公开(公告)号：WO2017092873A1

公开(公告)日：2017-06-08

申请号：PCT/EP2016/025155

申请日：2016-11-28

Applicant: LINDE AKTIENGESELLSCHAFT ,  BASF SE ,  THYSSENKRUPP AG ,  THYSSENKRUPP INDUSTRIAL SOLUTIONS AG

Inventor： MASS, Hans-Jürgen ,  GÖKE, Volker ,  MACHHAMMER, Otto ,  BODE, Andreas ,  KOLIOS, Grigorios ,  BÜKER, Karsten

IPC: C10K3/00 ,  C01B3/30 ,  C01B3/34 ,  C01B32/30

CPC classification number: C01B3/344 ,  C01B3/30 ,  C01B2203/0216 ,  C01B2203/0255 ,  C01B2203/0272 ,  C01B2203/0485 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/1247 ,  C01B2203/1252 ,  C01B2203/1258 ,  C01B2203/142 ,  C01B2203/82 ,  C10G2/32 ,  C10K3/02

Abstract: Verfahren zur Erzeugung von Synthesegas (5) beim dem ein kohlenwasserstoffhaltiges Koksgas (2) und ein kohlendioxidhaltiges Konvertergas (4) in eine erste Reaktionszone (Z1) eingeleitet werden und Wasserstoff, enthalten im kohlenwasserstoffhaltigen Koksgas (2), zumindest teilweise mit Kohlendioxid zu Wasser und das Wasser mit dem Kohlenwasserstoff thermisch zu Synthesegas, welches Kohlenmonoxid und Wasserstoff enthält, umgesetzt werden. Sowie dass in einer zweiten Reaktionszone (Z2) ein sauerstoffhaltiges Gas (3) eingeleitet wird und mit diesem und einem Teil des Wasserstoff aus der ersten Reaktionszone (Z1) thermische Energie erzeugt wird, wobei, die die in der zweiten Reaktionszone (Z2) erzeugte thermische Energie der ersten Reaktionszone (Z1) zugeführt wird.

Abstract translation:

一种用于生产（5），其中，含烃焦炉气（2），并在第一反应区（Z1）一个含二氧化碳的转炉煤气（4）被引入并含有含烃焦炉气中氢气的合成气的方法，（2） 至少部分地与二氧化碳反应成水并且水与烃热转化成含有一氧化碳和氢气的合成气。 并且，在第二反应区（Z2）的含氧气体（3）被启动，并且热能与后者和从与所述第二反应区（Z2）中产生的热的第一反应区（Z1）中，氢的一部分生成 提供第一个反应区（Z1）的能量。

公开(公告)号：EP2931415B1

公开(公告)日：2020-11-18

申请号：EP13814068.6

申请日：2013-12-12

Applicant: BASF SE ,  Linde GmbH

Inventor： MACHHAMMER, Otto ,  HORMUTH, Wolfgang Alois ,  SCHNEIDER, Christian ,  BODE, Andreas ,  GOEKE, Volker ,  MAASS, Hans-Juergen ,  KERN, Matthias ,  KLINGLER, Dirk ,  KÖNIG, Rene ,  BRÜGGEMANN, Philipp ,  BERNNAT, Jens ,  KOLIOS, Grigorios

IPC: B01J19/00 ,  B01J8/00

公开(公告)号：EP2935517A1

公开(公告)日：2015-10-28

申请号：EP13805375.6

申请日：2013-12-13

Applicant: BASF SE ,  Linde AG ,  ThyssenKrupp Industrial Solutions AG

Inventor： SCHNEIDER, Christian ,  BODE, Andreas ,  KLINGLER, Dirk ,  MACHHAMMER, Otto ,  BRÜGGEMANN, Philipp ,  KERN, Matthias ,  HORMUTH, Wolfgang Alois ,  GUZMANN, Marcus ,  KÖNIG, Rene ,  BERNNAT, Jens ,  KOLIOS, Grigorios ,  GOEKE, Volker ,  MAASS, Hans-Juergen ,  BÜKER, Karsten

IPC: C10B55/10 ,  C01B3/34

CPC classification number: C01B3/344 ,  C01B2203/0222 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/06 ,  C01B2203/0844 ,  C01B2203/085 ,  C01B2203/0855 ,  C01B2203/0861 ,  C01B2203/0883 ,  C01B2203/1235

Abstract: The invention relates to a process for utilizing a hydrocarbon-containing and/or carbon dioxide-containing blast furnace gas, accompanying gas and/or biogas, characterized in that hydrocarbon-containing and/or carbon dioxide-containing blast furnace gas, accompanying gas and/or biogas is introduced into a reaction chamber, and the multicomponent mixture present in the blast furnace gas, accompanying gas and/or biogas is converted in a high-temperature zone at temperatures of above 1000°C and in the presence of a support into a product-gas mixture which consists of more than 95% by volume CO, CO
2 , H
2 , H
2 O, CH
4 and N
2 , and optionally into a carbon-containing solid of which more than 75% by weight, based on the total mass of the carbon-containing solid, is deposited onto the support, wherein the flow velocity of the gas mixture blast furnace gas, accompanying gas and/or biogas in the reaction zone is less than 20 m/s.

Abstract translation: 本发明涉及一种利用含烃和/或二氧化碳的副产物气体，伴随的气体和/或生物气体的方法，其中含烃和/或二氧化碳的副产物气体，伴随的气体和/或生物气体是 引入到反应空间中，并且包含在副产气体中的伴随气体和/或生物气体的多组分混合物在高于1000℃的高温区域和在载体存在下转化成产物气体混合物 其包含超过95体积％的CO，CO 2，H 2，H 2 O，CH 4和N 2，并任选地加入到基于碳的总质量至少75重量％的程度沉积的含碳固体 在载体上，反应区中副产物气体，伴随气体和/或生物气体的气体混合物的流速小于20m / s的载体上。

公开(公告)号：EP2739388B1

公开(公告)日：2015-06-17

申请号：EP12740994.4

申请日：2012-08-01

Applicant: BASF SE

Inventor： OLBERT, Gerhard ,  WEGERLE, Ulrike ,  KOLIOS, Grigorios ,  TELLAECHE HERRANZ, Carlos ,  HÖCHST, Reinhold ,  GIENGER, Andrea ,  BAUER, Roland

IPC: B01J19/24 ,  C07C5/48

CPC classification number: B01J19/2485 ,  B01J2219/00155 ,  B01J2219/2411 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/32 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/08 ,  C07C15/46

公开(公告)号：EP2654941B1

公开(公告)日：2014-11-26

申请号：EP11802692.1

申请日：2011-12-13

Applicant: BASF SE

Inventor： OLBERT, Gerhard ,  WEGERLE, Ulrike ,  KOLIOS, Grigorios ,  KOSTOVA, Albena ,  KESSEL, Jasmina ,  WECK, Alexander ,  REZAI, Alireza

IPC: B01J19/24 ,  C07C5/48

CPC classification number: B01J19/2485 ,  B01J23/96 ,  B01J35/04 ,  B01J38/10 ,  B01J38/14 ,  B01J2219/2411 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/48 ,  C07C2521/06 ,  C07C2521/14 ,  C07C2521/16 ,  C07C2523/62 ,  C07C2527/22 ,  C07C2527/224 ,  C07C2527/24 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/167 ,  C07C15/46

公开(公告)号：EP2739386A1

公开(公告)日：2014-06-11

申请号：EP12740993.6

申请日：2012-08-01

Applicant: BASF SE

Inventor： OLBERT, Gerhard ,  WEGERLE, Ulrike ,  KOLIOS, Grigorios ,  KOSTOVA, Albena

IPC: B01J19/00 ,  B01J19/24 ,  B01J38/14 ,  C07C5/48

CPC classification number: B01J19/2485 ,  B01J19/0013 ,  B01J19/0026 ,  B01J19/0033 ,  B01J38/14 ,  B01J2219/00058 ,  B01J2219/00186 ,  B01J2219/002 ,  B01J2219/00202 ,  B01J2219/00213 ,  B01J2219/0022 ,  B01J2219/00229 ,  B01J2219/1925 ,  B01J2219/2409 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/48 ,  C07C5/50 ,  Y02P20/584 ,  C07C11/08 ,  C07C15/46 ,  C07C11/167 ,  C07C11/06

Abstract: The invention relates to a method for autothermal gas phase dehydrogenation of a hydrocarbon-containing gas stream (2) with an oxygen-containing gas stream (3), obtaining a reaction gas mixture in the presence of a heterogeneous catalyst which is constructed as a monolith (4), and regeneration of the catalyst in a reactor (1) in the form of a cylinder or prism, wherein: - the interior of the reactor (1) is subdivided by a plain cylindrical or prismatic gas-tight housing (G) that is arranged in the longitudinal direction of the reactor (1) into; - an internal region A and; - an external region B arranged coaxially to the internal region A, which is characterized in that the reactor is operated alternately in the production mode for the autothermal gas phase dehydrogenation, and in the regeneration mode, wherein: - the production mode for the autothermal gas phase dehydrogenation is run until the temperature elevation of the reaction gas mixture on exit of same from the discharge line (11) does not exceed 5 K, based on the time point from which the conversion rate fluctuates by no more than 1%, based on the final conversion rate, whereupon; - the reactor is switched into the regeneration mode, with supply of an inert regeneration gas which contains at least 10% by weight oxygen, based on the total weight of the regeneration gas.

公开(公告)号：EP2654941A1

公开(公告)日：2013-10-30

申请号：EP11802692.1

申请日：2011-12-13

Applicant: BASF SE

Inventor： OLBERT, Gerhard ,  WEGERLE, Ulrike ,  KOLIOS, Grigorios ,  KOSTOVA, Albena ,  KESSEL, Jasmina ,  WECK, Alexander ,  REZAI, Alireza

IPC: B01J19/24 ,  C07C5/48

CPC classification number: B01J19/2485 ,  B01J23/96 ,  B01J35/04 ,  B01J38/10 ,  B01J38/14 ,  B01J2219/2411 ,  B01J2219/2416 ,  B01J2219/2419 ,  B01J2219/2422 ,  B01J2219/2443 ,  C07C5/48 ,  C07C2521/06 ,  C07C2521/14 ,  C07C2521/16 ,  C07C2523/62 ,  C07C2527/22 ,  C07C2527/224 ,  C07C2527/24 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/167 ,  C07C15/46

Abstract: The invention relates to a reactor (1) in the form of a horizontal cylinder (3) for carrying out autothermal gas phase dehydration of a hydrocarbon-containing gas flow (2) with an oxygen-containing gas flow (3), yielding a reaction gas mixture, at a heterogeneous catalyst designed as a monolith (4), wherein the inner chamber of the reactor (1) is divided by a removable, circular cylindrical or prismatic housing G, which is disposed in the longitudinal direction of the reactor (1) and is gas-tight in the circumferential direction, into an inner area A having one or more catalytically active zones (5), in each of which a package of monoliths (4) stacked on each other, adjacent to each other, and arranged one behind the other is provided, a mixing zone (6) having fixed installed fixtures being provided in front of each active zone (5), and into an outer area B disposed coaxially to the inner area A, and wherein a heat exchanger (12) connected to the housing G is provided at an end of the reactor, characterized in that an inert gas is supplied to the outer area B.

公开(公告)号：EP4282815A1

公开(公告)日：2023-11-29

申请号：EP22175357.7

申请日：2022-05-25

Applicant: BASF SE

Inventor： KAPPERT, Emiel Jan ,  OPITZ, Bastian ,  VARGAS SCHMITZ, Juergen Jose ,  KOLIOS, Grigorios ,  SCHLERETH, David

IPC: C01B3/04 ,  B01D53/22 ,  C01B3/50

Abstract: The present invention relates to processes for recovering H 2 from converting NH 3 in an apparatus, the processes comprising one or more process stages, and an apparatus for these processes.

公开(公告)号：EP3981054A1

公开(公告)日：2022-04-13

申请号：EP20727667.6

申请日：2020-05-28

Applicant: BASF SE ,  thyssenkrupp AG ,  thyssenkrupp Industrial Solutions AG

Inventor： SCHEIFF, Frederik ,  KOLIOS, Grigorios ,  BODE, Andreas

IPC: H02J3/28 ,  H02J3/38 ,  H02J3/14 ,  H02J15/00

公开(公告)号：EP3744154A1

公开(公告)日：2020-12-02

申请号：EP19701109.1

申请日：2019-01-22

Applicant: BASF SE

Inventor： APPEL, Hagen ,  BERNNAT, Jens ,  GLENK, Friedrich ,  KOLIOS, Grigorios ,  OLBERT, Gerhard ,  SCHEIFF, Frederik ,  ZOELS, Bernd ,  KERN, Matthias ,  FLICK, Dieter ,  ANDERLOHR, Christopher Alec ,  KLINGLER, Dirk ,  WECHSUNG, Achim

IPC: H05B3/00 ,  F27D11/04 ,  H05B3/60