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    1.
    发明专利
    未知

    公开(公告)号：DE3776976D1

    公开(公告)日：1992-04-09

    申请号：DE3776976

    申请日：1987-04-03

    Applicant: BASF AG

    Inventor： MUELLER-MALL RUDOLF DR ,  FUNK GUIDO DR ,  BACHL ROBERT DR ,  HENNENBERGER PETER DR ,  KOLK ERICH DR

    IPC: C08F2/06 ,  C08F2/14 ,  C08F2/18 ,  C08F10/02 ,  C08F210/16

    Abstract: A process is claimed for the continuous prodn. of ethene homopolymer or copolymer (I) with sec. amts. of 3-8C alpha-olefins, of particle size 0.3-1.5 mm (DIN 53477) and bulk density 0.4-0.6 g/cm3 (DIN 53468), by catalytic polymerisation at 60-100 deg.C and 30-50 bar in a circular-tube reactor with 4-8C alkane as reaction medium contg. dissolved monomer(s) and suspended (I) and with a circulating reacton mixt. to which reactants are added and from which (I) is recovered by removal of mixt. The novelty is that the mean concn. of (I) (Cm) in the circulation is kept in the range 0.4-0.7 g per g reaction mxit. and that reaction mixt. is removed at a point in the cycle where the concn. of (I) is from 0.5Cm to 0.7Cm.

    PROCESS FOR PREPARING HOMO AND COPOLYMERS OF ALPHA-OLEFINES WITH A ZIEGLER CATALYST SYSTEM
    2.
    发明专利
    PROCESS FOR PREPARING HOMO AND COPOLYMERS OF ALPHA-OLEFINES WITH A ZIEGLER CATALYST SYSTEM 未知

    公开(公告)号：DE3561514D1

    公开(公告)日：1988-03-03

    申请号：DE3561514

    申请日：1985-02-01

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER DR ,  BACHL ROBERT DR ,  BALL WOLFGANG DR ,  FUNK GUIDO DR ,  LAUN MARTIN DR

    IPC: C08F4/00 ,  C08F4/14 ,  C08F4/16 ,  C08F4/20 ,  C08F4/60 ,  C08F4/622 ,  C08F4/64 ,  C08F4/658 ,  C08F4/68 ,  C08F10/00

    Abstract: alpha -Monoolefins are polymerized using a Ziegler catalyst system comprising (1) a transition metal catalyst component and (2) an organoaluminum catalyst component, in which (1) is a solid-phase product (VI) obtained by (1.1) first combining (1.1.1) an inorganic oxidic substance (I), as the carrier, with (1.1.2) a solution (II) consisting of (IIa) an organic solvent and (IIb) a transition metal composition to form a suspension (III), evaporating down this suspension to form a solid-phase intermediate (IV), and (1.2) then (1.2.1) combining the solid-phase intermediate (IV), obtained from (1.1), with (1.2.2) a solution of an organoaluminum compound (V) to form a suspension, the resulting suspended solid-phase product (VI) being the transition metal catalyst component (1). The characteristic feature is that (1) is a solid-phase product (VI) obtained using a solution (II) consisting of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex, (IIb2) a titanium trihalide and (IIb3) a zirconium tetrahalide.

    Process for the preparation of homopolymers of ethene and copolymers of ethene with higher alpha -monoolefins by means of a Ziegler catalyst system
    4.
    发明专利
    Process for the preparation of homopolymers of ethene and copolymers of ethene with higher alpha -monoolefins by means of a Ziegler catalyst system 未知

    公开(公告)号：DE3528101A1

    公开(公告)日：1987-02-12

    申请号：DE3528101

    申请日：1985-08-06

    Applicant: BASF AG

    Inventor： BACHL ROBERT DR ,  FUNK GUIDO DR ,  VOGT HEINZ DR ,  WARZELHAN VOLKER DR

    IPC: C08F10/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/02 ,  C08F4/52

    Abstract: The invention relates to the homopolymerization and copolymerization of ethene by means of a Ziegler catalyst system comprising (1) a transition-metal catalyst component, (2) an organoaluminium catalyst component and (3) optionally an organohalogen catalyst component, characterized in that (1) is the solid-phase product (VI) obtained by (1.1) first combining (1.1.1) an inorganic oxidic material (I) as support substance and (1.1.2) a solution (II) of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex, (IIb2) a titanium trihalide or titanium trihalide/alcohol complex and optionally (IIb3) a zirconium tetrahalide, with formation of a dispersion (III), evaporating the latter with formation of a solid-phase intermediate (IV), and (1.2) then (1.2.1) combining the intermediate (IV) from (1.1) and (1.2.2) a particular dissolved aluminium component (V) with formation of a dispersion, where the solid-phase product (VI) obtained as the dispersed material is the transition-metal catalyst component (1).

    5.
    发明专利
    未知

    公开(公告)号：DE3417238A1

    公开(公告)日：1985-11-14

    申请号：DE3417238

    申请日：1984-05-10

    Applicant: BASF AG

    Inventor： BACHL ROBERT DR ,  WARZELHAN VOLKER DR ,  SCHWEIER GUENTHER DR ,  GROPPER HANS DR ,  BALL WOLFGANG DR

    IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/642 ,  C08F4/658 ,  C08F4/68 ,  C08F10/00 ,  C08F10/02

    Abstract: Homopolymers and copolymers of ethene are prepared using a Ziegler catalyst system comprising (1) a transition metal catalyst component, (2) an organoaluminum catalyst component and (3) an organohalogen catalyst component, by a method in which the transition metal catalyst component (1) employed is a solid-phase product (VI) obtained by (1.1) first combining (1.1.1) an inorganic oxidic substrate (I), as the carrier, with (1.1.2) a solution (II) consisting of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex, (IIb2) a titanium trihalide or titanium trihalide/alcohol complex and, if required, (IIb3) a zirconium tetrahalide to form a suspension (III), evaporating down this suspension to form a solid-phase intermediate (IV), and (1.2) then (1.2.1) combining the solid-phase intermediate (IV) obtained from (1.1) with (1.2.2) a solution of an organoaluminum compound (V) to form a suspension, the resulting suspended solid-phase product (VI) being the transition metal catalyst component (1).

    Process for the preparation of ethene-alpha-monoolefin copolymers by copolymerisation by means of a Ziegler catalyst system
    7.
    发明专利
    Process for the preparation of ethene-alpha-monoolefin copolymers by copolymerisation by means of a Ziegler catalyst system 未知

    公开(公告)号：DE3633131A1

    公开(公告)日：1988-03-31

    申请号：DE3633131

    申请日：1986-09-30

    Applicant: BASF AG

    Inventor： BACHL ROBERT DR ,  VOGT HEINZ DR

    IPC: C08F4/00 ,  C08F4/64 ,  C08F210/02

    Abstract: The invention relates to a process for the preparation of binary or ternary ethene- alpha -monoolefin copolymers by copolymerisation of the monomers by means of a Ziegler catalyst system comprising (1) a transition-metal catalyst component comprising titanium, magnesium, chlorine and optionally minor amounts of other constituents, optionally and advantageously applied to a silicate support, and (2) an alkyl aluminium catalyst component, characterised in that a Ziegler catalyst system is employed which contains an additional catalyst component, namely (3) an oxygen bridge catalyst component comprising a particularly selected type of an ether, ester or siloxane, giving copolymers which are suitable for the production of high-quality films.

    Process for the preparation of a titanium-containing catalyst component for Ziegler catalyst systems
    8.
    发明专利
    Process for the preparation of a titanium-containing catalyst component for Ziegler catalyst systems 未知

    公开(公告)号：DE3433468A1

    公开(公告)日：1986-03-20

    申请号：DE3433468

    申请日：1984-09-12

    Applicant: BASF AG

    Inventor： VOGT HEINZ DR ,  BACHL ROBERT DR ,  WARZELHAN VOLKER DR ,  STAIGER GERHARD DR ,  FUNK GUIDO DR

    IPC: C08F4/64 ,  C08F4/65 ,  C08F10/00 ,  C08F4/52

    Abstract: The invention relates to the preparation of a titanium-containing catalyst component (1) for Ziegler catalyst systems, in which (1.1) first (1.1.1) an inorganic oxidic support material (I) and (1.1.2) a solution (II) of (IIa) a lower alcohol, (IIb) a titanium trichloride and (IIc) magnesium chloride are combined, forming a dispersion (III), which is evaporated to form an intermediate (IV), and (1.2) then (1.2.1) the product (IV) from (1.1) and (1.2.2) an aluminium component (V) are combined, the resultant product (VI) being the catalyst component (1), characterised in that the aluminium component (V) employed in (1.2) comprises (1.2.2.1) a complex compound of a certain oxacycloalkane carrying no substituents and a certain aluminium compound, and (1.2.2.2) optionally a certain free aluminium compound.

    9.
    发明专利
    未知

    公开(公告)号：DE3426193A1

    公开(公告)日：1986-01-23

    申请号：DE3426193

    申请日：1984-07-17

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER DR ,  KARER RAINER ,  BACHL ROBERT DR ,  FUNK GUIDO DR

    IPC: C08F4/02 ,  C08F4/62 ,  C08F4/64 ,  C08F4/68 ,  C08F10/00 ,  C08F4/52

    Abstract: A transition metal catalyst component (1) for Ziegler catalyst systems is prepared by (1.1) first combining (1.1.1) an inorganic oxidic substance (I), as the carrier, with (1.1.2) a solution (II) consisting of (IIa) an organic solvent and (IIb) a transition metal composition to form a suspension (III), evaporating down this suspension to form a solid-phase intermediate (IV) and (1.2) then combining (1.2.1) the solid-phase intermediate (IV) obtained from (1.1) with (1.2.2) a solution of an organoaluminum compound (V) to form a suspension, the resulting suspended solid-phase products (VI) being the transition metal catalyst component (1). The characteristic feature is that the solution (II) employed in stage (1.1) consists of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex, (IIb2) a titanium trihalide and (IIb3) a zirconium tetrahalide.

    10.
    发明专利
    未知

    公开(公告)号：DE3404668A1

    公开(公告)日：1985-08-14

    申请号：DE3404668

    申请日：1984-02-10

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER DR ,  BACHL ROBERT DR ,  BALL WOLFGANG DR ,  FUNK GUIDO DR ,  LAUN MARTIN DR

    IPC: C08F4/00 ,  C08F4/14 ,  C08F4/16 ,  C08F4/20 ,  C08F4/60 ,  C08F4/622 ,  C08F4/64 ,  C08F4/658 ,  C08F4/68 ,  C08F10/00 ,  C08F10/04 ,  C08F10/02 ,  C08F10/14 ,  C08F10/08 ,  C08F4/52

    Abstract: alpha -Monoolefins are polymerized using a Ziegler catalyst system comprising (1) a transition metal catalyst component and (2) an organoaluminum catalyst component, in which (1) is a solid-phase product (VI) obtained by (1.1) first combining (1.1.1) an inorganic oxidic substance (I), as the carrier, with (1.1.2) a solution (II) consisting of (IIa) an organic solvent and (IIb) a transition metal composition to form a suspension (III), evaporating down this suspension to form a solid-phase intermediate (IV), and (1.2) then (1.2.1) combining the solid-phase intermediate (IV), obtained from (1.1), with (1.2.2) a solution of an organoaluminum compound (V) to form a suspension, the resulting suspended solid-phase product (VI) being the transition metal catalyst component (1). The characteristic feature is that (1) is a solid-phase product (VI) obtained using a solution (II) consisting of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex, (IIb2) a titanium trihalide and (IIb3) a zirconium tetrahalide.

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