Abstract:
본 발명은 리쏘그래픽 공정에 유용한 반사방지성을 갖는 하드마스크 조성물에 관한 것으로, 본 발명에 따른 조성물은 매우 우수한 광학적 특성, 기계적 특성을 제공하며, 동시에 스핀-온 도포 기법을 이용하여 도포 가능한 특성을 제공한다. 특히, 본 발명의 조성물은 드라이 에칭 내성이 매우 우수한 박막으로서 높은 에스펙트비를 갖는 패턴을 형성할 수 있는 패턴형성용 다층막 및 패턴형성방법을 제공한다. 리쏘그래픽, 반사방지성, 하드마스크, 방향족 고리, 드라이 에칭 내성
Abstract:
A bottom anti-reflective coating composition and a method for making a patterned material form on a substrate are provided to minimize the reflectivity between a resist and back layer in performing lithography technique. A bottom anti-reflective coating composition comprises a compound of the chemical formula 3. In the chemical formula 3, Q- is anion and contains one on the chemical formula 4. The composition also contains: a polymer containing an aromatic ring of the chemical formula 1; a compound of the chemical formula 3; and an organic solvent. In the chemical formula 1, 1
Abstract:
본 발명은 리쏘그래픽 공정에 유용한 반사방지성을 갖는 하드마스크 조성물을 제공하기 위하여 하기 화학식 1 내지 3 중 어느 하나로 표시되는 방향족 고리 (aromatic ring) 함유 공중합체 및 상기 공중합체를 포함하는 것을 특징으로 하는 하드마스크 조성물을 제공한다. [화학식 1]
[화학식 2]
[화학식 3]
(상기 식에서, 1≤m 0 는 -OH, 탄소수 1~7의 -C n H 2n OH 이고, R 1 는 중 어느 하나이며, R 2 는 -O-, 탄소수 1~7의 -C n H 2n O- 이고, R 3 ~ R 7 는 각각 독립적으로 수소 (-H), 히드록시기 (-OH), C 1-10 의 알킬기, C 6-10 의 아릴기, 알릴기 및 할로겐 원자 중 어느 하나이다.) 본 발명에 따른 조성물은 매우 우수한 광학적 특성, 기계적 특성을 제공하며, 동시에 스핀-온 도포 기법을 이용하여 도포 가능한 특성을 제공한다. 특히, 본 발명의 조성물은 드라이 에칭 내성이 매우 우수한 박막으로서 높은 에스펙트비를 갖는 패턴을 형성할 수 있는 패턴형성용 다층막 및 패턴형성방법을 제공한다. 리쏘그래픽, 반사방지성, 하드마스크, 방향족 고리, 드라이 에칭 내성, 카본 함량
Abstract:
A copolymer containing an aromatic ring, an antireflective hard mask composition containing the copolymer, and a method for forming a patterned shape on a substrate by using the composition are provided to improve optical properties, mechanical properties and etching selectivity. A copolymer containing an aromatic ring is represented by the formula 1 or 2, wherein l, m and n are an integer of 1-190; R1 is H, OH, a C1-C10 alkyl group, a C6-C10 aryl group, an allyl group or a halogen atom; R2 is -CH2-, -H2C-Ph-CH2-, -H2C-Ph-Ph-CH2-, -C(OH-substituted Ph)H-, or -C(Ph)H-; R3 is a conjugated diene; and R4 is an unsaturated dienophile. An antireflective hard mask composition comprises 1-25 wt% of the copolymer; and 75-99 wt% of an organic solvent.
Abstract:
A hard mask composition having anti-reflective property is provided to minimize reflection between a resist layer and a backside layer, to realize excellent optical and mechanical properties and high etching selectivity during a lithographic process. A hard mask composition having anti-reflective property comprises: (a) an aromatic ring-containing polymer including at least one compound represented by the following formula 1 or 2; and (b) an organic solvent. In formula 1, n ranges from 1 to 190; R1 is a specific fused aromatic ring radical; R2 is an ethylene radical containing an aromatic ring or not; and each of X and Y represents H or OH. In formula 2, each of m and n is equal to or greater than 1 and less than 190 and m+n is equal to or greater than 3 and equal to or less than 190; each of R1 and R2 represents a specific fused aromatic ring radical; each of R3 and R4 represents an ethylene radical containing an aromatic ring or not; and each of X, Y and Z represents H or OH.
Abstract:
A hardmask composition for resist underlayers is provided to ensure anti-reflective characteristics and ensure a lithography process margin. An anti-reflective hardmask composition includes an aromatic ring-containing polymer represented by any one selected from the following formulae 1-3, and an organic solvent. The aromatic ring-containing polymer is contained in an amount of 1-30 parts by weight based on 100 parts by weight of the organic solvent, and has a weight average molecular weight of 1,000-30,000. The hardmask composition further comprises a cross-linking agent and a catalyst.
Abstract:
PURPOSE: A hard mask composition, a pattern forming method using the same, a semiconductor integrated circuit device including patterns are provided to secure resistance to multi-etching and to improve optical characteristic. CONSTITUTION: A hard mask composition includes an aromatic ring containing compound with either a part represented by chemical formula 1 or a part represented by chemical formula 2. In chemical formula 1 or 2, Ar is an aromatic cyclic group; R1 to R3 are respectively single bonds, substituted or non-substituted C1 to C30 alkylene groups, substituted or non-substituted C3 to C30 cycloalkylene groups, substituted or non-substituted C6 to C30 arylene groups, substituted or non-substituted C3 to C30 cycloalkenylene groups, substituted or non-substituted C7 to C20 arylalkylene groups, substituted or non-substituted C1 to C20 heteroalkylene groups, substituted or non-substituted C2 to C30 heterocycloalkylene groups, substituted or non-substituted C2 to C30 heteroarylene groups, substituted or non-substituted C2 to C30 alkenylene groups, substituted or non-substituted C2 to C30 alkynylene groups, or the combination of the same; and n is 1 to 100.
Abstract:
PURPOSE: A hard mask composition, a method for forming patterns using the same, and a semiconductor integrated circuit device including the patterns are provided to improve optical characteristic and to secure resistance to multiple etching. CONSTITUTION: A hard mask composition includes a compound with an aromatic ring represented by chemical formula 1 and a solvent. In chemical formula 1, A is an aromatic ring; R1 to R6 are respectively substituted or non-substituted C1 to C20 alkyl groups, substituted or non-substituted C3 to C30 cycloalkyl groups, substituted or non-substituted C6 to C30 aryl groups, substituted or non-substituted C3 to C30 cycloalkenyl groups, or substituted or non-substituted C7 to C20 arylalkyl groups, substituted or non-substituted C1 to C20 heteroalkyl groups, substituted or non-substituted C2 to C30 heterocycloalkyl groups, substituted or non-substituted C2 to C30 heteroaryl groups, substituted or non-substituted C2 to C30 alkenyl groups, substituted or non-substituted C2 to C30 alkynyl groups, substituted or non-substituted C1 to C30 alkoxyl groups, or the combination of the same; X1 to C6 are respectively C1 to C20 alkyl groups, substituted or non-substituted C3 to C30 cycloalkyl groups, substituted or non-substituted C6 to C30 aryl groups, substituted or non-substituted C1 to C30 alkoxyl groups, substituted or non-substituted C1 to C20 alkylamine groups, amino groups, hydroxyl groups, or the combination of the same; n1 to n6 are respectively 0 or 1; and the sum of n1 to n6 is between 1 and 6, inclusively.
Abstract:
PURPOSE: A polymer is provided to strong absorption in deep UV range and etching selectivity and to minimize reflection between a resist and lower layer. CONSTITUTION: A polymer has a repeat unit of chemical formula 1. The polymer composition contains a first polymer with a repeat unit of chemical formula 1 and a second polymer with repeat unit of chemical formula 2, *-[-Ar_3-X-]-*. A resist lower layer composition contains 1-20 weight% of polymer composition, 75-98.8 weight% of organic solvent, 0.1-5 weight% of cross linking ingredient, and 0.001-0.05 weight% of acid catalyst.
Abstract:
PURPOSE: An aromatic ring-containing polymer is provided to ensure high etching selectivity and to minimize reflection between the resist and backside layer. CONSTITUTION: An aromatic ring-containing polymer contains a repeat unit of chemical formulas 1 and 2. In chemical formula 1, R1-R3 are different or same hydrogen, hydroxyl group, halogen, substituted or non-substituted alkyl group, substituted or non-substituted aryl group, and substituted or non-substituted heteroaryl; x is 0 or 1; y is 03 integer; z is 0-2 integer; and A is substituted or non-substituted straight or branched alkylene group.