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    Process for the preparation of a titanium-containing catalyst component for Ziegler catalyst systems
    46.
    发明专利
    Process for the preparation of a titanium-containing catalyst component for Ziegler catalyst systems 未知

    公开(公告)号：DE3435389A1

    公开(公告)日：1986-04-03

    申请号：DE3435389

    申请日：1984-09-27

    Applicant: BASF AG

    Inventor： STAIGER GERHARD DR ,  SCHWEIER GUENTHER DR

    IPC: C08F4/50 ,  C08F4/64 ,  C08F10/00

    Abstract: The invention relates to the preparation of a titanium-containing catalyst component (1) for Ziegler catalyst systems, by reacting (1.1) in a first step (1.1.1) a preparation of (1.1.1.1) a titanium compound (I) and (1.1.1.2) a liquid alkane (II) and (1.1.2) a homogeneous solution of (1.1.2.1) a benzene hydrocarbon (III), (1.1.2.2) trichloroacetic acid (IV) and (1.1.2.3) magnesium ethylate (V) with one another, giving a suspended solid (VI), and then (1.2) in a second step isolating the solid (VI), washing it with an alkane (VII) and drying it, the resultant solid being the catalyst component (1), characterised in that (I) employed in (1.1.1) under (1.1.1.1) is a finely divided titanium compound of the formula TiCl3 . x AlCl3, where x = from 0.15 to 0.40, and (III) employed in (1.1.2) under (1.1.2.1) is toluene.

    Process for the preparation of homo- and copolymers of alpha -monoolefins by means of a Ziegler catalyst system
    48.
    发明专利
    Process for the preparation of homo- and copolymers of alpha -monoolefins by means of a Ziegler catalyst system 未知

    公开(公告)号：DE3406675A1

    公开(公告)日：1985-09-05

    申请号：DE3406675

    申请日：1984-02-24

    Applicant: BASF AG

    Inventor： STAIGER GERHARD DR ,  SCHWEIER GUENTHER DR

    IPC: C08F4/10 ,  C08F4/12 ,  C08F4/16 ,  C08F10/00 ,  C08F4/52

    Abstract: The invention relates to the homopolymerisation and copolymerisation of alpha -monoolefins by means of a Ziegler catalyst system comprising (1) a titanium catalyst component obtained by (1.1) in a first step (1.1.1) reacting a preparation of (1.1.1.1) a titanium compound (I) and (1.1.1.2) a liquid alkane (II) and (1.1.2) a homogeneous solution of (1.1.2.1) a benzene hydrocarbon (III), (1.1.2.2) trichoroacetic acid (IV) and (1.1.2.3) magnesium ethylate (V) with one another, giving a suspended solid (VI), and then (1.2) in a second step isolating the solid (VI), washing it with an alkane (VII) and drying it; the solid obtained here is the catalyst component (1) and (2) an aluminium catalyst component which is conventional in this context, characterised in that (1) is a titanium catalyst component obtained by employing as (I) in (1.1.1) under (1.1.1.1) a finely divided titanium compound of the formula TiCl3 . xAlCl3 , where x is 0.15 to 0.40, and, as (III) in (1.1.2) under (1.1.2.1), toluene.

    PROCESS FOR PRODUCING HOMO AND COPOLYMERS OF ALPHA-OLEFINS WITH A ZIEGLER TYPE CATALYTIC SYSTEM
    50.
    发明专利
    PROCESS FOR PRODUCING HOMO AND COPOLYMERS OF ALPHA-OLEFINS WITH A ZIEGLER TYPE CATALYTIC SYSTEM 未知

    公开(公告)号：DE3164993D1

    公开(公告)日：1984-08-30

    申请号：DE3164993

    申请日：1981-04-09

    Applicant: BASF AG

    Inventor： BACHL ROBERT DR ,  KLAERNER PETER DR ,  SCHWEIER GUENTHER DR ,  EHLERS EHLER

    IPC: C08F4/64 ,  C08F10/00

    Abstract: A process for the preparation of homopolymers and copolymers of alpha -monoolefins by polymerizing the monomer or monomers with a Ziegler catalyst system comprising (1) a titanium-containing catalyst component and (2) a relevant conventional organo-aluminum compound, (1.1) the catalyst component (1) having been prepared by (1.1.1) milling a titanium compound (I) of the formula TiCl3.z(AlCl3) or ClmTi(OB)4-m, where z is from 0 to 0.5, m is from 0 to 3 and B is alkyl, together with (1.1.2) a magnesium alcoholate (II) and, if desired, (1.1.3) a metal chloride (III) of the formula AlCl3, ZnCl2 or MnCl2, to form a milled product (IV), in which polymerization process a catalyst component (1) is employed, in the preparation of which (1.2) the milled product (IV) obtained according to (1.1) is brought together, in an additional step (1.2.1), with (1.2.2) an alkanol (V) and (1.2.3) a liquid alkane (VI), to form a suspension (VII), and thereafter (1.3), in a further additional step (1.3.1), there is added, to the suspension (VII) obtained according to (1.2), (1.3.2) a metal compound (VIII) of a certain type, the metal being aluminum, silicon or titanium, while preserving the suspension state, the product (IX), which results from stage (1.3) and is present as a solid phase in the suspension, constituting the titanium-containing catalyst component (1).

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