-
31.
公开(公告)号:DE10031809A1
公开(公告)日:2002-01-17
申请号:DE10031809
申请日:2000-07-04
Applicant: BASF AG
Inventor: HAREMZA SYLKE , PRECHTL FRANK , HABECK THORSTEN
IPC: A61K8/49 , A61Q17/00 , A61Q17/04 , C07D311/22 , C07D311/30 , C07D405/06 , C07D407/06 , A61K7/00 , A61K7/40
Abstract: Flavonoids (I) are new. Flavonoids of formula (I) are new: [Image] R : (CH=CR4>)nQ; Q : Ar or Het; Ar : phenyl optionally monosubstituted with R3>; R1>H, 1-4C alkyl, OH, 1-4C alkoxy, phenoxy or benzyloxy; R2>H or 1-4C alkyl; R3> = 1-4C alkyl, 1-4C alkoxy or CN; R4>H, 1-4C alkyl or phenyl; n = 0 or 1; Het : pyridyl, furyl or methylpyrrolyl; provided that no more than two of R1>-R3> are H when Q is Ar and n : 0.
-
公开(公告)号:DE10025782A1
公开(公告)日:2001-12-06
申请号:DE10025782
申请日:2000-05-26
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , PARKER ROBERT , KUERSCHNER KATHRIN , SCHUHMACHER PETER , SCHMIDT HANS-WERNER , SCHMITT GEROLD , GIESA REINER
IPC: B32B7/02 , C09B67/00 , C09B67/20 , C09B69/10 , C09D5/00 , C09K19/00 , C09K19/20 , C09K19/34 , C09K19/36 , C09K19/38 , C09K19/54 , C09K19/04 , G02F1/13 , C09D11/02
Abstract: New liquid crystalline mixtures comprise: (a) difunctional mesogenic compound(s) (I); (b) reactive compound(s);and (c) optionally additives. New liquid crystalline mixtures comprise: (a) at least one difunctional mesogenic compound of formula Z1-Y1-A1-Y3-M-Y4-A2-Y2-Z2 (I); (b) at least one reactive compound selected from (i) vinyl or allyl ethers, (ii) vinyl or allyl esters of (un)saturated carboxylic acids, (iii) (meth)acrylate esters of mono- or polyfunctional alcohols, (iv) polyester (meth)acrylates, (v) vinyl (hetero)aromatic compounds, and (vi) N-vinyl amide or amine compounds of formula CH2=CH-NR1R2 (II); and (c) optionally further additives. Z1, Z2 = reactive groups (preferably photopolymerizable groups); Y1 - Y4 = direct bond, O, S, OC(O), OC(O)O, C(O)NR, NRC(O), OC(O)NR, NRC(O)O or NRC(O)NR; R = H or 1-4C alkyl; A1, A2 = 1-30C spacers, in which the carbon chains are optionally substituted by one or more Me, F, Cl or Br and interrupted by one or more O, S or non-adjacent NH or N(1-4C alkyl); M = mesogenic group; R1, R2 = -C(O)R3 or R3; R2, R3 = H or 1-4C alkyl; R2 + R3 = optionally unsaturated 3-5C alkylene (in which 1 or 2 CH2 groups are optionally replaced by NH, N(1-4C alkyl), N(6-10C aryl) or O and 1 or 2 CH group are optionally replaced by N).
-
公开(公告)号:DE10013507A1
公开(公告)日:2001-09-27
申请号:DE10013507
申请日:2000-03-20
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , PARKER ROBERT , KUERSCHNER KATHRIN , VILL VOLKMAR , PAUL MATTHIAS
IPC: G02F1/13 , C07D319/06 , C08F20/30 , C08J5/18 , C09K19/34 , C09K19/38 , C09K19/58 , C07D405/02 , C07D413/02 , C07D417/02 , C07H9/04 , C09D7/02
Abstract: Chiral 2,4,5-tri-substituted 1,3-dioxane compounds (I), with different substituents containing a mesogenic group, and their diastereomers are new. Chiral 2,4,5-tri-substituted 1,3-dioxane compounds of formula (I), with different substituents containing a mesogenic group, and their diastereomers are new: [Image] R1>[P-Y1>-(A1>)m-Y2>-]qM-Y3>-(A2>)n-Y4>- group; R2>, R3>[P-Y1>-(A1>)m-Y2>-]qM-Y3>-(A2>)n-Y4>'-; A1>, A2>spacers with 1-30 carbon atoms; M : a mesogenic group; Y1>, Y2>, Y3>, Y4>a single bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -CO-N(R)-, -(R)N-CO-, -O-CO-O-, -O-CO-N(R)-, -(R)N-CO-O- or -(R)N-CO-N(R)-; Y4>' : -O-, -O-CO-, -O-CO-O- or -O-CO-N(R)-, with the O atom attaching R2>, R3> to the 1,3-dioxane ring; R : hydrogen or 1-4C alkyl; P : H, 1-12C alkyl, a polymerizable group or a group containing a polymerizable group; m, n : 0 or 1; q : 1, 2 or 3. Independent claims are also included for: (a) liquid crystal (LC) compositions containing chiral compound(s) (I); (b) polymerizable LC compositions containing chiral compound(s) (I); (c) optical devices produced using these compositions; (d) printed or coated substrates, dispersions and emulsions, films or pigments prepared using the polymerizable LC compositions.
-
34.
公开(公告)号:CA2316623A1
公开(公告)日:2001-02-27
申请号:CA2316623
申请日:2000-08-24
Applicant: BASF AG
Inventor: HEILMANN PETER , PRECHTL FRANK , SCHNEIDER NORBERT , PARKER ROBERT , SCHUHMACHER PETER , RICHTER VOLKER , MEYER FRANK , KOCH VOLKER
IPC: G02B5/30 , C08F2/46 , C08F20/26 , C09B67/00 , C09B67/02 , C09B67/08 , C09B67/20 , C09D5/29 , C09D5/36 , C09D201/00 , C09K19/00 , G02F1/1335 , C09K19/38 , B05D5/06
Abstract: The invention relates to cholesteric layered material having an improved color impression, to pigments prepared therefrom, and to a process for the production and use thereof.
-
公开(公告)号:DE19917906A1
公开(公告)日:2000-10-26
申请号:DE19917906
申请日:1999-04-20
Applicant: BASF AG
Inventor: HABECK THORSTEN , PRECHTL FRANK , WUENSCH THOMAS , WESTENFELDER HORST , HAREMZA SYLKE , BACH THORSTEN , SPIEGEL ANJA
IPC: C07D295/14 , A61K8/00 , A61K8/41 , A61K8/44 , A61K8/49 , A61K31/136 , A61K31/196 , A61K31/24 , A61K31/40 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07C225/00 , C07C225/22 , C07C229/52 , C07D295/10 , C07D295/112 , C09K3/00 , A61K7/42
Abstract: Amino-substituted hydroxybenzophenones (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. Amino-substituted hydroxybenzophenones of formula (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. [Image] R1>, R2>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl or 3-10C cycloalkenyl, or NR1>R2> is a 5- or 6-membered ring; R3>, R4>1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, 1-12C alkoxy, 1-20C alkoxycarbonyl, 1-12C alkylamino, 1-12C dialkylamino, aryl, heteroaryl, nitrile, carboxylate, sulfonate or ammonium; X : H, COOR5> or CONR6>R7>; R5>-R7>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, (YO)oZ or aryl; Y : (CH2)x or CH(Me)CH2; x : 2-4; Z : Et, n-Pr, n-Bu or i-Pr; m : 0-3; n : 0-4; o : 1-20. Independent claims are also included for: (1) use of (I) as UV stabilizers in cosmetic and pharmaceutical compositions; (2) cosmetic and pharmaceutical compositions for protecting human skin or hair against UV light of wavelength 280-400 nm, comprising compounds (I) in a carrier, optionally in combination with other UV absorbers.
-
公开(公告)号:AU2886900A
公开(公告)日:2000-10-26
申请号:AU2886900
申请日:2000-04-18
Applicant: BASF AG
Inventor: HABECK THORSTEN , PRECHTL FRANK , WUENSCH THOMAS , WESTENFELDER HORST , HAREMZA SYLKE , BACH THORSTEN , SPIEGEL ANJA
IPC: C07D295/14 , A61K8/00 , A61K8/41 , A61K8/44 , A61K8/49 , A61K31/136 , A61K31/196 , A61K31/24 , A61K31/40 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07C225/00 , C07C225/22 , C07C229/52 , C07D295/10 , C07D295/112 , C09K3/00 , A61K7/44 , A61P43/00
Abstract: Amino-substituted hydroxybenzophenones (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. Amino-substituted hydroxybenzophenones of formula (I) are used as photostable UV filters in cosmetic and pharmaceutical compositions for protecting human skin or hair against solar radiation, optionally in combination with other UV absorbers. [Image] R1>, R2>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl or 3-10C cycloalkenyl, or NR1>R2> is a 5- or 6-membered ring; R3>, R4>1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, 1-12C alkoxy, 1-20C alkoxycarbonyl, 1-12C alkylamino, 1-12C dialkylamino, aryl, heteroaryl, nitrile, carboxylate, sulfonate or ammonium; X : H, COOR5> or CONR6>R7>; R5>-R7>H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, (YO)oZ or aryl; Y : (CH2)x or CH(Me)CH2; x : 2-4; Z : Et, n-Pr, n-Bu or i-Pr; m : 0-3; n : 0-4; o : 1-20. Independent claims are also included for: (1) use of (I) as UV stabilizers in cosmetic and pharmaceutical compositions; (2) cosmetic and pharmaceutical compositions for protecting human skin or hair against UV light of wavelength 280-400 nm, comprising compounds (I) in a carrier, optionally in combination with other UV absorbers.
-
37.
公开(公告)号:AU2250300A
公开(公告)日:2000-09-28
申请号:AU2250300
申请日:2000-03-23
Applicant: BASF AG
Inventor: MEYER FRANK , SCHUHMACHER PETER , PRECHTL FRANK
IPC: C07D493/04 , A61K8/00 , A61K8/02 , A61K8/37 , A61K8/49 , A61Q5/00 , A61Q17/04 , C09K3/00 , C09K19/00 , C09K19/04 , C09K19/20 , C09K19/58 , C09B69/10 , C09K19/36 , C08F220/26 , A61K7/48 , A61K7/42 , A61K7/06
Abstract: New chiral doping agents (I) comprise dianhydrohexitol derivatives containing at least one polymerizable group. Chiral doping agents of formula (I) are new. Z1-Y1-(A1)m-Y2-M-Y3-X-Y4-(A2)n-Y5-Z 2 (I) A1, A2 = spacers having a chain length of 1-30C; Y1-Y5 = direct bond, O, S, C(O), C(O)O, OC(O), CH=CHC(O)O, OC(O)O, C(O)N(R), N(R)C(O), CH2O, CH=N, N=CH or N=N; M = mesogenic group; R = H or 1-4C alkyl; Z1, Z2 = H, 1-4C alkyl, polymerizable group (PG) or residue carrying a PG, provided that at least one is a PG or residue carrying a PG; X = dianhydrosorbitol, dianhydromannitol or dianhydroiditol residue; m, n = 0 or 1. An Independent claim is included for cholesteric liquid crystal compositions (A) (which preferably reflect left-circular polarized light in the UV region), comprising at least one chiral liquid crystalline monomer (I) which provides a cholesteric liquid crystalline phase having a pitch of less than 450 nm, optionally mixed with at least one achiral liquid crystalline monomer of formula (II). Z1-Y1-(A1)m-Y2-M-Y4-(A2)n-Y5-Z2 (II)
-
公开(公告)号:CA2294007A1
公开(公告)日:1999-02-04
申请号:CA2294007
申请日:1998-07-03
Applicant: BASF AG
Inventor: PATSCH MANFRED , PRECHTL FRANK , HOESSEL PETER
IPC: A61K8/00 , A61K8/46 , A61K8/49 , A61Q5/02 , A61Q5/06 , A61Q5/10 , C09B62/00 , C09B62/503 , D06P3/30
Abstract: The invention relates to the use of reactive dyes for dyeing hair. Said reactive dyes are of formula (I), wherein a represents 1 or 2, b represents 0 or 1, Y represents vinyl or a radical of formula C2H4Q, Q being a group which can be split off in alkaline reaction conditions, L3 represents a direct bond or a binding link of formula CO-NH-M1 which can be interrupted by 1 or 2 nonadjacent oxygen atoms, imino or C1-C4 alkylimino groups, M1 being C2-C6 alkylene, A1 represents hydroxysulfonyl or a radical of formula SO2Y, A2 represents hydrogen, hydroxysulfonyl, methoxy, chlorine, bromine or carboxyl, W represents 1) the radical of a coupling constituent, of a monoazo dye or additionally, when b=0, of a disazo dye, which can carry other reactive groups, or 2) the radical of a chromophore which optionally has other reactive groups, and L1 and L2 each represent a binding link. The invention also represents a method for dyeing hair, and cosmetic preparations for dyeing hair.
-
公开(公告)号:DE50112776D1
公开(公告)日:2007-09-13
申请号:DE50112776
申请日:2001-04-02
Applicant: BASF AG
Inventor: PRECHTL FRANK , PARKER ROBERT , SCHUHMACHER PETER , SCHNEIDER NORBERT , HAREMZA SYLKE , SCHMIDT HANS-WERNER , SCHMITT GEROLD
IPC: C07C69/94 , G02B5/30 , C07C67/14 , C07C69/92 , C09B67/00 , C09B69/10 , C09D5/00 , C09D7/12 , C09D201/00 , C09K19/00 , C09K19/20 , C09K19/38 , G02F1/13 , G02F1/1335
Abstract: New polymerizable liquid crystalline compounds with two disubstituted phenyl groups attached to a mesogenic group via single bonds, ether, thioether, ester, amide or similar linking groups, in which the two substituents on each phenyl group are crosslinkable groups. Polymerizable liquid crystalline (LC) compounds of formula (I) are new. A , A = crosslinkable groups; X = a single bond, -O-, -S-, -C=N-, -OCO-, -COO-, -OCOO-, -CONR-, -NRCO-, -NR-, -OCONR-, -NRCOO-, -CH2O- or -NRCONR-; R = H or 1-4C alkyl; and M = a mesogenic group. Independent claims are also included for the following: (a) A method for the production of (I) by reacting a compound of formula (III) with a mesogenic compound of formula X''-M-X'' (IV). X', X'' = reactive side-groups which combine to form group X. (b) Compositions containing (I) and optionally other components selected from cholesteric (optionally crosslinkable) compounds, inorganic pigments, coloring agents and optionally polymerizable diluents or supports. (c) Pigments containing (I) in crosslinked form. (d) Coating materials containing such compositions or pigments.
-
公开(公告)号:CA2589653A1
公开(公告)日:2006-07-06
申请号:CA2589653
申请日:2005-12-17
Applicant: BASF AG
Inventor: BLUM RAINER , KANNENGIESSER DETLEF , PRECHTL FRANK , KOCH OLIVER
IPC: D21H21/10
-
-
-
-
-
-
-
-
-