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公开(公告)号:ES2181347T3
公开(公告)日:2003-02-16
申请号:ES99117240
申请日:1999-09-02
Applicant: BASF AG
Inventor: MAYWALD VOLKER DR , HARTMANN HORST , GOTZ NORBERT DR , REISSENWEBER GERNOT DR , KONIG HARTMANN DR
IPC: C07D307/33 , C07D407/04
Abstract: Separation of impurities from 3-(2'-acetoxyethyl)-dihydro-2(3H)-furanone (I) obtained by acetylation of 3-(2'-hydroxyethyl)-dihydro-2(3H)-furanone comprises first separating high boiling impurities and subjecting the recovered distillation head product to a further step in which light and medium boiling components are taken off at the head and recovering pure (I) as the sump product.
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公开(公告)号:AT214383T
公开(公告)日:2002-03-15
申请号:AT98962407
申请日:1998-12-02
Applicant: BASF AG
Inventor: MAYWALD VOLKER , GOETZ NORBERT , KUEKENHOEHNER THOMAS , BORCHERS DIRK , KOENIG HARTMANN , HARTMANN HORST , WAGNER RUPERT
IPC: C07D307/32 , C07D307/33 , C07D407/04
Abstract: A process for removing impurities from 3-(2'-acetoxyethyl)-dihydro-2(3H)-furanone (I), which comprises initially preparing the 3-(2'-acetoxyethyl)-dihydro-2(3H)-furanone containing the undesirable impurities in a manner known per se by acetylating 3-(2'-hydroxylethyl)-dihydro-2(3H)-furanone, subsequently treating it with strong mineral acids and finally removing the decomposition products of the undesirable impurities from I.
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公开(公告)号:CZ20002026A3
公开(公告)日:2000-09-13
申请号:CZ20002026
申请日:1998-12-02
Applicant: BASF AG
Inventor: MAYWALD VOLKER , GOETZ NORBERT , KUEKENHOEHNER THOMAS , BORCHERS DIRK , KOENIG HARTMANN , HARTMANN HORST , WAGNER RUPERT
IPC: C07D307/33
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公开(公告)号:PT788475E
公开(公告)日:2000-04-28
申请号:PT95917966
申请日:1995-04-26
Applicant: BASF AG
Inventor: ALBRECHT HARREUS DR , HARTMANN HORST , NORBERT GOTZ DR , HARALD RANG DR , HEIMANN FRANK , BORCHERS DIRK , MAYWALD VOLKER , BUSCHULTE THOMAS
IPC: B01J23/02 , B01J31/02 , C07B61/00 , C07C239/20 , C07C249/12 , C07C251/54 , C07C309/66
Abstract: PCT No. PCT/EP95/01581 Sec. 371 Date Nov. 4, 1996 Sec. 102(e) Date Nov. 4, 1996 PCT Filed Apr. 26, 1995 PCT Pub. No. WO95/30648 PCT Pub. Date Nov. 16, 1995Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib (Ia): H2NOCH2CH(R1)OAr (Ib): H2NOCH(R1)CH2OAr and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb (IIa): (III): into a mixture of sulfonates IVa and IVb (IVa): (IVb): b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb (VIa): (VIb): c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.
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公开(公告)号:CA2311426A1
公开(公告)日:1999-06-17
申请号:CA2311426
申请日:1998-12-02
Applicant: BASF AG
Inventor: WAGNER RUPERT , HARTMANN HORST , KONIG HARTMANN , GOTZ NORBERT , MAYWALD VOLKER , KUKENHOHNER THOMAS , BORCHERS DIRK
IPC: C07D307/32 , C07D307/33 , C07D407/04
Abstract: The invention relates to a method for separating contaminants from 3-(2'-acetoxy-ethyl-dihydro-2(3H)furanone (I), whereby the 3-(2'-acetoxy-ethyl-dihydro-2(3H)furanone containing the undesired contaminants is first produced using known methods by acetylization of 3-(2'-hydroxy-ethyl-dihydro-2(3H)furanone and is subsequently treated with strong mineral acids. Finally, the decomposition products of the undesired contaminants of (I) are separated.
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公开(公告)号:PL175612B1
公开(公告)日:1999-01-29
申请号:PL30057893
申请日:1993-10-04
Applicant: BASF AG
Inventor: KLEIN ULRICH , BUSCHMANN ERNST , KEIL MICHAEL , GOETZ NORBERT , HARTMANN HORST
IPC: C07C239/20 , C07C217/06
Abstract: O-Substituted hydroxylammonium salts are prepared by hydrolysis of acetone oxime ethers with acid in the presence of an additive and removal of acetone and water by distillation with the aid of the additive.
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公开(公告)号:HU214693B
公开(公告)日:1998-04-28
申请号:HU9603054
申请日:1995-04-26
Applicant: BASF AG
Inventor: BORCHERS DIRK , BUSCHULTE THOMAS , GOETZ NORBERT , HARREUS ALBRECHT , HARTMANN HORST , HEIMANN FRANK , MAYWALD VOLKER , RANG HARALD
IPC: B01J23/02 , B01J31/02 , C07B61/00 , C07C239/20 , C07C249/12 , C07C251/54 , C07C309/66
Abstract: PCT No. PCT/EP95/01581 Sec. 371 Date Nov. 4, 1996 Sec. 102(e) Date Nov. 4, 1996 PCT Filed Apr. 26, 1995 PCT Pub. No. WO95/30648 PCT Pub. Date Nov. 16, 1995Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib (Ia): H2NOCH2CH(R1)OAr (Ib): H2NOCH(R1)CH2OAr and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb (IIa): (III): into a mixture of sulfonates IVa and IVb (IVa): (IVb): b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb (VIa): (VIb): c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.
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公开(公告)号:BR9508498A
公开(公告)日:1997-12-30
申请号:BR9508498
申请日:1995-07-28
Applicant: BASF AG
Inventor: HARREUS ALBRECHT , GOETZ NORBERT , RANG HARALD , HARTMANN HORST , MOHR JURGEN , GEHRER EUGEN , LAUTH GUNTER
IPC: B01J31/02 , C07B61/00 , C07C249/12 , C07C251/38 , C07C251/44 , C07C251/54
Abstract: Preparation of O-(2-hydroxyalkyl) oximes of formula (I), (R and R are alkyl or R and R and the common C atom are 5-membered to 7-membered cycloalkyl; R is alkyl) by causing a ketoxime II to react with an olefin oxide III in the presence of a tertiary amine or with a carbonate IV in the presence of a catalyst. The end products (I) are suitable for use as intermediates for crop protection agents.
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公开(公告)号:BR9507611A
公开(公告)日:1997-08-19
申请号:BR9507611
申请日:1995-04-26
Applicant: BASF AG
Inventor: RANG HARALD , GOETZ NORBERT , HARREUS ALBRECHT , BORCHERS DIRK , HARTMANN HORST , MAYWALD VOLKER , HEIMANN FRANK , BUSCHULTE THOMAS
IPC: B01J23/02 , B01J31/02 , C07B61/00 , C07C239/20 , C07C249/12 , C07C251/54 , C07C309/66
Abstract: PCT No. PCT/EP95/01581 Sec. 371 Date Nov. 4, 1996 Sec. 102(e) Date Nov. 4, 1996 PCT Filed Apr. 26, 1995 PCT Pub. No. WO95/30648 PCT Pub. Date Nov. 16, 1995Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib (Ia): H2NOCH2CH(R1)OAr (Ib): H2NOCH(R1)CH2OAr and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb (IIa): (III): into a mixture of sulfonates IVa and IVb (IVa): (IVb): b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb (VIa): (VIb): c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.
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公开(公告)号:DE19605286A1
公开(公告)日:1997-08-14
申请号:DE19605286
申请日:1996-02-13
Applicant: BASF AG
Inventor: BURST WOLFRAM , HARTMANN HORST , KAISER WULF DR
IPC: B01J19/32 , C07C17/38 , C07D311/72 , B01D3/00
Abstract: Packing elements which are subjected to low pressure losses and which are used in fractional distillation columns, have the same diameter as that of the column inner diameter, and a height of 40 to 300mm. The elements consist of dimensionally stable layers (2,3) with an ordered structure. They are made of cloth or cloth-like material with a specific surface of 2000m /m . The novelty is that: (a) the contacting, deformed layers of cloth or cloth-like material pref. metal cloth, are arranged to form a number of narrow flow ducts, pref. triangular, rectangular, square, or equilateral hexagonal flow ducts; (b) the angle of inclination (1) of the teeth in the individual cloth layers (2,3) of the packing towards the column axis is 0 to 25 degrees, pref. 3 to 14 degrees; (c) wires or thin rods (4) are mounted as required between th cloth layers (2,3), or the cloth layers (2,3) are rigidly connected at some points of contact, providing mechanical stability. Also claimed is a process for obtaining pure substances from mixtures by rectification using the packing elements described.
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