公开(公告)号：DE59905973D1

公开(公告)日：2003-07-24

申请号：DE59905973

申请日：1999-03-06

Applicant: DEGUSSA

Inventor： MACK DR ,  BARFURTH DIETER ,  EDELMANN ROLAND ,  FRINGS DR ,  HORN DR ,  JENKNER DR ,  LAVEN DR ,  MONKIEWICZ DR ,  STANDKE DR

IPC: C08K9/06 ,  C09C1/02 ,  C09C1/28 ,  C09C1/30 ,  C09C1/36 ,  C09C1/40 ,  C09C3/12 ,  C09J11/06

公开(公告)号：DE59909944D1

公开(公告)日：2004-08-19

申请号：DE59909944

申请日：1999-09-22

Applicant: DEGUSSA

Inventor： MACK DR ,  BARFURTH DIETER ,  EDELMANN ROLAND ,  FRINGS DR ,  HORN DR ,  JENKNER DR ,  LAVEN DR ,  MONKIEWICZ DR ,  STANDKE DR

IPC: C09K3/10 ,  C07F7/21 ,  C08G77/04 ,  C08G77/26 ,  C08L83/08 ,  C08L83/14 ,  C09D183/08 ,  C09D183/14 ,  C09J183/08 ,  C09J183/14

Abstract: Mixtures of linear and cyclic amino-functional siloxane oligomers containing: (i) 3-aminopropyl, N-(2-aminoethyl)-3-aminopropyl or N'-(2-aminoethyl)-N-(2-aminoethyl)-3-aminopropyl groups; (ii) optional alkoxy groups; and (iii) (cyclo)alkyl, alkenyl or aryl groups. Mixtures of chain-type and cyclic siloxane oligomers of formula (I) and (II): R = (i) groups of formula -(CH2)3-NH2, -(CH2)3-NHR', -(CH2)3-NH-(CH2)2-NH2 or -(CH2)3-NH-(CH2)2-NH-(CH2)2-NH2, with not more than one aminopropyl-functional group of this type attached to a silicon atom, (ii) methoxy, ethoxy, 2-methoxyethoxy and/or propoxy groups, with a silicon/alkoxy group mol ratio of at least 0.5 and optionally (iii) 1-18C alkyl, alkenyl, iso-alkyl or cycloalkyl, or 6-12C aryl; R' = linear, branched or cyclic 1-18C alkyl, or 6-12C aryl; m = more than 2 and less than 30; n = 3-30 An Independent claim is also included for a process for the production of these mixtures from mixtures of: (A) aminopropyl-functional trialkoxy- or methyldialkoxy-silanes; optionally (B) 1-18C alkyl-, alkenyl-, isoalkyl- or cycloalkyl-trialkoxysilanes and/or phenyl-trialkoxysilanes and/or corresponding methyldialkoxy silanes; and optionally (C) a tetra-alkoxysilane, by hydrolysis and condensation (in succession or as a mixture) at 10-95 degrees C with 0.6-1.2 mols water per 1 mol silicon and 0.1-5 times the weight of methanol or ethanol (based on alkoxysilanes), followed by distillation of alcohol at up to 120 degrees C under normal or reduced pressure.

公开(公告)号：DE59510492D1

公开(公告)日：2003-01-16

申请号：DE59510492

申请日：1995-10-12

Applicant: DEGUSSA

Inventor： STANDKE DR ,  FLIEDNER DR ,  FRINGS DR ,  HORN DR ,  KOETSZCH DR ,  MONKIEWICZ DR ,  SREBNY DR

IPC: C08L83/08 ,  C08G77/26 ,  C08G77/28 ,  C08L83/04 ,  C09D183/08 ,  C09K23/54

Abstract: Water-based, organopolysiloxane-contg. compsns. (A) are essentially free from organic solvent, have a flash pt. of more than 80 degrees C and generate no alcohol by hydrolysis when diluted with water. Also claimed is a process for the prodn. of compsns. (A).

公开(公告)号：DE59509258D1

公开(公告)日：2001-06-21

申请号：DE59509258

申请日：1995-09-01

Applicant: DEGUSSA

Inventor： KROPFGANS DR ,  FRINGS DR ,  HORN DR ,  KOETZSCH DR ,  MONKIEWICZ DR ,  SEILER DR ,  SREBNY DR ,  STANDKE DR

IPC: C07F7/18

Abstract: Prepn of 3-(pseudo)haloalkyl-silane esters of formula (I) comprises catalysed reaction of unsatd aliphatic cpds contg a reactive allyl (pseudo)halide gp and terminal double bond, of formula (II), with a hydridosilane ester of formula (III) in the presence of gp. VIII element and/or cpd. The novel features are that (a) a 0.1-0.0001 N soln or suspension of Ir and/or Ir cpds is prepd by stirring for at least 20 min with (II) alone or a mixt of (II) and (III) contg an excess of 0.01-100, pref 0.1-10 mole% (II) and opt in 5-95 wt% soln in inert solvents, eg hydrocarbons and/or (I); and (b) hydrosilylation is carried out with this at a catalyst concn of 10 - 10 mole%. R = 1-18C (halo)alkyl or (halo)cycloalkyl; R = R or H; R , R = R, H, aryl or halogen; R = 1-10C alkyl, opt contg aliphatic ether gps; X = F, Cl, Br, I, CN, NCO, NCS or N3; n = 0, 1 or 2.

公开(公告)号：DE59509204D1

公开(公告)日：2001-05-23

申请号：DE59509204

申请日：1995-08-24

Applicant: DEGUSSA

Inventor： STANDKE DR ,  ALBERT DR ,  HORN DR ,  KOETZSCH DR ,  KROPFGANS DR ,  MONKIEWICZ DR ,  SEILER DR ,  SREBNY DR

IPC: B01J27/122 ,  C07B61/00 ,  C07F7/02 ,  C07F7/04

Abstract: In the prepn of hydridoalkoxysilanes of formula (I) by direct reaction of metallic Si with alcohols with addn of suitable catalysts contg Cu, reaction is carried out with finely-divided Si and alcohol (mixt) in a heat carrier oil of opt substd tritoluene and/or tetratoluene at 100-350 degrees C. HnSi(O(CH2)mCH3)4-n (I) n = 1, 2 or 3; m = 0, 1 or 2.

公开(公告)号：DE59701107D1

公开(公告)日：2000-03-16

申请号：DE59701107

申请日：1997-10-11

Applicant: DEGUSSA

Inventor： JENKNER DR ,  FRINGS DR ,  HORN DR ,  JUST ECKHARD ,  MONKIEWICZ JAROSLAW ,  STANDKE DR

IPC: C08L83/08 ,  C03C25/40 ,  C08G77/24 ,  C09D183/08 ,  C09K3/18 ,  D06M13/513 ,  D06M15/657 ,  D21H19/32 ,  D21H21/16

Abstract: Alcohol-based, fluoroalkyl-functional organosiloxane-containing compositions are obtained by hydrolysis of fluoroalkyl- organosilanes of formula R -Y-(CH2)2SiHx(R )y(OR)3-x-y (I), where R, R = linear, branched or cyclic 1-8C alkyl, or aryl; R = mono-, oligo- or per- fluorinated 1-9C alkyl or aryl; Y = CH2, O or S; x, y = 0, 1 or 2; and x+y = not more than 2. The reaction is carried out for 0.5-24 hours at 0-120 degrees C with good stirring in an alcoholic medium containing water together with a weak mono- or poly-basic acid and/or a weak base or an acid or basic salt, with a molar ratio of water:(I) = (2-500):1. Also claimed is the above process for the production of these compositions.