prepared by addition of ethylene oxide and/or propylene oxide onto one or more aromatic amines, with the total amine content of the polyol mixture being from 1 to 10 % by weight, based on the polyol mixture, and the amount of the polyol mixture in the component b) is from 60 to 100 parts by mass per 100 parts by mass of the component b).

    METODO PARA LA PRODUCCION DE ESPUMAS DE POLIURETANO RIGIDAS.

    公开(公告)号:MX2007004388A

    公开(公告)日:2007-06-07

    申请号:MX2007004388

    申请日:2005-10-12

    Applicant: BASF AG

    Abstract: La invencion se refiere a un metodo para la produccion de espumas de poliuretano rigidas por reaccion de a) poliisocianatos con b) compuestos con atomos de hidrogeno que son por lo menos reactivos con grupos isocianato en presencia de c) agentes sopladores, caracterizado porque los compuestos con atomos de hidrogeno que son por lo menos reactivos con grupos isocianato comprenden bi 1) por lo menos un alcohol de polieter iniciado con sacarosa y/o sorbitol con una funcionalidad mayor de 4 y un numero de hidroxi en la escala entre 400 y 550 mg de KOH/g, bi2) por lo menos un alcohol de polieter iniciado con TDA con un numero de hidroxi entre 120 y 240 mg de KOH/g y un contenido de aromaticos de 6.5 a 15% en peso, o un alcohol de polieter iniciado con TMP con un numero de hidroxi de 120 a 240 mg de KOH/g y, opcionalmente, bi3) por lo menos un alcohol de polieter iniciado con un alcohol bi- o trifuncional con un numero de hidroxi de 300 a 600 mg de KOH/g.

    28.
    发明专利
    未知

    公开(公告)号:DE102004051102A1

    公开(公告)日:2006-04-27

    申请号:DE102004051102

    申请日:2004-10-19

    Applicant: BASF AG

    Abstract: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least hydrogen atoms which are reactive toward isocyanate groups, in the presence of c) blowing agents, wherein the compounds having at least hydrogen atoms which are reactive toward isocyanate groups comprise bi1) at least one polyether alcohol which has been initiated by means of sucrose and/or sorbitol and has a functionality of greater than 4 and a hydroxyl number in the range from 400 to 550 mg KOH/h, bi2) at least one polyether alcohol which has been initiated by means of TDA and has a hydroxyl number in the range from 120 to 240 mg KOH/g and an aromatics content in the range from 6.5 to 15% by weight, or a polyether alcohol which has been initiated by means of TMP and has a hydroxyl number in the range from 120 to 240 mg KOH/g, and, if appropriate, bi3) at least one polyether alcohol which has been inititated by means of a bifunctional or trifunctional alcohol and has a hydroxyl number in the range from 300 to 600 mg KOH/g.

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