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公开(公告)号：KR1020050055275A
公开(公告)日：2005-06-13
申请号：KR1020030088349
申请日：2003-12-06
Applicant: 한국화학연구원
IPC: C08G61/00
CPC classification number: C09D5/1662 , C08G8/10 , C12P7/00 , C12P7/22
Abstract: 본 발명은 페노티아진계 전달물질을 이용한 페놀계 고분자의 제조방법에 관한 것으로서, 더욱 상세하게는 퍼록시데이즈 생촉매와 산화제 존재 하에서 페놀계 단량체를 중합함에 있어 페노티아진계 전달물질을 추가로 사용하여 퍼록시데이즈의 효소 반응성을 개선시키는 페놀계 고분자의 제조방법에 관한 것이다.
본 발명의 중합방법으로 제조된 페놀계 고분자는 곁 사슬로 결합된 불포화 탄화수소기가 그대로 보존되어 있어 라디칼 경화반응이 용이하므로 경화수지로서 유용하게 사용될 수 있고, 또한 상기 경화수지가 포함된 도료가 코팅된 도막은 항산화능이 우수하고, 도막의 표면 에너지가 작아서 물리적인 해양생물의 부착을 저해하며, 방오작용기의 소모가 발생되지 않아 지속적으로 내구성을 발현하게 된다.-
公开(公告)号：KR1020030035636A
公开(公告)日：2003-05-09
申请号：KR1020010067888
申请日：2001-11-01
Applicant: 한국화학연구원
IPC: C12P19/00
Abstract: PURPOSE: A method for producing saccharides from waste sludge generated from the paper process is provided, thereby producing saccharides useful for microorganisms, and decreasing environmental pollution caused by the waste sludge of paper. CONSTITUTION: A method for producing saccharides from waste sludge generated from the paper process comprises the steps of: mixing the waste sludge of paper under following conditions: the temperature of 50 deg. C; the flow rate of 105 l/min; and the air flow rate of 15 l/min to separate small particles and powder; and treating the separated small particles and powder with hydrolase or acid catalysts, wherein the hydrolase is one or two selected from cellulase, amylase, xylase and hemicellulase and is added in an amount of 0.01 to 0.1 wt.%; and the acid catalyst is selected from sulfuric acid, hydrochloric acid, and nitric acid and is added in an amount of 0.01 to 0.1 wt.%.
Abstract translation: 目的：提供从造纸工艺生产的废污泥生产糖类的方法，从而生产有用的微生物糖，减少纸废物污染造成的环境污染。 构成：从纸张处理产生的废污泥生产糖的方法包括以下步骤：在以下条件下混合纸的废污泥：温度为50℃。 C; 流量105 l / min; 空气流速15 l / min，分离小颗粒和粉末; 用水解酶或酸催化剂处理分离的小颗粒和粉末，其中水解酶是选自纤维素酶，淀粉酶，淀粉酶和半纤维素酶中的一种或两种，并且以0.01至0.1重量％的量加入; 酸催化剂选自硫酸，盐酸和硝酸，其添加量为0.01〜0.1重量％。
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公开(公告)号：KR1020110013726A
公开(公告)日：2011-02-10
申请号：KR1020090071330
申请日：2009-08-03
Applicant: 한국화학연구원
IPC: C07K14/00
Abstract: PURPOSE: A thermally stable CiP(Coprinus cinereus peroxidase) mutant protein and a DNA encoding the same are provided to ensure high thermal stability and to be used in various industries. CONSTITUTION: A thermally stable CiP(Coprinus cinereus peroxidase) mutant protein has 323th amino acid of sequence number 1, in which serine is substituted with tyrosine; 328th amino acid in which glutamic acid is substituted with aspartic acid; or both thereof. A DNA encoding CiP mutant protein has 967-969th bases of sequence number 5, which are substituted with a codon encoding tyrosine and has a base sequence of sequence number 6.
Abstract translation: 目的：提供热稳定的CiP（鬼马菌过氧化物酶）突变蛋白和编码它的DNA，以确保高热稳定性并用于各种行业。 构成：热稳定的CiP（鬼马菌过氧化物酶）突变蛋白具有序列号1的323位氨基酸，其中丝氨酸被酪氨酸取代; 谷氨酸被天冬氨酸取代的第328位氨基酸; 或其两者。 编码CiP突变蛋白的DNA具有序列号5的967-969位碱基，其被编码酪氨酸的密码子取代并具有序列号6的碱基序列。
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公开(公告)号：KR1020090128276A
公开(公告)日：2009-12-15
申请号：KR1020080054358
申请日：2008-06-10
Applicant: 한국화학연구원
Abstract: PURPOSE: A bio sensor and a manufacturing method thereof are provided to fix metal nano-particle using a non-covalent binding mode without destroying covalent bond between carbons of the carbon nano-tube. CONSTITUTION: A manufacturing method with a metal immobilized carbon nano-tube comprises following steps. A carbon nano-tube transistor including source electrode, drain electrode, and gate and carbon nano-tube(30) is manufactured. In the carbon nano-tube transistor, all electrodes except for the carbon nano-tube are insulated. The insulated carbon nano-tube transistor is put into solution with metallic ion and fixes the metal nano-particle on the surface of the carbon nano-tube.
Abstract translation: 目的：提供生物传感器及其制造方法，以使用非共价结合模式固定金属纳米颗粒，而不破坏碳纳米管的碳之间的共价键。 构成：具有金属固定碳纳米管的制造方法包括以下步骤。 制造包括源电极，漏电极和栅极和碳纳米管（30）的碳纳米管晶体管。 在碳纳米管晶体管中，除了碳纳米管之外的所有电极是绝缘的。 将绝缘碳纳米管晶体管放入金属离子溶液中，并将金属纳米颗粒固定在碳纳米管表面。
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公开(公告)号：KR1020090095892A
公开(公告)日：2009-09-10
申请号：KR1020080021115
申请日：2008-03-06
Applicant: 한국화학연구원
IPC: C07C29/147 , C07C31/02
CPC classification number: C07C29/149 , B01J23/626 , B01J23/6567 , B01J23/8966 , B01J37/0009 , B01J37/031 , B01J37/10 , B01J37/18 , B01J2523/00 , C07C31/12 , B01J2523/27 , B01J2523/43 , B01J2523/821 , B01J2523/74 , B01J2523/828 , B01J2523/845 , B01J2523/17 , B01J2523/47 , B01J2523/41
Abstract: A method for manufacturing a monovalent alcohol is provided to improve selectivity and space yield even under the mild reaction condition by using a catalyst having excellent thermal stability, chemical stability and reaction activity. A method for manufacturing a monovalent alcohol comprises the step of direct gas phase reducing a C1~C10 monocarboxylic acid or its derivative by hydrogen on a catalyst represented by Ru(a)Sn(b)Zn(d)Ox, wherein (a), (b) and (d) are a component ratio based on an atomic number, and (a) is 1~20 and (b) is 1~40 if (d) is 100; and x is an atomic number of oxygen and is determined according to the valence and composition ratio of other components. The catalyst is plasticized at 300~800 °C under the air atmosphere.
Abstract translation: 提供一价醇的制造方法，通过使用具有优异的热稳定性，化学稳定性和反应活性的催化剂，即使在温和的反应条件下也能提高选择性和空间收率。 一价醇的制造方法包括在由Ru（a）Sn（b）Zn（d）Ox表示的催化剂上直接气相还原C1〜C10一元羧酸或其衍生物的工序，其中（a）， （b）和（d）是基于原子序数的成分比例，（a）如果（d）为100，（a）为1〜20，（b）为1〜40; x是氧的原子数，根据其他成分的化合价和成分比来确定。 催化剂在空气气氛下在300〜800℃下塑化。
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Patent Agency Ranking
公开(公告)号：KR1020080082858A
公开(公告)日：2008-09-12
申请号：KR1020070023706
申请日：2007-03-09
CPC classification number: C12Q1/04 , G01N27/30 , G01N33/5438 , G01N33/56911
Abstract: A microorganism detecting sensor is provided to estimate existence and concentration of E. coli in a sample simply without requiring any complicated laboratory facilities or equipments or any necessary conditions for culturing. A sensor for detecting microorganism comprises: a carbon nano-tube transistor array including a channel region consisting of a metal source electrode(12), a metal drain electrode(14), a gate(16) and a carbon nano-tube(18); an aptamer(20) which is absorption-modified into the carbon nano-tube, thereby being specifically bonded to microorganism(24); and a fixation material which fixates the aptamer on the carbon nanotube. A method for detecting microorganism comprises the steps of: (a) preparing a plurality of diluted solutions of the microorganisms having different diluted concentrations; (b) precipitating the aptamer of the microorganism detecting sensor having the carbon nanotube transistor in the microorganism diluted solutions; (c) measuring electroconductivity of the carbon nanotube transistor; and (d) after providing 0(on) or 1(off) in accordance with change of the electroconductivity value, estimating the microorganism concentration through an MPN table. Further, the channel region consisting of the carbon nano-tube consists of single wall nano-tube or multi wall nano-tube.
Abstract translation: 提供微生物检测传感器，以简单地估计样品中大肠杆菌的存在和浓度，而不需要任何复杂的实验室设施或设备或任何必要的培养条件。 一种用于检测微生物的传感器，包括：碳纳米管晶体管阵列，包括由金属源电极（12），金属漏电极（14），栅极（16）和碳纳米管（18）组成的沟道区， ; （20），其被吸收改性为碳纳米管，从而特异性地结合到微生物（24）上; 以及将适体固定在碳纳米管上的固定材料。 检测微生物的方法包括以下步骤：（a）制备具有不同稀释浓度的多种稀释的微生物溶液; （b）在微生物稀释溶液中沉淀具有碳纳米管晶体管的微生物检测传感器的适体; （c）测量碳纳米管晶体管的导电性; 和（d）根据电导率值的变化提供0（on）或1（off）之后，通过MPN表估计微生物浓度。 此外，由碳纳米管组成的通道区域由单壁纳米管或多壁纳米管组成。
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公开(公告)号：KR100597682B1
公开(公告)日：2006-07-07
申请号：KR1020040103608
申请日：2004-12-09
Applicant: 한국화학연구원
CPC classification number: C08G65/38 , B01J31/04 , B01J2531/72 , B01J2531/845 , C08G65/44
Abstract: 본 발명은 코프리너스 시네레우스 유래 퍼옥시다아제를 이용한 페놀계 고분자의 제조방법에 관한 것으로서, 더욱 상세하게는 페놀 단량체 중합시 유독성의 포르말린 사용이 필수적인 통상의 퍼옥시다아제와 가격이 매우 고가이고 과산화수소에 의하여 쉽게 불활성화되는 식물체 유래 퍼옥시다아제 대신에, 코프리너스 시네레우스 유래 퍼옥시다아제를 이용하여 페놀계 단량체를 극성 유기용매 내에서 온화한 반응조건(상온, 상압) 하에서 중합시킴으로써 수율이 증대되고, 경제적이며, 내수성, 내화학성이 뛰어난 페놀계 고분자를 제조하는 방법에 관한 것이다.
퍼옥시다아제, 페놀계 고분자, 코프리너스 시네레우스-
公开(公告)号：KR100535950B1
公开(公告)日：2005-12-09
申请号：KR1020030051034
申请日：2003-07-24
Applicant: 한국화학연구원
IPC: C08G61/00
Abstract: 본 발명은 생촉매를 이용한 페놀계 중합체의 제조방법 및 그의 용도에 관한 것으로서, 보다 상세하게는 식물에서 유래한 페놀계 단량체를 생촉매인 산화환원 효소의 작용으로 유기용매 내에서 중합시킴으로써 효과적으로 페놀계 중합체를 제조하며, 이를 경화시킨 후 방오도료에 적용할 경우 상기 방오도료를 코팅하여 형성된 페놀계 고분자 코팅 도막의 표면 에너지가 작아서 물리적인 해양생물의 부착을 저해하고, 또한, 방오작용기의 소모가 발생되지 않아 지속적으로 내구성을 발현하는 화학적 방오작용이 우수한 특성을 나타내는 생촉매를 이용한 페놀계 중합체의 제조방법 및 그의 용도에 관한 것이다.
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公开(公告)号：KR100493713B1
公开(公告)日：2005-06-03
申请号：KR1020010066230
申请日：2001-10-26
Applicant: 한국화학연구원
Abstract: 본 발명은 수중오염물질을 제거 처리하기 위한 고정화 이산화티탄 광촉매의 제조방법에 관한 것으로서, 더욱 상세하게는 나노크기의 이산화티탄 분말을 수중에서 음이온성 분산제로 분산안정화시키고, 이를 중공형 또는 다공성의 무기담체에 실리콘계 또는 알루미나계 바인더로 부착시켜 만든 고정화된 이산화티탄 광촉매의 제조방법에 관한 것이다. 상기의 방법으로 제조된 광촉매를 수처리장치에 적용함으로써 광촉매를 회수하기 위한 별도의 분리장치가 필요없고, 동시에 광촉매의 분산으로 인한 균일한 광조사 효과를 얻을 수 있어 경제적이면서도 대용량으로 확장이 용이하다.
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公开(公告)号：KR1020040094496A
公开(公告)日：2004-11-10
申请号：KR1020030028284
申请日：2003-05-02
Applicant: 한국화학연구원
IPC: C02F1/72
Abstract: PURPOSE: To provide a superior photocatalyst which can be reused by adding boracic acid and sodium ethoxide, thereby improving immobilization force of titanium dioxide and media, a water treatment apparatus for further improving efficiency of the photocatalyst by easily discharging purified treated water, and a water treatment method using the photocatalyst. CONSTITUTION: In a water treatment apparatus comprising a hollow reactor (10) having a certain volume, a raw water inflow pump (22) for flowing raw water in the reactor, and a transfer pump (26) for transferring treated water from the reactor, the water treatment apparatus using immobilized photocatalyst comprises a cylindrical rotary screen (12) vertically arranged in a central part inside the reactor in such a way that the rotary screen is rotated; vanes (18) attached to upper and lower end parts of the rotary screen; a variable motor (20) connected to a hollow rotary shaft by pulley and belt to provide the rotary screen with rotary force, wherein the hollow rotary shaft is integrally attached to an upper part of the rotary screen; a plurality of ultraviolet lamps (14) vertically arranged between the inner wall of the reactor and the rotary screen; and a pair of air lift pumps (16) communicatingly connected to the reactor, wherein the treated water is transferred by the transfer pump as the treated water is passing through the hollow rotary shaft in an upper part of the rotary screen from the rotary screen.
Abstract translation: 目的：提供一种可以通过添加硼酸和乙醇钠重新使用的优异的光催化剂，从而提高二氧化钛和介质的固定力，一种水处理设备，用于通过容易地排出经过净化的水，进一步提高光催化剂的效率，以及水 使用光催化剂的处理方法。 构成：在具有一定体积的中空反应器（10）的水处理装置中，将用于使反应器内的原水流动的原水流入泵（22）和从反应器输送处理水的输送泵（26） 使用固定化光催化剂的水处理装置包括垂直设置在反应器内的中心部分的圆筒形旋转筛（12），使得旋转筛旋转; 安装在旋转筛的上端部和下端部的叶片（18） 一个可变马达（20），其通过皮带轮和皮带带连接到空心旋转轴上，以向旋转屏幕提供旋转力，其中空心旋转轴一体地附接到旋转筛的上部; 垂直设置在反应器的内壁和旋转筛之间的多个紫外线灯（14）; 以及一对与反应器连通的空气提升泵（16），其中处理过的水在旋转筛网的上部通过旋转筛网的上部的中空旋转轴时，经处理后的水被转移。
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