METHOD FOR PRODUCING LONG-CHAIN GLYCINE-N,N-DIACETIC ACID DERIVATIVES
    1.
    发明申请
    METHOD FOR PRODUCING LONG-CHAIN GLYCINE-N,N-DIACETIC ACID DERIVATIVES 审中-公开
    用于生产长链甘氨酸-N,N-二乙酸衍生物

    公开(公告)号:WO9910314A3

    公开(公告)日:1999-07-01

    申请号:PCT/EP9805220

    申请日:1998-08-17

    CPC classification number: C07C229/08 C07C229/16 C07C253/00 C07C255/25

    Abstract: The invention relates to a method for producing compounds of general formula (IIb), wherein R represents C6-C30 alkyl or C6-C30 alkenyl which can also support up to 5 hydroxyl groups, formyl groups, C1-C4 alkoxy groups, phenoxy groups or C1-C4 alkoxycarbonyl groups as substituents and which can be interrupted by up to 5 non-adjacent oxygen atoms, or alkoxylate groupings of formula -(CH2)k-O-(A O)m-(A O)n - Y, wherein A and A represent 1,2 alkylene groups with 2 to 4 C-atoms, Y represents hydrogen, C1-C12 alkyl, phenyl, or C1-C4 alkoxycarbonyl, k represents the number 1, 2 or 3 and m and n each represent numbers from 0 to 50, the sum of m and n being at least 4, independently of each other. According to the inventive method, iminodiacetonitrile is reacted with aldehydes of general formula R-CHO and HCN or alkali cyanides. The method is carried out a) without using an organic solvent and in the presence of a Lewis or Bronsted acid, or b) with or without an organic solvent and in the presence of an emulsifier, or c) with or without an organic solvent and at a pressure of 1 to 40 bar.

    Abstract translation: 在对通式(IIb)的化合物的制备方法,其中R是C6至C30的烷基或C6至C30链烯基,其还携带作为取代基的最多5个羟基,甲酰基,C1至C4烷氧基,苯氧基或C1 - 承载一个至C4烷氧基羰基和可被最多5个不相邻的氧原子,或下式的烷氧基化物基团被中断 - (CH 2)CO(A <1> O)间 - (甲<2> O)N - ÿ 是,表示其中A <1>和A <2>独立地表示1,2-亚烷基基团的碳原子数为2〜4,Y是氢,C 1至C 12表示烷基,苯基或C1-C4烷氧羰基并且k 数字1,2或3,且m和n各自为从0到50,其中m的+ n之和必须至少是4,亚氨基二乙腈与通式R-CHO的醛和HCN或碱金属氰化物反应,则 方法a),而不使用有机溶剂的和在路易斯存在 或布朗斯台德酸,或者b))的使用或不使用有机溶剂的和在1至40巴,使用或不使用有机溶剂的和在乳化剂,或c的存在的范围内的压力下进行。

    5.
    发明专利
    未知

    公开(公告)号:DE10051196A1

    公开(公告)日:2002-05-08

    申请号:DE10051196

    申请日:2000-10-16

    Applicant: BASF AG

    Abstract: Cyanoalkylation of ammonia or organic compounds containing one or more NH functions, by reaction with a carbonyl compound and hydrocyanic acid in a solvent, is carried out in two stages comprising a first stage (i) at a temperature (T1) below the boiling point of the reaction mixture, and a second stage (i) at a temperature (T2) below 150 degrees C. Cyanoalkylation of ammonia or organic compounds containing one or more NH functions, by reaction with a carbonyl compound and hydrocyanic acid (each at 1 mol per NH function to be converted) in a solvent, is carried out in two stages comprising a first stage (i) at a temperature (T1) below the boiling point of the reaction mixture, carried out until the degree of HCN conversion is at least 60% and a second stage (i) at a temperature (T2) below 150degreesC, carried out until the degree of HCN conversion is at least 90%. An Independent claim is included for alpha -cyanoalkylamines (I) obtained by the process.

    6.
    发明专利
    未知

    公开(公告)号:ES2163610T3

    公开(公告)日:2002-02-01

    申请号:ES96901284

    申请日:1996-01-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00169 Sec. 371 Date Jul. 28, 1997 Sec. 102(e) Date Jul. 28, 1997 PCT Filed Jan. 17, 1996 PCT Pub. No. WO96/22964 PCT Pub. Date Aug. 1, 1996The use of triacids of the formula I where X1 to X3 are, independently of one another, carboxylic acid groups of the formula COOM, sulfonic acid groups of the formula SO3M or phosphonic acid groups of the formula PO3M2, where M is hydrogen, alkali metal, ammonium or substituted ammonium, A1 to A3 are, independently of one another, 1,2-alkylene with 2 to 18 carbon atoms, R1 to R3 are, independently of one another, C1-C8-alkylene, and x, y and z are, independently of one another, a number from 0 to 10, where the total of x+y+z must be greater than or equal to 1, as complexing agents for complexing heavy metals or for preparing heavy metal complexes for changing the redox potential, and as builders in detergents and cleaners.

    7.
    发明专利
    未知

    公开(公告)号:AT205183T

    公开(公告)日:2001-09-15

    申请号:AT96901284

    申请日:1996-01-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/00169 Sec. 371 Date Jul. 28, 1997 Sec. 102(e) Date Jul. 28, 1997 PCT Filed Jan. 17, 1996 PCT Pub. No. WO96/22964 PCT Pub. Date Aug. 1, 1996The use of triacids of the formula I where X1 to X3 are, independently of one another, carboxylic acid groups of the formula COOM, sulfonic acid groups of the formula SO3M or phosphonic acid groups of the formula PO3M2, where M is hydrogen, alkali metal, ammonium or substituted ammonium, A1 to A3 are, independently of one another, 1,2-alkylene with 2 to 18 carbon atoms, R1 to R3 are, independently of one another, C1-C8-alkylene, and x, y and z are, independently of one another, a number from 0 to 10, where the total of x+y+z must be greater than or equal to 1, as complexing agents for complexing heavy metals or for preparing heavy metal complexes for changing the redox potential, and as builders in detergents and cleaners.

    10.
    发明专利
    未知

    公开(公告)号:AT187976T

    公开(公告)日:2000-01-15

    申请号:AT97921715

    申请日:1997-04-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/02062 Sec. 371 Date Oct. 22, 1998 Sec. 102(e) Date Oct. 22, 1998 PCT Filed Apr. 23, 1997 PCT Pub. No. WO97/40088 PCT Pub. Date Oct. 30, 1997Process for preparing fine-particle, water-insoluble polymers of aziridines by polymerizing aziridines, preferably ethylenimine, in the presence of crosslinkers which contain at least two functional groups, and in at least one ether, and also modified, water-insoluble polymers of aziridines which can be obtained by reacting fine-particle, water-insoluble, crosslinked polymers of aziridines, in aqueous medium, with carbon disulfide or formaldehyde and a nucleophilic agent from the group consisting of alkali metal cyanides, primary amines, secondary amines, alkali metal sulfites and alkali metal phosphites, and use of the modified and non-modified fine-particle, water-insoluble polymers for immobilizing active compounds, as absorbents for aldehydes, ketones and acids, and also for removing heavy metal ions from wastewaters.

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