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公开(公告)号:AT172213T
公开(公告)日:1998-10-15
申请号:AT95926871
申请日:1995-07-13
Applicant: BASF AG
Inventor: NIESSNER MANFRED , WEISS WOLFRAM , TROPSCH JUERGEN , KUMMER MATTHIAS , MEICHSNER GEORG
IPC: C08L61/32 , C08G12/42 , C09D161/32 , C09D201/00
Abstract: PCT No. PCT/EP95/02747 Sec. 371 Date Jan. 23, 1997 Sec. 102(e) Date Jan. 23, 1997 PCT Filed Jul. 13, 1995 PCT Pub. No. WO96/03449 PCT Pub. Date Feb. 8, 1996Binders comprise A) an aminotriazine derivative in which the primary amino groups of the triazine are methylolated on average with at least one mole of formaldehyde per mole of primary amino groups, and these methylol groups are etherified on average with at least 0.5 mol of primary alcohol per mole of methylol group and the primary alcohols are a mixture containing a) 0.5-99.5 mol % of a C1-C4-alkanol and b) 99.5-0.5 mol % of an alcohol of the formulaR1-O-[R2-O]n-R3-OHI,in which R1 is C1-C24-alkyl or C6-C12-aryl which may be unsubstituted or substituted by from one to three C1-C8-alkyl groups, and R2 and R3 independently of one another are C2-C8-alkylene and n is an integer from 1 to 100, or of a mixture of higher-boiling alcohols having a boiling point of above 120 DEG C. at 1 bar which contains at least 10 mol %, based on the higher-boiling alcohols, of alcohols of the formula I, and B) a radical polymer, polycondensation product or polyadduct which is crosslinkable with the aminotriazine derivative.
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公开(公告)号:CA2199743A1
公开(公告)日:1997-09-19
申请号:CA2199743
申请日:1997-03-11
Applicant: TROPSCH JUERGEN , BREITENBACH JOERG , BASF AG
Inventor: TROPSCH JUERGEN , BREITENBACH JOERG
IPC: C08F2/18 , C08F8/06 , C08F222/04 , C08F226/06
Abstract: A process for preparing polymers comprising peroxycarboxyl groups, wherein a suspension of a polymer comprising monoolefinically unsaturated dicarboxylic anhydride basic building blocks is mixed with hydrogen peroxide in an inert diluent.
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23.
公开(公告)号:CA2195802A1
公开(公告)日:1996-02-08
申请号:CA2195802
申请日:1995-07-13
Applicant: BASF AG
Inventor: NIESSNER MANFRED , WEISS WOLFRAM , TROPSCH JUERGEN , KUMMER MATTHIAS , MEICHSNER GEORG
IPC: C08L61/32 , C08G12/42 , C09D161/32 , C09D201/00 , C07D251/00 , C07D253/00 , C09D161/28 , C08L61/28 , C08G12/30 , C08K5/3492
Abstract: The invention concerns binders containing: A) an aminotriazine derivative in which the triazine primary amino groups are methylolated on average with at least one mol of formaldehyde per mole of primary amino groups and these methylol groups are etherified on average with at least 0.5 mole primary alcohol per mole of methylol group, and the primary alcohols are a mixture containing: a) 0.5 to 99.5 mol % of a C1-C4 alkanol and b) 99.5 to 0.5 mol % of an alcohol of the formula (I) R1-O-¢R2-O!n-R3-OH, in which R1 stands for a C1-C24 alkyl group or a C6-C12 aryl group which may optionally be substituted by one to three C1-C8 alkyl groups, and R2 and R3, independently of each other, stand for a C2-C8 alkylene group, and n means an integer from 1 to 100, or a mixture of higher-boiling alcohols having a boiling point of more than 120 ~C at 1 bar, which contains at least 10 mol %, relative to the higherboiling alcohols, of alcohols of formula I; and B) a radical polymer, which can be crosslinked with the aminotriazine derivative, a polycondensate or polymer additive.
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公开(公告)号:BRPI0607908A2
公开(公告)日:2010-03-30
申请号:BRPI0607908
申请日:2006-04-05
Applicant: BASF AG
Inventor: STEPHAN JUERGEN , HEIDEMANN THOMAS , TRILLER MICHAEL , TROPSCH JUERGEN , ROEPER MICHAEL
Abstract: The present invention relates to a process for preparing polyol alkyl ethers by reacting compounds comprising at least three hydroxyl functionalities with olefins in the presence of acidic catalysts at temperatures of from 20 to 250° C. and pressures of from 0.5 to 10 bar, wherein the olefins correspond to the general formula (I) in which R1 is hydrogen and R2 is a linear or branched carbon radical having from 7 to 28 carbon atoms, or R1 and R2 are each linear or branched carbon radicals having from 1 to 27 carbon atoms, the sum of the carbon number of R1 and R2 being at most 28, to polyol alkyl ethers derived from compounds having at least three hydroxyl functionalities, not more than all but one hydroxyl functionality being replaced by a moiety of the general formula (VIII) to the use of these polyol alkyl ethers as surfactants and to laundry detergents and cleaning compositions comprising these polyol alkyl ethers.
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公开(公告)号:AT384693T
公开(公告)日:2008-02-15
申请号:AT04790431
申请日:2004-10-14
Applicant: BASF AG
Inventor: KLUMPE MARKUS , TROPSCH JUERGEN , KAHL ROLF-DIETER , BOEHN ROLAND , STUTZ SUSANNE , NOERENBERG RALF
Abstract: The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH(I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.
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公开(公告)号:BRPI0509872A
公开(公告)日:2007-10-23
申请号:BRPI0509872
申请日:2005-04-26
Applicant: BASF AG
Inventor: STEINBRENNER ULRICH , FER PAUL KLINGELH , TROPSCH JUERGEN
Abstract: The present invention relates to the use of surfactants of the general formula (I) R-O-(A)n-(B)m-H (I) where R is a C8-alkyl radical, A is propylenoxy, B is ethylenoxy, n is an average value of from 0.8 to 2.0 and m is an average value of from 2.0 to 5.0 as a wetting agent for hydrophobic polymer surfaces, and to a wetting agent comprising a) from 0.5 to 50% by weight of at least one surfactant of the general formula (I) according to claim 1, b) from 1.0 to 10% by weight of a C8-alcohol and c) from 0.5 to 30% by weight of a compound of the general formula (IV) R-O-(A)n-H (IV) where R is a C8-alkyl radical, A is propylenoxy and n is an average value of from 0.8 to 2.0.
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公开(公告)号:CA2640642A1
公开(公告)日:2007-08-30
申请号:CA2640642
申请日:2007-02-15
Applicant: BASF AG
Inventor: IYER SRIDHAR G , STEINBRENNER ULRICH , LIPPERT ERNST , KIEBURG CHRISTOFFER , BAUR RICHARD , ZIMDAHL SOEREN , DAILEY JAMES S , TROPSCH JUERGEN
Abstract: A surfactant composition includes a first surfactant, a second surfactant, and a polyalkylene glycol. The first surfactant is of the general formula R1-O-(A)mH, wherein R1 is an aliphatic hydrocarbon having 10 carbon atoms, A is an alkyleneoxy group having from 2 to 5 carbon atoms, and m is a positive number. The second surfactant is of the general formula R2-O-(B)nH, wherein R2 is an aliphatic hydrocarbon having from 12 to 14 carbon atoms, B is an alkyleneoxy group having from 2 to 5 carbon atoms, and n is a positive number. The polyalkylene glycol is present in the surfactant composition in an amount of from 3 to 20 parts by weight per 100 parts by weight of the surfactant composition.
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28.
公开(公告)号:MY129346A
公开(公告)日:2007-03-30
申请号:MYPI20001042
申请日:2000-03-17
Applicant: BASF AG
Inventor: MAAS HEIKO , ROEPER MICHAEL , WALTER MARC , SCHULZ RALF , TROPSCH JUERGEN , JAEGER HANS-ULRICH
IPC: C07F9/11 , C07H15/04 , C07B61/00 , C07C2/06 , C07C2/08 , C07C2/10 , C07C11/00 , C07C11/02 , C07C27/22 , C07C29/132 , C07C29/16 , C07C29/36 , C07C29/38 , C07C29/40 , C07C29/44 , C07C29/46 , C07C31/02 , C07C31/125 , C07C41/03 , C07C43/03 , C07C43/13 , C07C45/50 , C07C303/24 , C07C305/06 , C07C305/10 , C07F9/09 , C07H1/00 , C07H13/04 , C08B1/00 , C08B37/00 , C11D1/72
Abstract: THE INVENTION DESCRIBED A PROCESS FOR THE PREPARATION OF SURFACTANT ALCOHOLS AND SURFACTANT ALCOHOL ETHERS WHICH ARE , INTER ALIA, HIGHLY SUITABLE AS SURFACTANTS OR FOR THE PREPARATION OF SURFACTANTS. THE PROCESS, STARTING FROM OLEFIN MIXTURES HAVING A DEFINED MINIMUM CONTENT OF LINEAR HEXENES, GIVES MIXTURES HAVING A PREDOMINANT FRACTION OF BRANCHED DODECENES, WHICH ARE SUBSEQUENTLY DERIVATIZED TO GIVE SURFACTANT ALKOXYLATED.THE SURFACTANT ALCOHOL MIXTURE OBTAINED IN THE PROCESS HAS A DEGREE OF BRANCHING OF FROM 2.0 TO 3.0 AND IN PARTICULAR EXHIBITS ADVANTAGEOUS PROPERTIES AS REGARDS ECOTOXICITY AND BIODEGRADABILITY.A DESCRIPTION IS ALSO GIVEN OF THE USE OF THE SURFACTANT ALCOHOLS AND SURFACTANT ALCOHOL ETHERS AS SURFACTANTS BY GLYCOAIDATION OR POLYGLYCOSIDATION, SULFATION OR PHOSPHATION.
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29.
公开(公告)号:CA2620240A1
公开(公告)日:2007-03-08
申请号:CA2620240
申请日:2006-08-28
Applicant: BASF AG
Inventor: SEEBECK TANJA , TROPSCH JUERGEN , KISSAU LARS
Abstract: The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers o f a1) 50 to 93 mol% acrylic acid and/or of a water-soluble salt of acrylic aci d, a2) 5 to 30 mol% of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol% of at least one nonionic monomer of th e formula (I), b) 1 to 50% by weight of complexing agents chosen from the grou p consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N- diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonion ic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of components a) to g) is 100% by weight.
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公开(公告)号:DE102005041349A1
公开(公告)日:2007-03-01
申请号:DE102005041349
申请日:2005-08-31
Applicant: BASF AG
Inventor: SEEBECK TANJA , TROPSCH JUERGEN , KISSAU LARS
IPC: C11D3/37
Abstract: Phosphate-free cleaning formulation for dishwasher, comprises: (a) copolymers from monoethylenic unsaturated monocarboxylic acids; (b) a complexing agent from e.g. nitrilotriacetic acid; (C) weak foaming nonionic surfactant, (D) a bleaching agent and optionally a bleach activator; (e) a further builder; (f) enzyme; and (g) a further additives e.g. anionic or zwitterionic surfactant and bleaching catalyst. Phosphate-free cleaning formulation for dishwasher, comprises: (a) 1-20 wt.% of copolymers from (a1) 50-99.5 mol.% of a monoethylenic unsaturated monocarboxylic acid and/or its salt, (a2) 0.5-20 mol.% of an alkoxylated monoethylenic unsaturated monomer (I) of formula (CH 2=C(R1)-R2-[R3-O] n-R4), (a3) 0-50 mol.% of a monoethylenic unsaturated dicarboxylic acid, an anhydride and/or its salt and (a4) 0-20 mol.% of an another copolymerizable monoethylenic unsaturated monomer, where the copolymer exhibits an average molecular weight of 30000-500000 g/mol and a K-value of 40-150, measured at the pH of 7 in 1 wt.% aqueous solution at 25[deg]C; (b) 1-50 wt.% of complexing agent from nitrilotriacetic acid, ethyl diaminetetra acetic acid, diethyletriaminepentaacetic acid, hydroxyethylethyldiaminetriacetic acid and glycine-N, N-diacetic acid and its derivative, glutamic acid-N,N-diacetic acid, iminodisuccinate, hydroxyiminodisuccinate, S,S-ethyldiaminedisuccinate and asparaginic acid diacetic acid and the salts of the aforementioned substances; (C) 1-15 wt.% of weak foaming nonionic surfactant, (D) 0.1-30 wt.% of a bleaching agent and optionally a bleach activator; (e) 0-60 wt.% of a further builder; (f) 0-8 wt.% of enzyme; and (g) 0-50 wt.% of a further additives like anionic or zwitterionic surfactant, bleaching catalyst, alkali carrier, corrosion inhibitors, antifoaming agents, coloring materials, perfumes, fillers, organic solvents and water. An independent claim is included for a powder mixture or a granulate mixture for the cleaning formulations of the dishwasher, comprising: 30-95 wt.% of the copolymers from (a1), (a2) and optionally (a3) and (a4); (b) 5-70 wt.% of complexing agent; and (C) 0-20 wt.% of polyethylene glycol and/or nonionic surfactant. R1 : H or CH 3; R2 : -(CH 2) x-O-, -CH 2-NR5, -CH 2-O-CH 2-CR6R7-CH 2-O or -CONH; R3 : 2-4C-alkylene that can be arranged as block wise or static manner, where the portion of ethylene amounts to at least 50 mol.%; R4 : H, 1-4C-alkyl, -SO 3M or -PO 3M 2; R5 : H or -CH 2-CR1=CH 2; R6 : -O-[R3-O] n-R4, where the -[R3-O] n of the R6 is different compared to the [R3-O] n of (I); R7 : H or ethyl; M : alkali metal or H; n : 4-250; and x : 0 or 1.
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