Zpusob prípravy kyseliny (meth)akrylové

    公开(公告)号:CZ298267B6

    公开(公告)日:2007-08-08

    申请号:CZ43697

    申请日:1997-02-12

    Applicant: BASF AG

    Abstract: Postup prípravy kyseliny (meth)akrylové zahrnující následující stupne: (I) katalytickou oxidaci propenu nebo izobutenu a/nebo akroleinu nebo methakroleinu v plynné fázi na kyselinu (meth)akrylovou zavzniku plynného reakcního produktu obsahujícího kyselinu (meth)akrylovou; (II) absorpci tohoto reakcního produktu za použití vysokovroucího rozpouštedla; (III) rozdelení rozpouštedla s absorbovaným produktem ze stupne (I), které se získá ve stupni (II), na rozpouštedlo a surovou (meth)akrylovou kyselinu pomocí destilace; (IV) vycištení surové (meth)akrylové kyseliny ze stupne (III) krystalizací za vzniku (meth)akrylové kyseliny; a (V) recirkulaci prinejmenším cásti výsledného matecného louhu dostupne (II) a/nebo stupne (III).

    47.
    发明专利
    未知

    公开(公告)号:ES2168664T3

    公开(公告)日:2002-06-16

    申请号:ES97938814

    申请日:1997-07-09

    Applicant: BASF AG

    Abstract: A process for preparing acrylic acid or methacrylic acid comprises(a) preparing a gaseous product mixture having essentially the composition of a reaction mixture of the catalytic gas phase oxidation of C3-/C4-alkanes, -alkenes, -alkanols and/or -alkanals and/or precursors thereof to form acrylic acid or methacrylic acid, characterized by(b) condensing said product mixture,(c) crystallizing acrylic acid or methacrylic acid from the solution obtained in step (b), and(d) removing the resulting crystals from the mother liquor.

    48.
    发明专利
    未知

    公开(公告)号:DE59803651D1

    公开(公告)日:2002-05-08

    申请号:DE59803651

    申请日:1998-09-09

    Applicant: BASF AG

    Abstract: A process for preparing acrylic acid or methacrylic acid comprises preparing a gaseous product mixture having essentially the composition of a reaction mixture of the catalytic gas phase oxidation of C3-/C4-alkanes, -alkenes, -alkanols and/or -alkanals and/or precursors thereof to form acrylic acid or methacrylic acid. The product is removed from the gaseous product mixture by a process comprising the following steps:(a) condensing said gaseous product mixture,(b) crystallizing acrylic acid or methacrylic acid from the solution obtained in step (a),(c) removing the resulting crystals from the mother liquor, and(d) recycling at least a portion of said mother liquor from step (c) into step (a).

    49.
    发明专利
    未知

    公开(公告)号:DE59706057D1

    公开(公告)日:2002-02-21

    申请号:DE59706057

    申请日:1997-07-09

    Applicant: BASF AG

    Abstract: A process for preparing acrylic acid or methacrylic acid comprises(a) preparing a gaseous product mixture having essentially the composition of a reaction mixture of the catalytic gas phase oxidation of C3-/C4-alkanes, -alkenes, -alkanols and/or -alkanals and/or precursors thereof to form acrylic acid or methacrylic acid, characterized by(b) condensing said product mixture,(c) crystallizing acrylic acid or methacrylic acid from the solution obtained in step (b), and(d) removing the resulting crystals from the mother liquor.

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