公开(公告)号：FI971175A0

公开(公告)日：1997-03-20

申请号：FI971175

申请日：1997-03-20

Applicant: BASF AG

Inventor： BECKER RAINER ,  SIGWART CHRISTOPH ,  HESSE MICHAEL ,  FISCHER ROLF ,  ELLER KARSTEN ,  HEILEN GERD ,  PLITZKO KLAUS-DIETER

IPC: B01J23/24 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26 ,  C08G65/28 ,  C08G

Abstract: PCT No. PCT/EP95/03651 Sec. 371 Date Mar. 10, 1997 Sec. 102(e) Date Mar. 10, 1997 PCT Filed Sep. 21, 1995 PCT Pub. No. WO96/09335 PCT Pub. Date Mar. 28, 1996A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C1-C10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C1-C10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500 DEG to 1000 DEG C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.

公开(公告)号：MY120420A

公开(公告)日：2005-10-31

申请号：MYPI9700229

申请日：1997-01-22

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH ,  HEINEKE DANIEL ,  FLICK KLEMENS

IPC: B01J23/36 ,  B01J23/44 ,  B01J23/46 ,  B01J37/16 ,  C07B61/00 ,  C07D301/00 ,  C07D303/04

Abstract: A PROCESS FOR PREPARING 1,2-BUTYLENE OXIDE BY CATALYTIC HYDROGENATION OF VINYLOXIRANE OVER A HETEROGENEOUS CATALYST COMPRISES USING A CATALYST PREPARED BY APPLYING AT LEAST ONE ELEMENT OF GROUPS 7 TO 11 OF THE PERIODIC TABLE IN THE FORM OF A SOL TO AN INERT SUPPORT.

公开(公告)号：ES2231718T3

公开(公告)日：2005-05-16

申请号：ES02748813

申请日：2002-06-24

Applicant: BASF AG

Inventor： SCHLITTER STEPHAN ,  SIGWART CHRISTOPH ,  DORFLINGER WALTER ,  HESSE MICHAEL ,  FISCHER ROLF-HARTMUTH

IPC: B01J21/16 ,  B01J35/10 ,  C08G65/20 ,  C08G65/26

Abstract: Catalizador para la obtención de politetrahidrofurano, copolímeros de politetrahidrofurano, diésteres o monoésteres de estos polímeros mediante polimerización de tetrahidrofurano en presencia de al menos un telógeno y/o comonómero estando presente el mismo en forma de cuerpos moldeados de catalizador o partículas de catalizador con un volumen del cuerpo moldeado o partícula individual de al menos 0, 05 mm3, preferentemente de al menos 0, 2 mm3 y particularmente de 0, 1 mm3 y mostrando este catalizador ambas características a) y b): a)Distribución de radios de poros con al menos un máximo de la distribución de poros en el intervalo de 100 hasta 5000 A de radios de poros, y b)Volumen de poros de poros de catalizador con radios de 2oo a 3000 A mayor que 0, 05 cm3/g y/o radios de 200 a 5000 A mayor que 0, 075 cm3/g y/o un radio de > 200 A mayor que 0, 1 cm3/g.

公开(公告)号：DE59807875D1

公开(公告)日：2003-05-15

申请号：DE59807875

申请日：1998-05-06

Applicant: BASF AG

Inventor： ELLER KARSTEN ,  STEIN FRANK ,  SIGWART CHRISTOPH ,  BECKER RAINER ,  PLITZKO KLAUS-DIETER ,  FISCHER ROLF ,  MUELLER ULRICH

IPC: C08G65/10 ,  B01J29/04 ,  B01J29/89 ,  C08G59/68 ,  C08G65/06 ,  C08G65/20 ,  C08G65/26

Abstract: A process for polymerizing cyclic ethers over a heterogeneous catalyst comprises using a heterogeneous catalyst comprising one or more pillared interlayered clays (PILCs).

公开(公告)号：AU2166702A

公开(公告)日：2002-04-22

申请号：AU2166702

申请日：2001-10-11

Applicant: BASF AG

Inventor： DERNBACH MATTHIAS ,  SIGWART CHRISTOPH ,  HESSE MICHAEL ,  MAAS STEFFEN

IPC: B01J23/44 ,  C07C29/90 ,  C07C31/22

Abstract: A process is provided for improving the color number of polyhydric alcohols, especially trimethylolpropane, by catalytic hydrogenation, the polyhydric alcohol used in the hydrogenation having been purified by distillation following its preparation, wherein the hydrogenation is carried out in the presence of a macroporous supported heterogeneous catalyst containing, as the active metal, at least one metal of subgroups VII to X of the Periodic Table.

公开(公告)号：DE10032268A1

公开(公告)日：2002-01-17

申请号：DE10032268

申请日：2000-07-03

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  NARBESHUBER THOMAS ,  SIGWART CHRISTOPH ,  BOHNER GERD ,  HESSE MICHAEL ,  FISCHER ROLF

IPC: B01J21/06 ,  B01J23/30 ,  B01J27/188 ,  B01J35/10 ,  B01J37/00 ,  C08G65/20 ,  C08G65/26 ,  B01J23/24 ,  B01J27/053

Abstract: Catalyst (A) comprises active oxygen compounds of molybdenum and/or tungsten (I) on an oxide carrier and is prepared by: (i) applying precursors of (I) to the carrier (or its precursor); and (ii) calcining at 400-900 deg C. It is characterized by having transport pores of diameter over 25 nm and transport pore volume at least 50 mm /g. Independent claims are also included for: (a) method for preparing (A); and (b) preparation of poly(tetrahydrofuran) or tetrahydrofuran (THF) copolymers (or their di- or mono-esters) by polymerization of THF in presence of at least one telogen and/or comonomer, and in presence of (A).

公开(公告)号：DE10032267A1

公开(公告)日：2002-01-17

申请号：DE10032267

申请日：2000-07-03

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  NARBESHUBER THOMAS ,  HAUBNER MARTIN ,  SIGWART CHRISTOPH

IPC: B01J21/06 ,  B01J23/30 ,  B01J27/188 ,  B01J35/10 ,  B01J37/00 ,  C08G65/20 ,  C08G65/26 ,  B01J23/24 ,  B01J27/053

Abstract: Catalyst (A) comprises active oxygen compounds of molybdenum and/or tungsten (I) on an oxide carrier and is prepared by: (i) applying precursors of (I) to the carrier (or its precursor); and (ii) calcining at 400-900 deg C. It is characterized by having transport pores of diameter over 25 nm and transport pore volume at least 50 mm /g. Independent claims are also included for: (a) method for preparing (A); and (b) preparation of poly(tetrahydrofuran) or tetrahydrofuran (THF) copolymers (or their di- or mono-esters) by polymerization of THF in presence of at least one telogen and/or comonomer, and in presence of (A).

公开(公告)号：CZ288130B6

公开(公告)日：2001-04-11

申请号：CZ24498

申请日：1996-07-26

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH ,  FISCHER ROLF ,  ELLER KARSTEN ,  BECKER RAINER ,  PLITZKO KLAUS-DIETER ,  HEILEN GERD

IPC: C08G18/48 ,  C08G18/67 ,  C08G63/66 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26 ,  C08G65/28 ,  C08G69/40

Abstract: In the present invention there is disclosed a process for preparing copolymers of tetrahydrofuran and but-2-ine-1,4-diol by catalytic polymerization of tetrahydrofuran: The invented preparation process is characterized by polymerization on a heterogeneous acidic polymerization catalyst having acidity of acid centers pKia less than + 2 at concentration of at least 0.005 mmole per one gram of the catalyst, in the presence of but-2-ine-1,4-diol, being present particularly in an amount ranging from 0.04 to 17 molar percent based on tetrahydrofuran. In this preparation process there can be used a series of polymerization catalyst. It is preferred when the catalyst selected contains a molybdenum or tungsten compound. Preferably the catalyst can be doped with a sulfur or phosphorus compound, too.

公开(公告)号：DE59606394D1

公开(公告)日：2001-03-01

申请号：DE59606394

申请日：1996-08-29

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH ,  HARTH KLAUS ,  FISCHER ROLF

IPC: B01J23/36 ,  B01J23/42 ,  C07D303/04 ,  B01J23/44 ,  B01J23/46 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B01J37/02 ,  B01J37/34 ,  C07B61/00 ,  C07D301/00 ,  C23C14/18 ,  C23C16/06

Abstract: PCT No. PCT/EP96/03799 Sec. 371 Date Mar. 5, 1998 Sec. 102(e) Date Mar. 5, 1998 PCT Filed Aug. 29, 1996 PCT Pub. No. WO97/09321 PCT Pub. Date Mar. 13, 19971,2-Butylene oxide is prepared by catalytic hydrogenation of vinyloxirane over a heterogeneous catalyst produced by depositing one or more catalytically active elements of groups 7 to 11 of the Periodic Table of the Elements from the gas phase onto an inert, nonmetallic support.

公开(公告)号：PL179471B1

公开(公告)日：2000-09-29

申请号：PL31930095

申请日：1995-09-21

Applicant: BASF AG

Inventor： BECKER RAINER ,  SIGWART CHRISTOPH ,  HESSE MICHAEL ,  FISCHER ROLF ,  ELLER KARSTEN ,  HEILEN GERD ,  PLITZKO KLAUS-DIETER

IPC: B01J23/24 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26 ,  C08G65/28

Abstract: PCT No. PCT/EP95/03651 Sec. 371 Date Mar. 10, 1997 Sec. 102(e) Date Mar. 10, 1997 PCT Filed Sep. 21, 1995 PCT Pub. No. WO96/09335 PCT Pub. Date Mar. 28, 1996A process for the preparation of polytetrahydrofuran or polytetrahydrofuran monoesters of C1-C10 monocarboxylic acids by the polymerization of tetrahydrofuran over a heterogeneous catalyst in the presence of one of the telogens water, 1,4-butanediol or polytetrahydrofuran having a molecular weight of from 200 to 700 dalton or a C1-C10 monocarboxylic acid or mixtures of these telogens, wherein a supported catalyst is used as catalyst, which contains a catalytically active amount of an oxygen-containing tungsten or molybdenum compound or mixtures of these compounds on an oxidic support material and which was calcined at temperatures ranging from 500 DEG to 1000 DEG C. following the application of the precursor compounds of said oxygen-containing molybdenum and/or tungsten compounds to the support material precursor.