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    31.
    发明专利
    未知

    公开(公告)号：ES2098081T3

    公开(公告)日：1997-04-16

    申请号：ES94111341

    申请日：1994-07-21

    Applicant: BASF AG

    Inventor： LUX MARTIN DR ,  FUNK GUIDO DR ,  SAIVE ROLAND DR ,  GOERTZ HANS-HELMUT DR ,  KONRAD RAINER DR

    IPC: C09K3/16 ,  C08F2/34 ,  C08F2/44 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08K5/17 ,  C08K5/20 ,  C08L23/02

    Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d

    32.
    发明专利
    未知

    公开(公告)号：DE59401850D1

    公开(公告)日：1997-04-03

    申请号：DE59401850

    申请日：1994-07-21

    Applicant: BASF AG

    Inventor： LUX MARTIN DR ,  FUNK GUIDO DR ,  SAIVE ROLAND DR ,  GOERTZ HANS-HELMUT DR ,  KONRAD RAINER DR

    IPC: C09K3/16 ,  C08F2/34 ,  C08F2/44 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08K5/17 ,  C08K5/20 ,  C08L23/02

    Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d

    33.
    发明专利
    未知

    公开(公告)号：AT149183T

    公开(公告)日：1997-03-15

    申请号：AT94111341

    申请日：1994-07-21

    Applicant: BASF AG

    Inventor： LUX MARTIN DR ,  FUNK GUIDO DR ,  SAIVE ROLAND DR ,  GOERTZ HANS-HELMUT DR ,  KONRAD RAINER DR

    IPC: C09K3/16 ,  C08F2/34 ,  C08F2/44 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08K5/17 ,  C08K5/20 ,  C08L23/02

    Abstract: A process for the preparation of homopolymers of ethylene or copolymers of ethylene with secondary amounts of other C3- to C12-alk-1-enes by catalytic polymerisation in a suspension or in the gas phase in the presence of an antistatic at a temperature of from 50 to 120 DEG C and at a pressure of from 5 to 50 bar, characterised in that the antistatic employed is a mixture of the following substances: a) a metal salt of medialanic acid of formula (I) , b) a metal salt of an anthranilic acid of formula (II) , where the organic radical R is either alpha ) -CO-(CH2)x-CH3 (III alpha ) or ss) -CO-(CH2)y-CH=CH-(CH2)z-CH3 (IIIss), where x, y and z are each an integer, and x is in the range from 6 to 18, y is in the range from 1 to 16, z is in the range from 1 to 16 and y + z is in the range from 4 to 17, and c) a polyamine obtainable by reacting epichlorohydrin with an aliphatic primary monoamine or an N-alkylalkylenediamine of the formula (IV> R NH-R -NH2 (IV), where R is a C8-C24-alkyl radical and R is a C2-C6-alkylene radical. d

    37.
    发明专利
    未知

    公开(公告)号：AT113616T

    公开(公告)日：1994-11-15

    申请号：AT91103644

    申请日：1991-03-09

    Applicant: BASF AG

    Inventor： BUESCHGES ULRICH DR ,  SAIVE ROLAND DR

    IPC: C08F4/629 ,  C08F4/685 ,  C08F10/00 ,  C08F10/02

    Abstract: A transition-metal catalyst component for a Ziegler catalyst system, obtainable by 1) mixing, in a solvent, an inorganic, oxidic carrier with 1.1) a vanadium trihalide/alcohol complex of the formula VY3nZ-OH, where Y is chlorine or bromine, N is from 1 to 6, and Z is a monovalent, saturated, aliphatic or araliphatic hydrocarbon radical having not more than 10 carbon atoms, and 1.2) a titanium trihalide or a titanium trihalide/aluminum trihalide complex, where the halogen can be chlorine and/or bromine, or a titanium trihalide complex of the formula TiY3. nZ-OH or a mixture thereof, where Y is chlorine or bromine, n is from 1 to 6, and Z is a monovalent, saturated, aliphatic or araliphatic hydrocarbon radical having not more than 10 carbon atoms or a mixture thereof, and 1.3) a zirconium tetrahalide, where the halogen can be chlorine and/or bromine, 2) removing the solvent by evaporation, 3) mixing the solid-phase intermediate from step (2) with 3.1) an organoaluminum catalyst component of the formula AlRmX3-m, where R is a C1- to C18 - hydrocarbon radical, m is from 1 to 3, and X is OR, chlorine, bromine or hydrogen, and 3.2) an organic carboxylate or an organosilicon compound or a mixture thereof in an organic solvent, and 4) if desired, isolating the solid-phase intermediate by filtration, washing and drying. and the use thereof for the homopolymerization or copolymerization of ethane are described.

    39.
    发明专利
    未知

    公开(公告)号：DE4121355A1

    公开(公告)日：1993-01-07

    申请号：DE4121355

    申请日：1991-06-28

    Applicant: BASF AG

    Inventor： MUELLER HANS-JOACHIM DR ,  KONRAD RAINER DR ,  SCHWEIER GUENTHER DR ,  WEBER SIEGFRIED DR ,  SAIVE ROLAND DR ,  KOELLE PETER DR

    IPC: C08F4/02 ,  C08F4/24 ,  C08F4/60 ,  C08F4/69 ,  C08F10/00 ,  C08F10/02

    Abstract: A novel Phillips catalyst for the homopolymerisation of ethylene and the copolymerisation of ethylene with alpha -olefins contains, as catalytically active components, a specific aluminium phosphate-supported chromium catalyst and cocatalysts of the general formulae I to IV MR M R2 M R 3-nXn MM RR@ (I) (II) (III) (IV> in which the index and variables have the following meanings: M is lithium, sodium or potassium, M is magnesium or zinc, M is boron or aluminium, R is C1- to C10-alkyl or C6- to C20-aryl, R is R or C1- to C10-alkoxy or C6- to C20-aryloxy, X is chlorine, bromine or iodine, N is 0, 1 or 2. The aluminium phosphate-supported chromium catalyst is obtainable by applying chromium compounds to a finely divided aluminium phosphate having a P:Al molar ratio of close or equal to 1 and a pore volume of > 1 cm /g, and activating the resulting intermediate at elevated temperatures in an oxidising atmosphere. The novel Phillips catalyst has an extremely long mean service life, and its productivity can be further increased by adding hydrogen.

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