公开(公告)号：ES2107721T3

公开(公告)日：1997-12-01

申请号：ES94111539

申请日：1994-07-23

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS DR ,  POLANEK PETER DR ,  IRGANG MATTHIAS DR ,  PETERSEN HERMANN DR ,  LINDEN GERD DR ,  VOIT GUIDO DR

IPC: B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  B01J37/08 ,  C07B61/00 ,  C07C209/48 ,  C07C209/50 ,  C07C211/36

Abstract: Cobalt catalysts whose catalitically active composition consists of from 55 to 98% by wt. of cobalt, from 0.2 to 15% by wt. of phosphorus, from 0.2 to 15% by wt. of manganese and from 0.2 to 15% by wt. of alkali, calculated as oxide, by calcining the catalyst composition in a first step at final temperatures of from 550 to 750 DEG C and in a second step at final temperatures of from 800 to 1000 DEG C and also a process for hydrogenating organic nitriles and/or imines by use of the new cobalt catalysts.

公开(公告)号：DE4428994A1

公开(公告)日：1996-02-22

申请号：DE4428994

申请日：1994-08-16

Applicant: BASF AG

Inventor： SCHNURR WERNER DR ,  FISCHER ROLF DR ,  WULFF-DOERING JOACHIM DR ,  IRGANG MATTHIAS DR

IPC: B01J23/10 ,  C07C45/41 ,  C07C67/313 ,  C07C47/54 ,  C07C47/542 ,  C07C47/544 ,  C07C47/575 ,  C07C67/30 ,  C07C69/76

Abstract: Prodn. of an aromatic aldehyde of formula (I) comprises treating the corresp. carboxylic acid of formula (II) with hydrogen in the gas phase at 200-450 deg C, 0.1-20 bar in the presence of a catalyst (III). (III) has a catalytic mass comprising 80-99.9 wt.% zirconium oxide and 0.1-20 wt.% one or more lanthanide elements. R1, R2 = H, 1-6C alkyl, 3-8C cycloalkyl, aryl, OH, 1-4C alkoxy, phenoxy, 7-12C alkylphenyl, 7-12C phenylalkyl, NH2, NHMe, NMe2 or halo; R3 = as R, or COOR4; R' = as R3 or formyl; R4 = H, 1-6C alkyl, 3-8C cycloalkyl, aryl, 7-12C alkyl phenyl or 7-12C phenyl alkyl.

公开(公告)号：DE3717111C2

公开(公告)日：1996-02-22

申请号：DE3717111

申请日：1987-05-21

Applicant: BASF AG

Inventor： EICHHORN HANS-DIETER DR ,  GRUENDLER KARL-HEINZ DR ,  IRGANG MATTHIAS DR ,  SCHACHNER HELMUT DR ,  SPRAGUE MICHAEL JOLYON DR

IPC: B01J23/00 ,  B01J23/80 ,  B01J37/03 ,  B01J37/08 ,  C01B3/16

公开(公告)号：DE4325847A1

公开(公告)日：1995-02-02

申请号：DE4325847

申请日：1993-07-31

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS DR ,  POLANEK PETER DR ,  IRGANG MATTHIAS DR ,  PETERSEN HERMANN DR ,  LINDEN GERD DR ,  VOIT GUIDO DR ,  WITZEL TOM DR

IPC: B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  B01J37/08 ,  C07B61/00 ,  C07C209/48 ,  C07C209/50 ,  C07C211/36 ,  B01J23/74 ,  C07C209/52

Abstract: Cobalt catalysts whose catalitically active composition consists of from 55 to 98% by wt. of cobalt, from 0.2 to 15% by wt. of phosphorus, from 0.2 to 15% by wt. of manganese and from 0.2 to 15% by wt. of alkali, calculated as oxide, by calcining the catalyst composition in a first step at final temperatures of from 550 to 750 DEG C and in a second step at final temperatures of from 800 to 1000 DEG C and also a process for hydrogenating organic nitriles and/or imines by use of the new cobalt catalysts.

公开(公告)号：ES2053646T3

公开(公告)日：1994-08-01

申请号：ES88113657

申请日：1988-08-23

Applicant: BASF AG

Inventor： WAMBACH LUDWIG DR ,  IRGANG MATTHIAS DR ,  FISCHER MARTIN DR

IPC: C07C47/54 ,  B01J23/745 ,  B01J31/20 ,  C07B61/00 ,  C07C45/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/542 ,  C07C67/00

公开(公告)号：DE58904053D1

公开(公告)日：1993-05-19

申请号：DE58904053

申请日：1989-07-22

Applicant: BASF AG

Inventor： SCHOMMER CHARLES DR ,  EBEL KLAUS DR ,  DOCKNER TONI DR ,  IRGANG MATTHIAS DR ,  HOELDERICH WOLFGANG DR ,  RUST HARALD

IPC: B01J21/06 ,  B01J23/04 ,  C07B61/00 ,  C07C45/00 ,  C07C45/48 ,  C07C45/74 ,  C07C49/04 ,  C07C49/76 ,  C07C49/792 ,  C07C67/00 ,  C07D213/50

公开(公告)号：DE3920280A1

公开(公告)日：1991-01-03

申请号：DE3920280

申请日：1989-06-21

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  IRGANG MATTHIAS DR ,  RUST HARALD ,  EBEL KLAUS DR ,  SCHOMMER CHARLES DR

IPC: B01J23/04 ,  C07C45/48 ,  C07D213/50

Abstract: In a new process for the prodn of ketone of formula R1-C0-R2 (I) by reaction of a carboxylic acid of formula R1-C00H (IIa) with a carboxylic acid of formula (IIb) or with a ketone of formula (Ib) or of a mixture of (IIa), R2-C00H (IIb) and R2C0-R2 (Ia) in the gas phase in the presence of a catalyst, a catalyst is used in which at least 50% of the active mass consists of titanium dioxide and which has a specific surface of greater than 10 sq metres/gramme. In (I)-(IIb) R1, R2 = alkyl, cycloalkyl, arylalkyl, aryl or heteroaryl, at least one of R1 and R2 carrying at least one H-atom in the alpha-position.

公开(公告)号：DE3665134D1

公开(公告)日：1989-09-28

申请号：DE3665134

申请日：1986-06-14

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  BIFFAR WERNER DR ,  IRGANG MATTHIAS DR ,  MROSS WOLF DIETER DR ,  KROENER MICHAEL DR ,  AMBACH EBERHARD DR

IPC: B01J23/06 ,  B01J23/84 ,  B01J23/85 ,  B01J23/88 ,  B01J27/18 ,  B01J27/188 ,  B01J27/198 ,  B01J27/199 ,  B01J35/04 ,  C01B3/16 ,  C07B61/00 ,  C07C1/00 ,  C07C5/333 ,  C07C15/46 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C233/03

Abstract: A honeycomb catalyst consisting of from 30 to 95% by weight, calculated as Fe2O3, of an iron compound and from 0.1 to 60% by weight, calculated as Al2O3, CeO2 or Cr2O3, of an aluminum, cerium and/or chromium compound and/or from 1 to 50% by weight of an alkali metal compound, in particular potassium, calculated as K2O, and/or from 0.2 to 20% by weight, calculated as MeO3, of an element of sub-group 6, preferably MoO3 and WO3, and/or from 0.1 to 20% by weight, calculated as V2O5, of a compound of vanadium and/or from 0.1 to 20% by weight, calculated as P2O5, of a compound of phosphorus, a process for the preparation of the honeycomb catalyst, and the use of the catalyst for organic reactions.

公开(公告)号：AT45684T

公开(公告)日：1989-09-15

申请号：AT86108178

申请日：1986-06-14

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  BIFFAR WERNER DR ,  IRGANG MATTHIAS DR ,  MROSS WOLF DIETER DR ,  KROENER MICHAEL DR ,  AMBACH EBERHARD DR

IPC: B01J23/06 ,  B01J23/84 ,  B01J23/85 ,  B01J23/88 ,  B01J27/18 ,  B01J27/188 ,  B01J27/198 ,  B01J27/199 ,  B01J35/04 ,  C01B3/16 ,  C07B61/00 ,  C07C1/00 ,  C07C5/333 ,  C07C15/46 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C233/03

公开(公告)号：DE3710433A1

公开(公告)日：1988-10-06

申请号：DE3710433

申请日：1987-03-28

Applicant: BASF AG

Inventor： MAROSI LASZLO DR ,  STABENOW JOACHIM DR ,  EGER KNUT DR ,  IRGANG MATTHIAS DR ,  ZIRKER GUENTER DR

IPC: B01J23/72 ,  B01J37/30 ,  C01B33/20 ,  C01B33/22 ,  B01J23/74

Abstract: Amorphous metal/magnesium silicates of the general formula MxMgy(SiO2).nH2O. where M is a divalent, reducible metal atom from the group consisting of Cu, FeII, Co and Ni, x and y are numbers which together can add up to a value of 1.5 and n after drying, expressed in % by weight, ranges from 0 to 80 are prepared by subjecting a freshly precipitated magnesium silicate to an ion exchange, washing the product and then neutralizing it with an alkali and are used in catalytic reactions after the reducible metal in the metal/magnesium silicates has been converted into the metallic state with a reducing gas.