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公开(公告)号:BG104789A
公开(公告)日:2001-09-28
申请号:BG10478900
申请日:2000-09-20
Applicant: BASF AG
Inventor: BREINER ULRIKE , JULIUS MANFRED , NEUBERG RAINER , WEISS ROBERT , WILMS AXEL , HU HARRY Y
Abstract: The invention relates to a method for producing polyamides, characterized in that the polymerization of starting monomers or starting oligomers is carried out in the presence of at least one compound of formula where R is a functional group R8 which has 1 to 4 identical or different amide-forming groups R7; R1 is H, C1-C20 alkyl, cycloalkyl, benzyl, OR6 where R6 is H, C1-C20 alkyl, cycloalkyl, benzyl; R2, R3, R4, R5 independently of each other are C1-C10 alkyl; n is a natural number greater than 1, and the piperidine derivatives linked to R are identical to or different from the substituents, that is R1, R2, R3, R4 and R5. Said polyamides can be used to produce thread, fibres, films, flat structures and moulded bodies. 13 claims
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公开(公告)号:PL343068A1
公开(公告)日:2001-07-30
申请号:PL34306899
申请日:1999-03-18
Applicant: BASF AG
Inventor: BREINER ULRIKE , JULIUS MANFRED , NEUBERG RAINER , WEISS ROBERT , WILMS AXEL , HU HARRY Y
Abstract: A process for preparing polyamides comprises polymerizing starting monomers or starting oligomers in the presence of at least one compound of the formula (I)whereR is a functional group R which bears 1-4 identical or different amide-forming groups R ,R is H, C1-C20-alkyl, cycloalkyl, benzyl or OR , where R is H, C1-C20-alkyl, cycloalkyl or benzyl,R , R , R and R are independently C1-C10-alkyl,n is a natural number greater than 1, andthe piperidine derivatives attached to R are identical or different with regard to the substituents, meaning R , R , R , R and R .The polyamides are useful for preparing filaments, fibers, films, sheetlike structures and moldings.
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公开(公告)号:CO5060545A1
公开(公告)日:2001-07-30
申请号:CO99007887
申请日:1999-02-10
Applicant: BASF AG
Inventor: ILG OTTO , BREINER ULRIKE , JULIUS MANFRED
IPC: C08G69/00 , C08G69/48 , C08K5/3435
Abstract: Un método para la obtención de una poliamida inherentementeestabilizada a la luz y al calor, que comprende someter uno o más monómeros formadores de poliamida a un proceso de polimerización en presencia de (a) una cantidad activa de, como mínimo un compuesto de piperidina representado por la fórmula (I): donde R1 significa hidrógeno, bencilo, o un C1 -C20 alquilo, R2 -R5 significan cada uno hidrógeno o C1 -C6 alquilo idéntico o diferente, X tiene n sitios de unión de valencia libre y significan alquilo o alquilo sustituido con aprox. 1 hasta 30 átomos de carbono o arilo o arilo sustituido con aproxi. 6 hasta aprox. 20 átomos de carbono, m es 0 ó 1, -C(O)-R6 es un grupo que puede formar un enlace de amida junto con una amida, y n es 1, 2, ó 3, y (b) como mínimo, un compuesto de 4-amino-2,2,6,6- tetrametilpiperidina representado por la fórmula (II): donde R7 significa hidrógeno, bencilo, o C1 -C20 alquilo. 1Una poliamida inherentemente estabilizada a la luz y al calor que comprende (a) un polímero de respaldo que posee dos extremos terminales de cadena, (b) por lo menos un radical piperidilo ligado a un extremo de la cadena polímera de respaldo de la poliamida inherentemente estabilizada a la luz y al calor, ...
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公开(公告)号:BR9906843A
公开(公告)日:2000-10-17
申请号:BR9906843
申请日:1999-02-12
Applicant: BASF AG
Inventor: ILG OTTO , BREINER ULRIKE , JULIUS MANFRED
IPC: C08G69/00 , C08G69/48 , C08K5/3435
Abstract: An inherently light- and heat-stabilized polyamide has at least one piperidine compound bonded to the backbone polymer chain and at least one 4-amino-2,2,6,6-tetramethylpiperidine compound bonded to the backbone polymer chain. The inherently light- and heat-stabilized polyamide may be used to form articles such as, for example, fibers, carpets, yarns, and textile fabrics.
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公开(公告)号:ZA9901130B
公开(公告)日:2000-08-14
申请号:ZA9901130
申请日:1999-02-12
Applicant: BASF AG
Inventor: ILG OTTO , BREINER ULRIKE , JULIUS MANFRED
CPC classification number: C08G69/48 , C08K5/3435 , Y10T428/2969 , Y10T428/2971 , Y10T442/162 , Y10T442/179 , Y10T442/198 , Y10T442/3894 , C08L77/00
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公开(公告)号:CZ20001042A3
公开(公告)日:2000-07-12
申请号:CZ20001042
申请日:1998-09-25
Applicant: BASF AG
Inventor: JULIUS MANFRED , SIEGEL HARDO , WITZEL TOM , SIEGEL WOLFGANG
IPC: C07D211/58
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公开(公告)号:ES2140208T3
公开(公告)日:2000-02-16
申请号:ES97903354
申请日:1997-02-21
Applicant: BASF AG
Inventor: JULIUS MANFRED , ETTL ROLAND , GUNTHER WOLFGANG , GREINDL THOMAS
IPC: C10L1/234 , C07C235/80 , C07C235/88 , C07C255/25 , C08F8/00 , C08F8/30 , C08F8/32 , C10L1/14 , C10L1/18 , C10L1/22 , C10L1/224 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10L10/08 , C10M133/16 , C10M133/24 , C10M133/52 , C10M133/54 , C10M149/12
Abstract: Compounds of the general formula Iwheren is 0 or 1,Z is a straight-chain or branched polyalkyl radical having a number average molecular weight of from about 150 to 40,000, andY is a radical of the formula IIa or IIb wherethe radicals R, R1 and R2 independently of one another, are each hydrogen, an unsubstituted or substituted alkyl, alkenyl or alkynyl radical or an unsubstituted or substituted cycloalkyl, aryl or arylalkyl radical, which may carry one or more heteroatoms, andA is an alkyleneimine radical; or, ifn is 0, one of the radicals Y may be a polyoxyalkylene radical,and processes for their preparation and fuel and lubricant compositions, and mixtures of additives, which contain the novel compounds.
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公开(公告)号:AU9746998A
公开(公告)日:1999-04-23
申请号:AU9746998
申请日:1998-09-25
Applicant: BASF AG
Inventor: JULIUS MANFRED , SIEGEL HARDO , WITZEL TOM , SIEGEL WOLFGANG
IPC: C07D211/58
Abstract: The invention relates to a method for purifying 2,2,6,6-tetrasubstituted 4-amino-piperidines produced from the corresponding piperidin-4-ones, and subsequent distillation. According to the invention, the distilled 2,2,6,6-tetrasubstituted 4-amino-piperidine is reacted with hydrogen in the presence of a hydrating or dehydrating catalyst and the 4-amino piperidine is then separated from the reaction mixture.
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49.
公开(公告)号:AU6623098A
公开(公告)日:1998-10-12
申请号:AU6623098
申请日:1998-02-23
Applicant: BASF AG
Inventor: ETTL ROLAND , SCHUHMACHER RUDOLF , BONN JOHANN , REUTHER WOLFGANG , UTECHT JENS , JULIUS MANFRED
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公开(公告)号:CA2257095A1
公开(公告)日:1997-12-11
申请号:CA2257095
申请日:1997-05-30
Applicant: BASF AG
Inventor: SIEGEL HARDO , RUST HARALD , SIEGEL WOLFGANG , WITZEL TOM , KRAUSE ALFRED , JULIUS MANFRED
IPC: C07D211/58 , C07D211/56 , C07D221/20
Abstract: A process for purifying raw piperidines of formula (I), where R1 to R4 are C1 to C6 alkyl, R1 and R2 and/or R3 and R4 together are a CH2 chain with 2 to 5 C atoms. Said process is characterized in that in an initial step high-boiling-point substances and possible water are eliminated by distillation from the raw piperidines, in a second step 0.01 to 5 wt %, in relation to the product of the first step, of a reducing agent are added and in a third step the piperidines are isolated by distillation.
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