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    31.
    发明专利
    未知

    公开(公告)号：DE59503924D1

    公开(公告)日：1998-11-19

    申请号：DE59503924

    申请日：1995-01-12

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PINKOS ROLF ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: B01J21/16 ,  B01J27/18 ,  B01J29/06 ,  C07B61/00 ,  C07C27/00 ,  C07C29/17 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C43/15 ,  C07C45/51 ,  C07C47/02

    Abstract: PCT No. PCT/EP94/00114 Sec. 371 Date Jul. 12, 1996 Sec. 102(e) Date Jul. 12, 1996 PCT Filed Jan. 12, 1995 PCT Pub. No. WO95/19334 PCT Pub. Date Jul. 20, 1995A process for the preparation of n-butyraldehyde and/or n-butanol, wherein a) 1,3-butadiene is caused to react with an alcohol of the formula IROHI, to form a mixture of adducts of the formulas II II and III III b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst to form the enol ether of the formula IV IV and d) n-butyraldehyde and/or n-butanol is/are produced from this ether IV by the reaction thereof with hydrogen and water or water only in the presence of a homogeneous or heterogeneous catalyst.

    METHOD FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL
    32.
    发明专利
    METHOD FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL 未知

    公开(公告)号：CA2282538A1

    公开(公告)日：1998-09-24

    申请号：CA2282538

    申请日：1998-03-06

    Applicant: BASF AG

    Inventor： PACIELLO ROCCO ,  KANAND JUERGEN ,  ROEPER MICHAEL

    IPC: C07C27/06 ,  C07B61/00 ,  C07C29/132 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C41/54 ,  C07C45/51 ,  C07C47/02 ,  C07C43/303

    Abstract: The invention relates to a method for producing n-butyraldehyde and/or nbutanol, whereby a) 1.3 butadiene or hydrocarbon mixtures containing butadiene are reacted with an alcohol of the formula (I) ROH wherein the radical R is an unsubstituted C2- to C20-alkyl- or alkenyl- or a C2- to C20-alkyl- or alkenylsubstituted with 1 to 2 C1- to C10-alkoxy- or hydroxy groups, a C6- to C10aryl- or a C7- to C11- arylkyl group or methyl group at a high temperature and under high pressure in the presence of a bronsted acid or in the presence of a complex of an element from group IA, VIIA or VIIIA of the periodic table of elements with ligands containing phosphor or nitrogen to form a mixture of adducts of formulae (II) and (III); b) isomerizing adduct (III) to adduct (II); c) converting adduct (III) into acetal of formula (IV) in the presence of a sufficient quantity of an alcohol ROH I to form acetal (IV) and a homogeneous or heterogeneous transitional metal element catalyst which is different from dicobaltoctacarbonyl or hydridocobalttetracarbonyl in the liquid phase in essentially water-free conditions and d) then reacting this acetal (IV) with hydrogen and water or water in the presence of a homogenous or heterogeneous transitional metal element catalyst which is different from dicobaltoctacarbonyl or hydridocobalttetracarbonyl in liquid phase to produce n-butyraldehyde and/or n-butanol and releasing the alcohol ROH I and returning the released alcohol ROH I to the reaction in accordance with partial reaction a) and/or c).

    33.
    发明专利
    未知

    公开(公告)号：NO970944L

    公开(公告)日：1997-04-28

    申请号：NO970944

    申请日：1997-02-28

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: C07C27/00 ,  C07B61/00 ,  C07C29/00 ,  C07C29/09 ,  C07C29/17 ,  C07C31/12 ,  C07C45/51 ,  C07C45/56 ,  C07C47/02 ,  C07D295/023

    Abstract: PCT No. PCT/EP95/03358 Sec. 371 Date Jul. 23, 1997 Sec. 102(e) Date Jul. 23, 1997 PCT Filed Aug. 24, 1995 PCT Pub. No. WO96/07630 PCT Pub. Date Mar. 14, 1996A process for the preparation of n-butyraldehyde and/or n-butanol, in which a) 1,3-butadiene is caused to react with an amine of the formula I R1R2NH, I in which R1 and R2 independently denote hydrogen, optionally substituted aliphatic or cycloaliphatic radicals, or aryl or aralkyl radicals or are linked to form a bridging member which can contain hetero atoms, at elevated temperature and under superatmospheric pressure in the presence of a compound of a Group VIIIb element and in the presence of an alkali metal amide or a basic metal oxide to form a mixture of the adducts of the formulas II II and III III b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous catalyst containing a transition metal element in the gaseous phase to form the enamine of the formula IV IV and d) n-butyraldehyde and/or n-butanol is/are produced from this enamine.

    34.
    发明专利
    未知

    公开(公告)号：FI970837A

    公开(公告)日：1997-04-25

    申请号：FI970837

    申请日：1997-02-27

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: C07C27/00 ,  C07B61/00 ,  C07C29/00 ,  C07C29/09 ,  C07C29/17 ,  C07C31/12 ,  C07C45/51 ,  C07C45/56 ,  C07C47/02 ,  C07D295/023 ,  C07C

    Abstract: PCT No. PCT/EP95/03358 Sec. 371 Date Jul. 23, 1997 Sec. 102(e) Date Jul. 23, 1997 PCT Filed Aug. 24, 1995 PCT Pub. No. WO96/07630 PCT Pub. Date Mar. 14, 1996A process for the preparation of n-butyraldehyde and/or n-butanol, in which a) 1,3-butadiene is caused to react with an amine of the formula I R1R2NH, I in which R1 and R2 independently denote hydrogen, optionally substituted aliphatic or cycloaliphatic radicals, or aryl or aralkyl radicals or are linked to form a bridging member which can contain hetero atoms, at elevated temperature and under superatmospheric pressure in the presence of a compound of a Group VIIIb element and in the presence of an alkali metal amide or a basic metal oxide to form a mixture of the adducts of the formulas II II and III III b) the adduct III is isomerized to the adduct II, c) the adduct II is isomerized in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous catalyst containing a transition metal element in the gaseous phase to form the enamine of the formula IV IV and d) n-butyraldehyde and/or n-butanol is/are produced from this enamine.

    PROCESS FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL
    37.
    发明专利
    PROCESS FOR PRODUCING N-BUTYRALDEHYDE AND/OR N-BUTANOL 未知

    公开(公告)号：CA2180982A1

    公开(公告)日：1995-07-20

    申请号：CA2180982

    申请日：1995-01-12

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PINKOS ROLF ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: B01J21/16 ,  B01J27/18 ,  B01J29/06 ,  C07B61/00 ,  C07C27/00 ,  C07C29/17 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C43/15 ,  C07C45/51 ,  C07C47/02

    Abstract: In a process for producing n-butyraldehyde and/or n-butanol, (a) 1,3-butadiene is reacted with an alcohol having the formula ROH, in which the residue R stands for a non-substituted C2-C20-alkyl or alkenyl group that may also be substituted by 1 or 2 C1-C10-alkoxy or hydroxy groups, a C6-C10-aryl or C7-C11-aralkyl group or the methyl group, at a higher temperature and pressure in the presence of a Brönsted acid or in the presence of a compound of an element from groups IB, VIIb or VIIIb of the periodic table of elements with phosphoric or nitrogenated ligands, so as to produce a mixture of addition compounds having the formulas (II) and (III); (b) the addition compound III is isomerised into the addition compound II; (c) the addition compound II is isomerised in the presence of a homogeneous or heterogeneous transition metal element catalyst in liquid phase or in the presence of a heterogeneous transition metal element-containing catalyst in gaseous phase, so as to produce an enol ether having the formula (IV); and (d) n-butyraldehyde and/or n-butanol are generated by reacting said enol ether IV with hydrogen and water or with water in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous transition metal element-containing catalyst in the gaseous phase. The alcohol ROH released is recycled into the partial reaction (a).

    PRODUCCION DE (CO) AGENTES TENSIOACTIVOS AL HACER REACCIONAR POLIOLES CON OLEFINAS.
    38.
    发明专利
    PRODUCCION DE (CO) AGENTES TENSIOACTIVOS AL HACER REACCIONAR POLIOLES CON OLEFINAS. 未知

    公开(公告)号：MX2007012263A

    公开(公告)日：2007-10-12

    申请号：MX2007012263

    申请日：2006-04-05

    Applicant: BASF AG

    Inventor： HEIDEMANN THOMAS ,  TRILLER MICHAEL ,  STEPHAN J RGEN ,  ROEPER MICHAEL ,  TROPSCH J RGEN

    IPC: C07C43/13 ,  C07C41/06 ,  C08G65/00 ,  C08G65/34 ,  C11D1/66

    Abstract: La invencion se refiere a un metodo para producir eteres de poliolalquilo al hacer reaccionar al menos tres compuestos teniendo funciones de hidroxi con olefinas en presencia de catalizadores acidos a temperaturas de entre 20 - 250 degree C y presiones de entre 0.5 - 10 bar. Las olefinas corresponden a la formula general (I), en donde R1 representa hidrogeno y R2 es radicales de carbono lineales o ramificados teniendo 7 - 28 atomos de carbono, o R1 y R2 respectivamente representan radicales de carbono lineales o ramificados teniendo 1 - 27 atomos de carbono, por lo que el numero de atomos de carbono de R1 y R2 es, a lo mucho, 28. La invencion tambien se refiere a eteres de poliolalquilo que se derivan de compuestos que tienen al menos tres funciones de hidroxi, o todas las funciones de hidroxi hasta que una es reemplazada por un grupo de la formula general (VIII). La invencion se refiere ademas a dichos eteres de polioalquilo como agentes tensioactivos y dichos agentes de lavado y limpieza conteniendo eteres de polioalquilo (ver formulas (I) y (VIII)).

    39.
    发明专利
    未知

    公开(公告)号：AT352536T

    公开(公告)日：2007-02-15

    申请号：AT02797551

    申请日：2002-08-28

    Applicant: BASF AG

    Inventor： ROEPER MICHAEL ,  STEPHAN JUERGEN

    IPC: C07C6/04 ,  C07C11/06 ,  C07C6/10

    Abstract: The invention relates to a method for the production of propene by multiple execution of the following sequence of steps, whereby in step 1 a mixture M1, essentially comprising unbranched C4- to C9 monoolefins (Components 04-9), 0 to 15 mol. % ethylene (component E), based on the components 04-9, 0 to 100 mol. % saturated hydrocarbons (components KG), based on the components 04-9, 0 to 30 mol. % olefins with more than 9 hydrocarbon atoms (components 0>9), based on components 04-9, 0 to 1 mol. %, based on the components 04-9, propene (component 03), 0 to 10 mol. %, based on the components 04-9, of other hydrocarbons (components KS), is brought into contact with a metathesis catalyst at a temperature of 20 to 350° C., with the proviso that the molar proportion of the sum of the 1-olefins and the sum of the 2-olefins to the sum of the components 04-9 and 0>9 is at least 0.5%, so long as the mixture M1 is not simultaneously or previously subjected to an isomerisation, correspondingly changing the proportion of 1- and 2-olefins, thus producing a mixture M2. In step II a mixture M1 is produced from a mixture M2 whereby a) propene and optionally components 0>9 and components KS are completely or partially removed and b) amounts of components 04-09 are added, a maximum of 1 mol. % of component E, based on the added amounts of components 04-09 and optionally other saturated or olefinically-unsaturated hydrocarbons, based on the added amounts of components 04-09, are added.

    40.
    发明专利
    未知

    公开(公告)号：AT334134T

    公开(公告)日：2006-08-15

    申请号：AT02800574

    申请日：2002-09-26

    Applicant: BASF AG

    Inventor： SAVA XAVIER ,  SLANY MICHAEL ,  ROEPER MICHAEL

    IPC: B01J31/28 ,  B01J31/24 ,  C07B61/00 ,  C07C51/14 ,  C07C57/03 ,  C07C67/38 ,  C07C69/533 ,  C07F9/6568 ,  C07F9/6571

    Abstract: A system comprising a diphosphine of the formula R 1 >P-(CH) n -PR 2 R 3 where R 1 is a divalent radical which together with the phosphorus atom to which it is linked forms an unsubstituted or substituted 2-phosphatricyclo[3.3.1.1{3,7}]decyl group or a derivative thereof in which one or more of the carbon atoms are replaced by heteroatoms, R 2 , R 3 are each, independently of one another, a monovalent radical having from 1 to 20 atoms or together form a divalent radical having from 2 to 20 atoms, n is 4 or 5, and a mixture of such diphosphines, and palladium or a palladium compound is suitable as carbonylation catalyst for the carbonylation of a conjugated diene.

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