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公开(公告)号:CA2496884A1
公开(公告)日:2004-03-18
申请号:CA2496884
申请日:2003-08-29
Applicant: BASF AG
Inventor: GEPRAEGS MICHAEL
IPC: F21S8/10 , C08K3/00 , C08K3/34 , C08K5/00 , C08L67/00 , C08L67/02 , C08L101/12 , F21W101/10
Abstract: The invention relates to thermoplastic moulding masses comprising: A) 10 to 89.9 wt. % of a thermoplastic polyester with a viscosity number (VZ) of at least 145 ml/g, B) 10 to 89.99 wt. % of a thermoplastic polyester with a viscosity number (VZ) of at most 135 ml/g, C) 0.01 to 5 wt. % of at least on e nucleation agent, D) 0 to 5 wt. % of at least one lubricant and E) 0 to 70 w t. % of further additives, whereby the sum of the weight percentages of components A) to E) = 100 %.
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公开(公告)号:DE19959252A1
公开(公告)日:2001-06-13
申请号:DE19959252
申请日:1999-12-09
Applicant: BASF AG
Inventor: GEPRAEGS MICHAEL , QUEISSER JOACHIM , OKUDA JUN , HULTZSCH KAI CARSTEN , BECKERLE KLAUS
IPC: C08F4/52 , C08F12/00 , C08F12/04 , C08J5/00 , C08F297/06 , C08F4/44 , C08F10/00 , C08F297/00
Abstract: The invention relates to a method for carrying out the transition metal-catalyzed production of polymers having a syndiotactic or predominantly syndiotactic structure from vinyl aromatic monomers. The invention also relates to a method for producing block copolymers from vinyl aromatic monomers and from olefinically unsaturated polar monomers. According to the invention, transition metal compounds of general formula (I) are used in which the substituents and indices have the following meanings: M represents scandium, yttrium, lanthanum or a lanthanoid metal; R''' represents pi -C3 to C20 alkyl; L represents a low-molecular, Lewis-basic organic compound, whereby n1 and n2 = 0 or n1 = 0 and n2 = 1 or n1 = 1 and n2 = 0, and; m represents 1 or 2.
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公开(公告)号:DE19933383A1
公开(公告)日:2001-01-25
申请号:DE19933383
申请日:1999-07-21
Applicant: BASF AG
Inventor: QUEISSER JOACHIM , GEPRAEGS MICHAEL , RIEGER BERNHARD , HUHN WOLFGANG
Abstract: A process for the production of linear, alternating carbon monoxide copolymers (I) comprises copolymerization of a 2-20C olefinically unsaturated compound (II) and carbon monoxide in the presence of a metal complex of formula whereby a further 2-20C olefinically unsaturated compound that is different to the first compound is added during the reaction in at least two separate doses. A process for the production of linear, alternating carbon monoxide copolymers (I) comprises copolymerization of a 2-20C olefinically unsaturated compound (II) and carbon monoxide in the presence of: (A) a metal complex of formula (1); (B) optionally a protonic or Lewis acid; and (C) optionally a hydroxy compound whereby a further 2-20C olefinically unsaturated compound (III) that is different to the compound (II) is added during the reaction in at least two separate doses. Independent claims are included for: (i) the resulting carbon monoxide copolymer (I); (ii) fiber , film or molded articles containing the copolymer (I). G = 5-7 membered carbocyclic ring, optionally containing heteroatoms; -(CRb2)r-, -(CRb2)s-Si(Ra)2-(CRb2)t, -A-O-B- or -A-Z(R )-B-; R = H, 1-28C alkyl, 3-14C cycloalkyl, 6-15C aryl or alkylaryl having 1-20C alkyl and 6-15C aryl, -N(Rb)2 or -S(Ra)3, optionally substituted; A, B = (CRb2)t-, -(CRb2)s-Si(Ra)2-(CRb2)t, -N(Rb)-, a r'-, S- or t- atom containing component of a ring system or together with Z forms a (r'+1)-, (s+1)- or (t+1)- atoms containing component of a heterocycle; Rn = 1-20C alkyl, 3-10C cycloalkyl, 6-15C aryl or alkylaryl having 1-10C alkyl and 6-15C aryl, optionally substituted; RbRa = H or Si(Ra)3; r = 1-4; r' = 1 or 2; s,t = 0-2; s+t = 1-3; Z = a Group 14 element; M = a Group 8-12 element; R -R = 1-28C alkyl, 3-14C cycloalkyl, 6-15C aryl or alkylaryl with 1-28C alkyl and 6-15C aryl, optionally substituted; L , L = neutral or charged ligand; X = mono- or multivalent anion; m, n, p = 0-3; p = m \* n
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公开(公告)号:DE19927347A1
公开(公告)日:2000-12-21
申请号:DE19927347
申请日:1999-06-16
Applicant: BASF AG
Inventor: MUELHAUPT ROLF , HEINEMANN JOHANNES , BAUMERT MARTIN , QUEISSER JOACHIM , GEPRAEGS MICHAEL
IPC: C08F4/80 , C08F210/02 , C08F255/00 , C08F255/02 , C08F265/00 , C08F271/00 , C08F283/00 , C08F290/06 , C08F291/00 , C08L51/06 , C08F4/60
Abstract: The invention relates to a method for producing graft copolymers, containing an elastic copolymer backbone. In a first stage of said method, a) ethene, as the principal monomer, is copolymerised co-ordinatively with an alpha -olefin which is substituted with an alkoxyamine group as the additional comonomer in the presence of a transition metal compound which has been complexed using a bisimin chelate ligand, into an elastomeric graft copolymer backbone. In a second stage b) the copolymer produced in a) is reacted under controlled radical polymerisation conditions in the presence of monomers, selected from the group of vinyl aromatic compounds, vinyl heteroaromatic or vinyl heteroalicyclic compounds, alkyl esters, and amides of (meth)acryl acid, acryl nitrile, methacryl nitrile, maleimide or vinyl ferrocene and optionally also reacted in the presence of conjugated organic dienes, involving the formation of covalently linked graft branches. In a further stage c) the graft copolymer obtained in b) is either directly isolated, or the alkoxyamine groups which terminate the graft polymer lateral branches are first removed under reductive reaction conditions and the graft polymer thus obtained is subsequently isolated.
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公开(公告)号:DE19926778A1
公开(公告)日:2000-12-14
申请号:DE19926778
申请日:1999-06-11
Applicant: BASF AG
Inventor: QUEISSER JOACHIM , GEPRAEGS MICHAEL , ERBES JOERG , BAUMERT MARTIN , MUELHAUPT ROLF
IPC: C08F28/00 , C08G75/22 , C08F228/00
Abstract: The invention relates to a method for the production of polysulphon with an aliphatic main chain, wherein a) sulphur dioxide and b) a vinyl aromatic compound and c) an unsaturated compound are reacted by means of d) radical polymerization in a mass or a solution e) at temperatures ranging from -80 DEG C to -150 DEG C, f) optionally using a radical chain initiator as a catalyst.
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公开(公告)号:DE19829519A1
公开(公告)日:2000-01-05
申请号:DE19829519
申请日:1998-07-02
Applicant: BASF AG
Inventor: QUEISSER JOACHIM , SLANY MICHAEL , GEPRAEGS MICHAEL , LINDNER EKKEHARD , SCHMID MARKUS , WALD JOACHIM , WEGNER PETER
Abstract: The invention relates to water-soluble transition metal complexes of the general formula (I), in which the rests R to R are linear or branched C2-C28 alkyl substituted by at least one polar functional group which is ionic or has a protonic action and based on elements of groups IVA to VIA of the periodic table, C3-C14 cycloalkyl or alkyl aryl with between 1 and 28 C-atoms in the alkyl part and between 6 and 15 C-atoms in the aryl part.
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公开(公告)号:DE19820716A1
公开(公告)日:1999-11-18
申请号:DE19820716
申请日:1998-05-11
Applicant: BASF AG
Inventor: GEPRAEGS MICHAEL , QUEISSER JOACHIM , RIEGER BERNHARD , MOELLER MARTIN , HUHN WOLFGANG , VOS SICCO DE
IPC: C08L23/14 , C08L25/12 , C08L73/00 , C08J3/20 , C08J5/00 , C08J5/18 , C08L23/02 , C08L33/00 , D01F6/20
Abstract: Carbon monoxide/ alpha -olefin copolymer mixture, with a wider range of polymers in the mixture, contains copolymers of vinyl aromatic compounds and vinyl cyanide polymer mixture. Polymer mixture comprises carbon monoxide/ alpha -olefin copolymers (A) and copolymers (B) of vinyl aromatic compounds and vinyl cyanides. Independent claims are included for: (i) the preparation of the above polymer mixture by mixing the components at 150-270 deg C; and for (ii) molded articles, fibers, films and coatings prepared from the mixture.
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公开(公告)号:ZA9707594B
公开(公告)日:1999-02-25
申请号:ZA9707594
申请日:1997-08-25
Applicant: BASF AG
Inventor: WUENSCH JOSEF , GEPRAEGS MICHAEL
IPC: C08J5/18 , C07F7/28 , C08F2/00 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/645 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F212/02 , C08F212/04 , C08F212/34 , C08F230/04 , C08F297/02 , D01F6/28 , C08F , C08J , D01F
CPC classification number: C08F297/02 , C07F7/28 , C08F4/659 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F212/04 , C08F212/08 , C08F212/14 , C08F212/32 , C08F212/34
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公开(公告)号:DE50210717D1
公开(公告)日:2007-09-27
申请号:DE50210717
申请日:2002-07-03
Applicant: BASF AG
Inventor: GEPRAEGS MICHAEL
IPC: C08J3/22 , C08L67/02 , C08K3/22 , C08K3/32 , C08K7/02 , C08L23/02 , C08L27/18 , D01F6/92 , H05K1/03
Abstract: Thermoplastic molding compositions comprising A) from 10 to 97% by weight of at least one polyester a1) other than polyethylene terephthalate (PET), which comprises, based on 100% by weight of A), from 1 to 50% by weight of PET a2), B) from 1 to 30% by weight of a flame retardant combination made from, based on 100% by weight of B), b1) from 20 to 99% by weight of a halogen-containing flame retardant, and b2) from 1 to 80% by weight of an antimony oxide, C) from 0.01 to 5% by weight of KH2PO4 or LiH2PO4, or a mixture of these D) from 0.01 to 3% by weight of an antidrop agent, and E) from 0 to 70% by weight of other additives, where the total of the percentages by weight of components A) to E) is 100%.
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