公开(公告)号：ZA967618B

公开(公告)日：1998-03-10

申请号：ZA967618

申请日：1996-09-10

Applicant: BASF AG

Inventor： SCHULZ MICHAEL ,  TELES JOAQUIM HENRIQUE ,  SUNDERMEYER JOERG ,  WAHL GUENTHER

IPC: B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  C07B61/00 ,  C07D301/06 ,  C07D301/12 ,  C07D303/04 ,  B01J ,  C07D

Abstract: PCT No. PCT/EP96/03888 Sec. 371 Date Mar. 11, 1998 Sec. 102(e) Date Mar. 11, 1998 PCT Filed Sep. 4, 1996 PCT Pub. No. WO97/10054 PCT Pub. Date Mar. 20, 1997Olefins can be epoxidized using catalysts I where M is a metal of the 4th to 7th transition group of the Periodic Table of the Elements, L1 is an amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligand of the formula II, III, VII or VIII, L2 is a customary auxiliary ligand or a further ligand L1 or a free coordination site, X is oxo oxygen or an imido ligand, m is 1 or 2, and n is 1, 2 or 3.

公开(公告)号：AU3093197A

公开(公告)日：1998-01-07

申请号：AU3093197

申请日：1997-05-30

Applicant: BASF AG

Inventor： MULLER ULRICH ,  GROSCH GEORG HEINRICH ,  HAUER BERNHARD ,  SCHULZ MICHAEL ,  RIEBER NORBERT

IPC: B01J29/04 ,  B01J29/89 ,  C07D301/12 ,  C07D301/19

Abstract: A process for producing epoxides from olefines and hydrogen peroxide or hydroperoxides in the liquid phase using an oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure, in which the concentration of the hydrogen peroxide or hydroperoxides in the reaction mixture is in the range from 0.05 to less than 1 wt.% during the reaction.

公开(公告)号：AU3030997A

公开(公告)日：1998-01-07

申请号：AU3030997

申请日：1997-05-30

Applicant: BASF AG

Inventor： GROSCH GEORG HEINRICH ,  MUELLER ULRICH ,  SCHULZ MICHAEL ,  RIEBER NORBERT ,  WUERZ HARALD

IPC: C07D301/06 ,  B01J29/04 ,  B01J29/89 ,  C07D301/04 ,  C07D301/10 ,  C07D303/04

Abstract: PCT No. PCT/EP97/02821 Sec. 371 Date Dec. 14, 1998 Sec. 102(e) Date Dec. 14, 1998 PCT Filed May 30, 1997 PCT Pub. No. WO97/47386 PCT Pub. Date Dec. 18, 1997An oxidation catalyst based on titanium silicalites or vanadium silicalites having a zeolite structure and containing from 0.01 to 30% by weight of one or more noble metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver has been molded by a compacting shaping process. This oxidation catalyst is used for the preparation of epoxides, in particular propylene oxide, from olefins, hydrogen and oxygen.

公开(公告)号：BR9607257A

公开(公告)日：1997-12-30

申请号：BR9607257

申请日：1996-02-10

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  SCHNURR WERNER ,  FISCHER ROLF ,  RIEBER NORBERT ,  SCHULZ MICHAEL

IPC: C07C45/41 ,  C07D301/14 ,  C07D303/04

Abstract: PCT No. PCT/EP96/00578 Sec. 371 Date Aug. 5, 1997 Sec. 102(e) Date Aug. 5, 1997 PCT Filed Feb. 10, 1996 PCT Pub. No. WO96/26198 PCT Pub. Date Aug. 29, 1996Preparation of epoxides from olefins by means of aromatic peroxycarboxylic acids comprises a step A of epoxidizing the olefin and removing the resulting aromatic carboxylic acid from the epoxide, a step B of catalytically hydrogenating the removed aromatic carboxylic acid to the corresponding aromatic aldehyde, and a step C of oxidizing this aldehyde with oxygen or an oxygen-containing gas mixture back to the aromatic peroxycarboxylic acid for re-use for epoxidizing an olefin.

公开(公告)号：CA2256395A1

公开(公告)日：1997-12-18

申请号：CA2256395

申请日：1997-05-30

Applicant: BASF AG

Inventor： GROSCH GEORG HEINRICH ,  SCHULZ MICHAEL ,  RIEBER NORBERT ,  HAUER BERNHARD ,  MUELLER ULRICH

IPC: B01J29/04 ,  B01J29/89 ,  C07D301/12 ,  C07D301/19 ,  C07D303/04

Abstract: A process for producing epoxides from olefines and hydrogen peroxide or hydroperoxides in the liquid phase using an oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure, in which the concentration of the hydrogen peroxide or hydroperoxides in the reaction mixture is in the range from 0.05 to less than 1 wt.% during the reaction.

公开(公告)号：CA2248545A1

公开(公告)日：1997-09-12

申请号：CA2248545

申请日：1997-03-05

Applicant: BASF AG

Inventor： HARDER WOLFGANG ,  MUELLER ULRICH ,  MAROSI LASZLO ,  SCHULZ MICHAEL

IPC: C07D301/08 ,  B01J27/18 ,  B01J27/185 ,  B01J27/24 ,  B01J37/02 ,  C01B15/029 ,  C07D301/12 ,  C07B33/00 ,  C07C39/04 ,  C07D303/04 ,  C07C37/60

Abstract: The invention concerns a catalyst composition which is free from noble metals and is obtained by: a) preparing an aqueous mixture which comprises: i) a salt of at least one base metal selected from elements having the atomic numbers 21 to 32, 39 to 42, 48 to 51, 57 to 75 and 81 to 83; ii) phosphate ions; and iii) at least one nitrogen source; and b) concentrating the aqueous mixture produced and drying the resultant catalyst compound. The invention further concerns the preparation of this composition and its use in the production of hydrogen peroxide and the epoxidation of olefins.

公开(公告)号：AU4830796A

公开(公告)日：1996-09-11

申请号：AU4830796

申请日：1996-02-10

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  SCHNURR WERNER ,  FISCHER ROLF ,  RIEBER NORBERT ,  SCHULZ MICHAEL

IPC: C07C45/41 ,  C07D301/14 ,  C07D303/04

Abstract: PCT No. PCT/EP96/00578 Sec. 371 Date Aug. 5, 1997 Sec. 102(e) Date Aug. 5, 1997 PCT Filed Feb. 10, 1996 PCT Pub. No. WO96/26198 PCT Pub. Date Aug. 29, 1996Preparation of epoxides from olefins by means of aromatic peroxycarboxylic acids comprises a step A of epoxidizing the olefin and removing the resulting aromatic carboxylic acid from the epoxide, a step B of catalytically hydrogenating the removed aromatic carboxylic acid to the corresponding aromatic aldehyde, and a step C of oxidizing this aldehyde with oxygen or an oxygen-containing gas mixture back to the aromatic peroxycarboxylic acid for re-use for epoxidizing an olefin.

公开(公告)号：DE50014201D1

公开(公告)日：2007-05-10

申请号：DE50014201

申请日：2000-07-26

Applicant: BASF AG

Inventor： AUER HEINZ ,  DAHLHAUS JUERGEN ,  FISCHER KARL ,  HAMMER HANS ,  KELLENBENZ JOCHEN ,  SCHULZ MICHAEL ,  THIEL JOACHIM ,  VICARI MAXIMILIAN

IPC: B01D3/00 ,  C07C67/36 ,  B01J3/00 ,  B01J3/02 ,  B01J19/00 ,  C07B61/00 ,  C07C29/80 ,  C07C31/04 ,  C07C69/06

Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.

公开(公告)号：DE102004058886A1

公开(公告)日：2006-06-08

申请号：DE102004058886

申请日：2004-12-06

Applicant: BASF AG

Inventor： GRAFMANS HORST ,  MAAS STEFFEN ,  WECK ALEXANDER ,  RUETTER HEINZ ,  SCHULZ MICHAEL ,  ROS KARL-HEINZ

IPC: C07C231/02 ,  C07C233/05

Abstract: A process for preparing N,N-dimethylacetamide (DMAC) by continuously reacting methyl acetate (MeOAc) with dimethylamine (DMA) in the presence of a basic catalyst, wherein MeOAc is used in the form of a methanolic solution which is obtained as a by-product in the preparation of polyTHF by transesterifying polyTHF diacetate with methanol.

公开(公告)号：ES2232203T3

公开(公告)日：2005-05-16

申请号：ES99968384

申请日：1999-12-23

Applicant: BASF AG

Inventor： DAHLHAUS JURGEN ,  KARL JORN ,  SCHULZ MICHAEL ,  WENZEL ANNE ,  HARDER WOLFGANG ,  HOHN ARTHUR

IPC: B01J23/04 ,  B01J31/40 ,  C07B61/00 ,  C07C231/10 ,  C07C233/03

Abstract: Procedimiento para la obtención de formamida mediante reacción de amoniaco y monóxido de carbono en presencia de al menos un catalizador y al menos un alcohol en un reactor, caracterizado porque la mezcla de reacción que contiene formamida se traslada del reactor a una instalación separada, y se elabora en la misma, y el catalizador presente como metanolato sódico y/o diformilamida sódica se separa en esta instalación, y se devuelve al reactor o componente de una mezcla que contiene formamida.