Abstract:
PURPOSE: A biosensor for detecting heavy metal is provided to detect a subject heavy metal with high sensitivity. CONSTITUTION: A biosensor for detecting heavy metal comprises: a substrate; and one or more demetalated metalloprotein placed on the substrate. The biosensor contains alkane compound having thiol group (SH-) at one end and a carboxyl group(COOH-) at the other end. The biosensor further comprises a self-assembled monolayer between the substrate and metal protein. The subject heavy meal is copper ion.
Abstract:
PURPOSE: A fast image scanning method for the operation of an atomic force microscope under liquid conditions is provided to minimize image distortion without an additional device. CONSTITUTION: A force applied to a cantilever is the sum of squeeze-film effects(Fsc) and drag force(Fd) made from intrinsic features of fluid while the cantilever approaches a surface in z-direction. The force applied to the cantilever during sample surface analysis is the sum of a divided force in y axis direction, coquette flow(Fc) generated during scan in y axis direction, and a frictional force(Ff) during surface scanning of a tip of a cantilever end.
Abstract:
PURPOSE: A manufacturing method of a catalyst and a manufacturing method of propanediol using the same are provided to produce propanediol from glycerol with high yield at a low temperature and pressure condition. CONSTITUTION: A manufacturing method of a catalyst includes the following steps: preparing a metal precursor solution by dissolving a metal precursor in a solvent; preparing a support containing metals dipped in the metal oxide by agitating and mixing the metal oxide in the metal precursor solution; removing the solvent; pulverizing and drying the support containing the metal; and calcinating the support containing the metal. The manufacturing method of the catalyst further includes a step for reducing the catalyst to increase catalytic activity. The metal of the metal precursor is ruthenium, platinum, rhodium or palladium.
Abstract:
The present invention provides a complex oxide catalyst having cylindrical regular mesopores and excellent acid characteristics and a manufacturing method thereof. A complex oxide catalyst according to the concrete example of the present invention includes tungsten oxide, zirconium oxide, and silicon oxide. The atomic fraction of the tungsten and the silicon is 0.1/1-0.14/1, and the atomic fraction of the zirconium and the silicon is 0.1/1-0.14/1. Moreover, the present invention provides a method for effectively manufacturing a high-value ester compound from ethanol and a carboxylic acid compound using the complex oxide catalyst. [Reference numerals] (AA) Example 1;(BB) Example 2;(CC) Example 3;(DD) Comparative example 2;(EE) Comparative example 3
Abstract:
PURPOSE: Provided are an aluminosilicate sphere nano particle, a manufacturing method thereof, and a method for acrylic acid using the same, wherein the aluminosilicate sphere nano particle can easily transfer a reactant to the inside of a pore, minimize material transfer resistance, and have wide specific surface area while maintaining an acid characteristic of the aluminosilicate. CONSTITUTION: An aluminosilicate sphere nano particle has an open pore structure in a form wherein the size of the particle increases in a direction in which the radius of the particle increases from the center of the particle. The specific surface area of the nano particle is at least 100 m^2/g. The manufacturing method of the aluminosilicate sphere nano particle comprises the steps of: performing a first hydrothermal process on a solution including a silica precursor, a polar solvent, a non-polar solvent, an ionic surfactant and an alkaline compound in a pressure vessel; controlling the pH of the first hydrothermal process treated solution to 2-7 using an acidic aqueous solution; inserting an aluminum precursor into a pH-controlled solution; and performing a second hydrothermal process on the solution into which aluminum precuesor is inserted in the pressure vessel.
Abstract:
PURPOSE: A high sensitivity heavy metal detecting sensor using the plasmon resonance of a center-satellite nano structure and a detecting method thereof are provided to amplify a plasmon resonance phenomenon, thereby detecting a trace amount of heavy metal existing in a solution at high sensitivity. CONSTITUTION: A high sensitivity heavy metal detecting sensor using the plasmon resonance of a center-satellite nano structure comprises a supporter(10), a first metal nano particle(20), and a second metal nano particle(30). The first metal nano particle is arranged on the supporter and surface-polished by a first compound(24) including a first functional group(22). The second metal nano particle is surface-polished by a second compound(34) including a second functional group(32). The second metal nano particle is arranged around the first metal nano particle by joining the first and second groups, thereby inducing a plasmonic resonance.