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公开(公告)号:AU5360998A
公开(公告)日:1998-06-22
申请号:AU5360998
申请日:1997-11-18
Applicant: CLOROX CO
Inventor: ALVAREZ VICENT E , DELINE JAMES E , FOLAND LAFAYETTE D , KAARET THOMAS W , PETRIN MICHAEL J , SMITH WILLIAM L , SUDBURY BARRY A , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C01B3/00 , C11D7/38 , C07D265/12 , C07D211/26 , C07D211/34
Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
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公开(公告)号:AU5265198A
公开(公告)日:1998-06-22
申请号:AU5265198
申请日:1997-11-18
Applicant: CLOROX CO
Inventor: ANNEN ULRICH , DELINE JAMES E , KLOTTER KEVIN A , MULLER MICHAEL , MUNDINGER KLAUS , PERKINS SARAH A , PHILLIPPI MARTIN A , SCHOLTISSEK MARTIN , SCHONHERR MICHAEL , SMITH WILLIAM L , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/39 , C11D3/395 , D06L3/02 , D06L4/12 , C07D265/30 , C07D295/12 , C07D211/26 , C07D211/34 , C01B3/00 , C11D7/38
Abstract: A substantially solid composition, the composition having therein a compound with the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure.
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公开(公告)号:CA2273088A1
公开(公告)日:1998-06-04
申请号:CA2273088
申请日:1997-11-18
Inventor: ANNEN ULRICH , PHILLIPPI MARTIN A , SCHOLTISSEK MARTIN , PERKINS SARAH A , DELINE JAMES E , MUNDINGER KLAUS , SMITH WILLIAM L , ZIELSKE ALFRED G , SCHONHERR MICHAEL , KLOTTER KEVIN A , MULLER MICHAEL
IPC: C07D295/14 , C07D295/15 , C11D3/39 , C11D3/395 , D06L3/02 , D06L4/12 , C07D265/30 , C01B3/00 , C07D295/12 , C07D211/26 , C07D211/34 , C11D7/38
Abstract: A substantially solid composition, the composition having therein a compound with the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure.
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公开(公告)号:MX221944B
公开(公告)日:2004-08-04
申请号:MX9905078
申请日:1999-05-31
Inventor: ANNEN ULRICH , DELINE JAMES E , KLOTTER KEVIN A , MUELLER MICHAEL , MUNDINGER KLAUS , PERKINS SARAH A , PHILLIPPI MARTIN A , SCHOLTISSEK MARTIN , SCHOENHERR MICHAEL , SMITH WILLIAM L , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/39 , C11D3/395 , D06L3/02 , D06L4/12
Abstract: A substantially solid composition, the composition having therein a compound with the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure.
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公开(公告)号:AT250046T
公开(公告)日:2003-10-15
申请号:AT96917033
申请日:1996-06-03
Applicant: CLOROX CO
Inventor: ARBOGAST JAMES W , DELINE JAMES E , FOLAND LAFAYETTE , KAARET THOMAS W , KLOTTER KEVIN A , PETRIN MICHAEL J , SMITH WILLIAM L , ZIELSKE ALRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C11D1/58 , C11D1/62
Abstract: Bleaching compositions are provided that comprise two nitrile groups where each nitrile is bonded to a quaternary nitrogen through a methylene unit. The quaternary nitrogens are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitriles for bleaching applications.
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公开(公告)号:AT236138T
公开(公告)日:2003-04-15
申请号:AT97948371
申请日:1997-11-18
Inventor: ANNEN ULRICH , DELINE JAMES E , FOLAND LAFAYETTE D , KLOTTER KEVIN A , MUELLER JOSEF , MUELLER MICHAEL , MUENDINGER KLAUS , PHILLIPPI MARTIN A , RULAND ALFRED , SCHAEFER WOLFGANG , SCHUERMANN GREGOR , WIDDER RUDI , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D265/12 , C07D291/00 , C07D295/15 , C11D3/39 , C07D295/12 , C07D211/26 , C07D211/34
Abstract: A process for the preparation of a compound having the structure of Formula (I) wherein A, R1, R2, R3, Y and Z are as defined in the disclosure. The process includes reacting a heterocyclic amine with a monoaldehyde or a dialdehyde in a pH range of from about 8 to 14 and then quaternizing the so-reacted heterocyclic amine with an alkylating agent at a pH of not less than about 2. The use of a pH control substantially prevents formation of an undesirable protonated intermediate.
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公开(公告)号:AU746352B2
公开(公告)日:2002-04-18
申请号:AU5360998
申请日:1997-11-18
Applicant: CLOROX CO
Inventor: ALVAREZ VICENT E , DELINE JAMES E , FOLAND LAFAYETTE D , KAARET THOMAS W , PETRIN MICHAEL J , SMITH WILLIAM L , SUDBURY BARRY A , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C01B3/00 , C11D7/38 , C07D265/12 , C07D211/26 , C07D211/34
Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
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公开(公告)号:CO5040177A1
公开(公告)日:2001-05-29
申请号:CO97069847
申请日:1997-11-28
Inventor: ULRICH ANNEN , DELINE JAMES E , KLOTTER KEVIN A , MULLER MICHAEL , KLAUS MUNDINGER , PERKINS SARAH A , PHILLIPPI MARTIN A , SCHOLTISSEK MARTIN , SCHONHERR MICHAEL , SMITH WILLIAM L , ZIELSKE ALFRED G
IPC: C07D295/14 , C07C255/03 , C07D295/15 , C11D3/39 , C11D3/395 , D06L3/02 , D06L4/12
Abstract: Una composición substancialmente sólida, lacomposición tiene allí un compuesto con la estructura de la Fórmula I en donde A es un anillo saturado formado por una pluralidad de átomos además del átomo de N1 , los átomos del anillo saturado incluyendo, por lo menos, un átomo de carbono y por lo menos uno de los átomos de 0, S, y N, el R1 substituyente enlazado al átomo N1 de la estructura de la Fórmula I incluyendo, ya sea, (a) un alquilo C1-24 o alquilalcoxilatado en donde el alcoxi es C2-4 , (b) un cicloalquilo C4-24 , (c) un alcarilo C7-24 , (d) un alcoxi o alcohol alcoxilado repetido o no repetido en el que la unidad de alcoxi es C2-4 , o (e) -CR2 R3 CºN, donde los sustitutos R2 y R3 es cada uno H, un alquilo C1-24 , cicloalquilo o alcarilo, o un alcoxilo o alcohol alcoxilado repetido o no repetido donde la unidad de alcoxi es C2-4 , Z es un valor en el rango de 0 a 10, e Y es monovalente o multivalente y es sulfato, bisulfato, tosilato, o mezclas de sulfato y bisulfato, como contraión.La composición de sal como en la reivindicación 27, estando en forma de gránulos.
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公开(公告)号:PH11997058671B1
公开(公告)日:2000-12-04
申请号:PH11997058671
申请日:1997-11-28
Applicant: CLOROX CO
Inventor: ALVAREZ VICENT E , DELINE JAMES E , FOLAND LAFAYETTE D , KAARET THOMAS W , PETRIN MICHAEL J , SMITH WILLIAM L , SUDBURY BARRY A , ZIELSKE ALFRED G
IPC: C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06
Abstract: Preferred embodiments of the invention are heterocyclic cationic activators with the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is an anionic peracid activator. When these are dissolved in an aqueous solution in the presence of an active oxygen source, coactivation will occur for improved bleaching.
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公开(公告)号:BR9713986A
公开(公告)日:2000-10-31
申请号:BR9713986
申请日:1997-11-18
Inventor: CASELA VICTOR M , ULRICH BRUCKEL , CHOY CLEMENT K , DELINE JAMES E , FOLAND LAFAYETTE D , HUESTIS SUSAN P , KLOTTER KEVIN A , PERKINS SARAH A , PETERSON DAVID , PETRIN MICHAEL J , PHILLIPPI MARTIN A , SIBERT WILLIAM P , SCHONHERR MICHAEL , SEELMAN-EGGEBERT HANS PETER , SMITH WILLIAM L , ZIELSKE ALFRED G , KAARET THOMAS W
IPC: C07D295/14 , C07D295/15 , C11D3/12 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/06 , D06L3/02 , H04B7/06 , C01B3/00 , C11D7/38 , B29C67/00 , B29C59/00 , D04H1/64 , C07D265/12 , C07D295/12 , C07D295/26 , C07D211/26 , C07D211/34
Abstract: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of Formula I FORMULA I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) -CR2R3C 3BOND N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is a counterion. The salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, aluminum silicate, or mixtures thereof.
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