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    36.
    发明专利
    未知

    公开(公告)号：AT248142T

    公开(公告)日：2003-09-15

    申请号：AT01115054

    申请日：2001-06-21

    Applicant: BASF AG

    Inventor： GYPSER ANDREAS DR ,  GROTE THOMAS DR ,  RHEINHEIMER JOACHIM DR ,  ROSE INGO DR ,  CULLMANN OLIVER DR ,  GEWEHR MARKUS DR ,  GRAMMENOS WASSILIOS DR ,  TORMO I BLASCO JORDI DR ,  MUELLER BERND DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  LORENZ GISELA DR ,  STIERL REINHARD DR

    IPC: C07C251/80 ,  A01N33/26 ,  A01N37/50 ,  C07C249/16 ,  C07C251/86

    Abstract: Hydrazonomethyl-salicylic acid (I) derivatives are new. The hydrazonomethyl-salicylic acid derivatives are compounds of formula (I). X = halo, NO2, CN, 1-4C alkyl, or 1-4C alkoxy; m = 0-3; A = OH, 1-4C alkoxy, NH2, NHCH3, or N(CH3)2; R = phenyl, naphthyl, 3-10C cycloalkyl, 5- or 6-membered heteroaryl or heterocyclyl containing 1-3 N and/or 1 O or S or 1 or 2 O and/or S (each optionally substituted with 1-3 Ra); Ra = CN, NO2, NH2, H2NCO-, H2NCS-, halo, OH, 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo), 1-6C alkylcarbonyl, 1-6C alkylsulfonyl, 1-6C alkylsulfoxyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 1-6C alkyl-NH-CO-, (1-6C alkyl)2N-CO-, 1-6C alkyl-NH-CS-, (1-6C alkyl)2N-CS-, 2-6C alkenyl, 2-6C alkenyloxy, phenyl, phenoxy, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, heteroaryl or heteroaryloxy, C(=NOR alpha )-OR beta , or OC(R alpha )2-C(R beta )=NOR beta , and cyclic groups are optionally substituted with 1-3 Rb; Rb = CN, NO2, NH2, H2NCO-, H2NCS-, halo, OH, 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo), 1-6C alkylcarbonyl, 1-6C alkylsulfonyl, 1-6C alkylsulfoxyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 1-6C alkyl-NH-CO-, (1-6C alkyl)2N-CO-, 1-6C alkyl-NH-CS-, (1-6C alkyl)2N-CS-, 2-6C alkenyl, 2-6C alkenyloxy, 3-6C cycloalkenyl, phenyl, phenoxy, phenylthio, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, heteroaryl or heteroaryloxy, or C(=NOR alpha )-OR beta ; R alpha and R beta = H or 1-6C alkyl; R = H, CN, or 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C haloalkyl, 1-6C alkoxy or 1-6C alkylthio (each optionally substituted with 1 or more halo and/or 1-3 Rc); Rc = halo, CN, NO2, OH; 1-6C alkyl or 1-6C alkoxy (each optionally substituted with halo); 1-6C alkylcarbonyl, 3-6C cycloalkyl, 1-6C alkoxycarbonyl, 1-6C alkylthio, NH(1-6C alkyl), N(1-6C alkyl)2, 2-6C alkenyl, 3-6C alkenyloxy, 3-6C alkynyloxy, or 1-4C alkylenedioxy (optionally halogenated). An Independent claim is also included for the preparation of compounds (I).

    40.
    发明专利
    未知

    公开(公告)号：ES2063075T3

    公开(公告)日：1995-01-01

    申请号：ES89110566

    申请日：1989-06-10

    Applicant: BASF AG

    Inventor： RHEINHEIMER JOACHIM DR ,  EICKEN KARL DR ,  PLATH PETER DR ,  PAUL GERHARD DR ,  HARREUS ALBRECHT DR ,  WESTPHALEN KARL-OTTO DR ,  WUERZER BRUNO DR ,  GROSSMANN KLAUS DR ,  RADEMACHER WILHELM DR ,  JUNG JOHANN PROF DR

    IPC: A01N43/40 ,  A01N43/54 ,  A01N43/64 ,  A01N43/66 ,  C07D213/64 ,  C07D213/70 ,  C07D239/38 ,  C07D239/52 ,  C07D239/56 ,  C07D239/60 ,  C07D251/22 ,  C07D251/30 ,  C07D251/34 ,  C07D251/38 ,  C07D403/12 ,  C07D521/00

    Abstract: Salicylic acid derivatives and their sulphur analogues of the formula I … … in which the substituents have the following meaning: R is hydrogen, succinyliminooxy; substituted C1-C10-alkoxy; optionally substituted 5-membered heteroaryl; a radical -OR in which R denotes hydrogen; optionally substituted C1-C10-alkyl, C3-C6-alkenyl or C3-C6-alkynyl; or a radical ON=CR R in which R and R denote optionally substituted C1-C20-alkyl, phenyl or, together, optionally substituted C3-C12-alkylene; R and R are C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and/or C1-C4-alkylthio; X is an oxygen or sulphur Y and Z are nitrogen or =CH-; R is halogen, optionally substituted C1-C4-alkyl, C1-C4-alkoxy; C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl or C3-C6-alkynyloxy; C1-C4-alkylamino, C2-C8-dialkylamino, arylamino or N-C1-C4-alkyl-N- arylamino; R is hydrogen or one of the radicals R , with the proviso that R denotes C1-C4-haloalkyl or X denotes sulphur or Y denotes =CH- or R denotes optionally substituted C3-C6-alkenyl or C3-C6-haloalkenyloxy if R stands for hydrogen or -OR , and their environmentally tolerable salts, their use as herbicides, and growth-regulating salicylic acid derivatives of the general formula Ia … … in which the substituents have the following meaning: R is hydrogen, succinyliminooxy; substituted C1-C10-alkoxy; optionally substituted 5-membered heteroaryl; a radical -OR in which R denotes hydrogen; optionally substituted C1-C10-alkyl, C3-C6-alkenyl or C3-C6-alkynyl; or a radical ON=CR R in which R and R denote optionally substituted C1-C20-alkyl, phenyl or, together, optionally substituted C3-C12-alkylene; R and R are C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and/or C1-C4-alkylthio; X is oxygen; Y is nitrogen; Z is nitrogen or =CH-; R is halogen, optionally substituted C1-C4-alkyl, C1-C4-alkoxy; C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl or C3-C6-alkynyloxyl; C1-C4-alkylamino, C2-C8-dialkylamino, arylamino or N-C1-C4-alkyl-N- arylamino; n is 0, 1 or 2.

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