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公开(公告)号:DE58902753D1
公开(公告)日:1992-12-24
申请号:DE58902753
申请日:1989-08-08
Applicant: HOECHST AG
Inventor: HEMMERLING WOLFGANG DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , ILLIAN GERHARD DR , INOGUCHI YOSHIO DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: G02F1/13 , C07D307/24 , C07D307/56 , C07D405/12 , C07D405/14 , C07D407/12 , C07D407/14 , C07D409/12 , C07D409/14 , C07D417/12 , C07D417/14 , C09K19/54 , C09K19/58 , G02F1/137 , G02F1/141
Abstract: Optically active tetrahydrofuran-2-carboxylic acid esters containing a mesogenic molecular building block are suitable as dopes in liquid-crystal mixtures. They result in liquid-crystalline ferroelectric phases having short switching times and in electroclinic phases having high electroclinic coefficients. A further advantage is that they induce a helix of very low pitch, so they are also suitable for helix compensation in LC mixtures. The compounds are symbolised by the general formula in which the symbols and indices essentially have the following meanings: R = alkyl/alkenyl or tetrahydrofurancarbonyloxy or -thio; j, l and n = zero, 1 or 2; k and m = zero or 1; -A , -A and -A = phenylene, cycloalkylene or corresponding N-, O- or S-containing heterocycles; -M and -M = bridges, such as -CO-O-, -OCH2- or -CH=CH-; and X = O or S.
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公开(公告)号:DE3917472A1
公开(公告)日:1990-12-06
申请号:DE3917472
申请日:1989-05-30
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , ILLIAN GERD DR , MURAKAMI MIKIO , OHLENDORF DIETER DR
IPC: G02F1/1333 , G02F1/1335 , G02F1/1362 , G02F1/137 , G02F1/141
Abstract: PCT No. PCT/EP90/00761 Sec. 371 Date Nov. 27, 1991 Sec. 102(e) Date Nov. 27, 1991 PCT Filed May 11, 1990 PCT Pub. No. WO90/15360 PCT Pub. Date Dec. 13, 1990.A ferroelectric liquid crystal switching or display device, in which the liquid crystal film has a constant thickness, wherein one of the glass sheets in the device is planar and the other glass sheet has at least one step. The switching or display device of the present invention does not require shortened switching times or more contacts or drivers and does not show unwanted switching.
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公开(公告)号:DE3909356A1
公开(公告)日:1990-09-27
申请号:DE3909356
申请日:1989-03-22
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HARADA TAKAMASA , HEMMERLING WOLFGANG DR , ILLIAN GERHARD DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
Abstract: PCT No. PCT/EP90/00458 Sec. 371 Date Nov. 6, 1991 Sec. 102(e) Date Nov. 6, 1991 PCT Filed Mar. 21, 1990 PCT Pub. No. WO90/11336 PCT Pub. Date Oct. 4, 1990.The novel liquid-crystalline mixtures (in the case of ferroelectric behavior they additionally contain an optically active compound as dope) are based on at least two mixture components of the general formula (I) and at least one carboxylate of the general formula (II), (III) or (IV). (* CHEMICAL STRUCTURE *) (I) (* CHEMICAL STRUCTURE *) (II) X = O or a single bond (* CHEMICAL STRUCTURE *) (III) (* CHEMICAL STRUCTURE *) (IV) The mixtures have favorable properties for use in electrooptical display elements, such as high contrast, low melting point and short switching times.
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公开(公告)号:DE3824902A1
公开(公告)日:1990-02-15
申请号:DE3824902
申请日:1988-07-22
Applicant: HOECHST AG
Inventor: SCHEROWSKY G PROF DR , GAY JUERGEN , WINGEN RAINER DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , INOGUCHI YOSHIO DR , MUELLER INGRID DR , OHLENDORF DIETER DR
IPC: G02F1/13 , C07D317/22 , C07D317/24 , C07D317/36 , C07D317/72 , C07D405/12 , C07D405/14 , C07D407/12 , C07D409/12 , C07D409/14 , C07D417/12 , C07D417/14 , C09K19/34 , C09K19/54 , C09K19/58 , G02F1/137 , G02F1/33
Abstract: Optically active 1,3-dioxolane derivates of the general formula which carry a mesogenic radical in the 4-position are suitable as dopes in - in particular ferroelectric - liquid-crystal mixtures. The symbols in the general formula have the following meanings: R has a structure analogous to the moiety of the general formula on the right of X or is an alkyl or alkylene radical, which may be substituted, R , R and R are H or alkyl (R is alternatively alkenyl), which may also be substituted [R and R , together with the C(2) of the dioxolane ring, may alternatively be cycloaliphatic or keto groups], j, l and n are zero, 1 or 2, and k and m are zero or 1, with the proviso that n is zero if k is zero, m is zero if n is zero, and 1 , -A and -A are an aromatic, heterocyclic or aliphatic ring system, -M and -M are -CO-O, -O-CO, -CH2CH2, -CH=CH, -CH2O, -OCH2 or -C IDENTICAL C and X is O, S or O-CO-O. The particular advantage of the compounds of the general formula (I) is that they are able to induce a high twisting power in the cholesteric phase, but without significantly affecting the magnitude of the spontaneous polarisation already present in the mixture in the smectic C phase. They are therefore suitable for pitch compensation, in particular for ferroelectric liquid-crystal mixtures.
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公开(公告)号:DE3839330A1
公开(公告)日:1989-06-08
申请号:DE3839330
申请日:1988-11-22
Applicant: HOECHST AG
Inventor: MEIJERE ARMIN DE PROF DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , MUELLER INGRID DR , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: C07D20060101 , C07D213/30 , C07D237/08 , C07D237/10 , C07D237/14 , C07D239/26 , C07D239/32 , C07D239/34 , C07D239/38 , C07D241/12 , C07D285/12 , C07D303/48 , C07D317/10 , C07D405/12 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , G02F1/137 , G02F1/141
Abstract: The novel cyclopropylalkyl- or -alkenyl-heterocycles of the formula are liquid-crystalline. In this formula, the symbols A , A and A are aromatic or heteroaromatic moieties, such as 1,4-phenylene or pyrimidine-2,5-diyl, which are linked via a single bond (where k and m = zero) or via functional groups M and M , such as CO-O or CH2-O; j, k, l, m and n are zero or 1 (j + l + n = 2 or 3). The radicals R , R and R are H or alkyl/alkenyl, R is alkyl/alkenyl or a substituent known from LC chemistry, such as an alpha -haloalkanoic acid radical. In addition, at least one of the units A , A and A must be heteroaromatic, G is alkylene or alkenylene.
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公开(公告)号:DE3475514D1
公开(公告)日:1989-01-12
申请号:DE3475514
申请日:1984-12-18
Applicant: HOECHST AG
IPC: C09K3/00 , C07C53/126 , C07C53/15 , C07C53/21 , C07C65/10 , C07C65/11 , C07C67/00 , C07C209/00 , C07C211/63 , C07C213/00 , C07C217/08 , C07C231/00 , C07C233/36 , C07C301/00 , C07C311/01 , C07C311/02 , C07C313/00 , C07C323/25 , C07D213/04 , C07D213/20 , C07D213/26 , F15D1/06 , C07C87/30 , C07C91/26 , C07C103/54 , C07C143/02 , C07C143/74 , C07C149/24
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公开(公告)号:DE3703228A1
公开(公告)日:1988-08-18
申请号:DE3703228
申请日:1987-02-04
Applicant: HOECHST AG
Inventor: MUELLER INGRID DR , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: C07C69/035 , C07D239/26 , C07D239/34 , C07D239/38 , C09K19/20 , C09K19/22 , C09K19/34 , C07C69/92 , C07D317/32 , C07D339/08 , G09F9/35
Abstract: The novel compounds are chiral esters made from alpha -substituted carboxylic acids and mesogenic hydroxyl compounds which are characterised by the formula (I) in which the symbols have the following meanings: MO is the moiety of a mesogenic hydroxyl compound MOH after removal of an H, where the radical MO is expressed by the formula (II> R - (A )n1 - (B-)n2(A )n3 - O (II> where R is straight-chain or branched (C1-C12)alkyl or alkenyl, where one or two non-adjacent CH2 groups can be replaced by O and/or S atoms, or, if n1 = 1, is alternatively F, Cl, Br or CN, A and A , independently of one another, are 1,4-phenylene, pyrimidine-2,5-diyl, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,3-dithian-2,5-diyl or 1,4-bicyclo[2.2.2]octylene, where these groups may also be at least monosubstituted by F, Cl, Br, CN and/or (C1-C12)alkyl (one or two non-adjacent CH2 groups are optionally replaced by O and/or S atoms), B is CO-O, O-CO, CH2-CH2, OCH2, CH2O, CH = N, N = CH, N = N or N(O) = N, and n1, n2 and n3, independently of one another, are 0, 1 or 2, where n1 and n3 are not simultaneously 0, Y is F, Cl, Br, CN or CF3, and R is branched (C3-C9)alkyl, benzyl or phenyl, where the compounds where R = branched (C3-C7)alkyl, benzyl or phenyl, Y = F, Cl or Br, R = (C1-C11)alkoxy, A and A = phenyl, n1, n3 = 1 and n2 ... Original abstract incomplete.
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公开(公告)号:DE3336198A1
公开(公告)日:1985-04-25
申请号:DE3336198
申请日:1983-10-05
Applicant: HOECHST AG
Inventor: OHLENDORF DIETER DR , WESTER NORBERT DR
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公开(公告)号:DE3224148A1
公开(公告)日:1983-12-29
申请号:DE3224148
申请日:1982-06-29
Applicant: HOECHST AG
Inventor: OHLENDORF DIETER DR , HOFFMANN HEINZ PROF DR , INTERTHAL WERNER DR DR , PINTSCHOVIUS ULRICH DR
IPC: C07C51/00 , C07C51/41 , C07C63/04 , C07C63/70 , C07C65/00 , C07C65/01 , C07C65/03 , C07C65/05 , C07C65/10 , C07C65/11 , C07C65/21 , C07C67/00 , C07C201/00 , C07C205/59 , C07C209/00 , C07C209/14 , C07C211/62 , C07C211/63 , C07C213/10 , C07C301/00 , C07C303/32 , C07C309/01 , C07C309/04 , C07C309/20 , C07C309/43 , C07D213/04 , C07D213/20 , C09K3/00 , C10M133/06 , C10M133/40 , C10M173/00 , C10N20/00 , C10N30/00 , F17D1/16 , C07C143/02 , C07C87/30 , C07C143/48
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公开(公告)号:AT117996T
公开(公告)日:1995-02-15
申请号:AT88710048
申请日:1988-11-22
Applicant: HOECHST AG
Inventor: DE MEIJERE ARMIN PROF DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , MUELLER INGRID DR , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: C07D20060101 , C07D213/30 , C07D237/08 , C07D237/10 , C07D237/14 , C07D239/26 , C07D239/32 , C07D239/34 , C07D239/38 , C07D241/12 , C07D285/12 , C07D303/48 , C07D317/10 , C07D405/12 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , G02F1/137 , G02F1/141
Abstract: The liquid crystalline cyclopropylalkyl or -alkenyl heterocycles have the formula in which the symbols A , A , A are aromatic or heteroaromatic molecular building blocks, such as 1,4-phenylene or pyrimidin-2,5-diyl which are linked via a single bond (if k,m are zero) or via functional groups M , M , such as CO-O or CH2-O; j, k, l, m, n are zero or 1 (j+l+n = 2 or 3). The radicals R , R , R are H or alkyl/alkenyl, R is alkyl/alkenyl or one of the substituents known from LC chemistry, such as an alpha -haloalkanoic radical. In addition, at least one of the building blocks A , A , A must be heteroaromatic and G denotes alkylene or alkenylene.
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