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公开(公告)号:DE3676283D1
公开(公告)日:1991-01-31
申请号:DE3676283
申请日:1986-10-27
Applicant: BASF AG
Inventor: JAGGARD JAMES F R DR , WERNER RAINER ALEXANDER DR , GRUBER WOLFGANG DR
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2.
公开(公告)号:DE3262988D1
公开(公告)日:1985-05-15
申请号:DE3262988
申请日:1982-07-15
Applicant: BASF AG
Inventor: JAGGARD JAMES F R DR , BEST WALTER DR , KLAERNER PETER DR , BLEI PETER
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公开(公告)号:AT12650T
公开(公告)日:1985-04-15
申请号:AT82106337
申请日:1982-07-15
Applicant: BASF AG
Inventor: JAGGARD JAMES F R DR , BEST WALTER DR , KLAERNER PETER DR , BLEI PETER
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公开(公告)号:DE3322937A1
公开(公告)日:1985-01-03
申请号:DE3322937
申请日:1983-06-25
Applicant: BASF AG
Inventor: JAGGARD JAMES F R DR , SCHOENE WERNER DR , SCHWEIER GUENTHER DR
IPC: C08F4/12 , C08F4/14 , C08F4/16 , C08F10/06 , C08K3/22 , C08K3/26 , C08K5/10 , C08K5/53 , C08L23/10
Abstract: The invention relates to a process for the preparation of homopolymers and copolymers of propylene by means of a Ziegler-Natta catalyst system comprising (1) a certain titanium halide (titanium trichloride/aluminium chloride cocrystallizate), (2) a certain oxygen compound (ester), (3) an alkylaluminium compound and (4) a certain phenolic substance, which is characterised in that, in a separate process step, the polymer is homogenised and extruded without other interim treatment together with small amounts of (A) a complex compound of formula [Mg1-xAlx(OH)2+x.m'H2O]n, where x = 0.1 to 0.5, m' = 0 to 2, and n' = 3 to 12, (B) pentaerythrityl tetrakis [3-(3,5-di-t-butyl-4-hydroxyphenyl)]propionate, (C) tetrakis (2,4-di-t-butylphenyl)-4,4-diphenyl diphosphonite, and (D) calcium stearate, with melting of the polymer, giving polymers which have particularly good applicational properties.
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5.
公开(公告)号:DE3160412D1
公开(公告)日:1983-07-14
申请号:DE3160412
申请日:1981-05-07
Applicant: BASF AG
Inventor: JAGGARD JAMES F R DR , KLAERNER PETER DR , SCHWEIER GUENTHER DR
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公开(公告)号:AT59190T
公开(公告)日:1991-01-15
申请号:AT86114928
申请日:1986-10-27
Applicant: BASF AG
Inventor: WERNER RAINER ALEXANDER DR , JAGGARD JAMES F R DR , GRUBER WOLFGANG DR
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公开(公告)号:DE3580535D1
公开(公告)日:1990-12-20
申请号:DE3580535
申请日:1985-07-03
Applicant: BASF AG
Inventor: STAIGER GERHARD DR , JAGGARD JAMES F R DR , GRUBER WOLFGANG DR , WERNER RAINER ALEXANDER DR
IPC: C08F4/14 , C08F4/16 , C08F4/64 , C08F10/06 , C08F110/06
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公开(公告)号:DE3540699A1
公开(公告)日:1987-05-27
申请号:DE3540699
申请日:1985-11-16
Applicant: BASF AG
Inventor: JAGGARD JAMES F R DR , WERNER RAINER ALEXANDER DR , GRUBER WOLFGANG DR
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公开(公告)号:DE3540698A1
公开(公告)日:1987-05-21
申请号:DE3540698
申请日:1985-11-16
Applicant: BASF AG
Inventor: WERNER RAINER ALEXANDER DR , JAGGARD JAMES F R DR , GRUBER WOLFGANG DR
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公开(公告)号:DE3322938A1
公开(公告)日:1985-01-10
申请号:DE3322938
申请日:1983-06-25
Applicant: BASF AG
Inventor: JAGGARD JAMES F R DR , SCHOENE WERNER DR , SCHWEIER GUENTHER DR
IPC: C08F4/12 , C08F4/14 , C08F4/16 , C08F6/02 , C08F10/06 , C08K3/22 , C08K3/26 , C08K5/10 , C08K5/53 , C08L23/10
Abstract: The invention relates to a process for the preparation of homopolymers and copolymers of propylene by means of a Ziegler-Natta catalyst system comprising (1) a certain titanium halide (titanium trichloride/aluminium chloride cocrystallizate), (2) a certain oxygen compound (ester), (3) an alkylaluminium compound and (4) a certain phenolic substance, which is characterised in that, in a separate process step, the polymer is homogenised and extruded without other interim treatment together with small amounts of (A) a complex compound of formula MgxAly(OH)2x+3y-2z(CO3)z.aH2O, where x = 3 to 8, y = 1 to 3, z = 0.5 to 2 and a = 0 to 6, (B) pentaerythrityl tetrakis [3-(3,5-di-t-butyl-4-hydroxyphenyl)]propionate, (C) tetrakis (2,4-di-t-butylphenyl)-4,4-diphenyl diphosphonite, and (D) calcium stearate, with melting of the polymer, giving polymers which have particularly good applicational properties.
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