公开(公告)号：CA2461672A1

公开(公告)日：2003-04-10

申请号：CA2461672

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  KROENER HUBERTUS

IPC: C08F2/38 ,  C08F212/08 ,  C08F236/06

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by carrying out a radical aqueous emulsion polymerization of a monomer mixture M containing: 40 to 80 wt. % of styrene depicted as Monomer M1; 20 to 60 wt. % of butadiene depicted as monomer M2, and; 0 to 40 wt. %, with regard to 100 wt. % of the monomers, of ethylenically unsaturate d comonomers M3 that differ from styrene and butadiene. The polymerization is carried out according to a monomer feeding method in the presence of 0.05 to 0.5 wt. %, with regard to 100 wt. % of the monomers, of at least one hydrocarbon KW selected among compounds having 6 to 20 C atoms that form a pentadienyl radical or a 1-phenylallyl radical when a hydrogen atom is abstracted, and the .alpha.-methylstyrene dimer. The inventive method is characterized in that the monomers to be polymerized are introduced within three hours of the polymerization reaction.

公开(公告)号：DE59406985D1

公开(公告)日：1998-10-29

申请号：DE59406985

申请日：1994-06-22

Applicant: BASF AG

Inventor： WIRTH THOMAS ,  NISSLER HARALD ,  STURM BERTHOLD ,  LAWRENZ DIRK ,  SCHULER BERNHARD

IPC: C09D109/00 ,  C09D109/10 ,  C09D113/02 ,  C09D121/00 ,  C09D133/04 ,  C09D133/06 ,  D21H19/44 ,  D21H19/58

Abstract: PCT No. PCT/EP94/02034 Sec. 371 Date Mar. 29, 1996 Sec. 102(e) Date Mar. 29, 1996 PCT Filed Jun. 22, 1994 PCT Pub. No. WO95/11342 PCT Pub. Date Apr. 27, 1995Papers which are coated with a paper coating slip based on a binder containing A) from 1 to 49% by weight of polymers based on esters of acrylic acid or of methacrylic acid with a C4-C12-alkanol, having a glass transition temperature of from -80 DEG to +25 DEG C., and B) from 51 to 99% by weight of polymers based on butadiene, the stated weights being based on the sum A)+B), are used for offset printing.

公开(公告)号：DE59502829D1

公开(公告)日：1998-08-20

申请号：DE59502829

申请日：1995-01-23

Applicant: BASF AG

Inventor： LEUBE HARTMANN ,  WIRTH THOMAS ,  LAWRENZ DIRK

IPC: C08F257/02 ,  C08F265/00 ,  C08F265/04 ,  C08F265/06 ,  C09J151/00 ,  D21H17/34 ,  D21H19/20 ,  D21H19/58

Abstract: PCT No. PCT/EP95/00224 Sec. 371 Date Aug. 5, 1996 Sec. 102(e) Date Aug. 5, 1996 PCT Filed Jan. 23, 1995 PCT Pub. No. WO95/21294 PCT Pub. Date Aug. 10, 1995Binders for papercoating slips which permit uniform printability contain a polymer prepared by the seed procedure and comprising from 1 to 49% by weight of a polymer seed A) having a glass transition temperature of from -80 DEG to +25 DEG C. and based on esters of acrylic acid or methacrylic acid, and from 51 to 99% by weight of ethylenically unsaturated monomers B), from 10 to 100% by weight of which monomers are butadiene, the polymer seed A being added before or during the polymerization of the ethylenically unsaturated monomers.

公开(公告)号：CA2230827A1

公开(公告)日：1997-03-27

申请号：CA2230827

申请日：1996-09-13

Applicant: BASF AG

Inventor： GULBINS ERICH ,  RAU MARIA GYOPAR ,  WIRTH THOMAS ,  MELDER JOHANN-PETER ,  KOKEL NICOLAS ,  ETTL ROLAND ,  LARBIG HARALD

IPC: C08L75/04 ,  C08G18/08 ,  C08G18/12 ,  C08G18/38 ,  C08G18/40 ,  C08G18/50 ,  C08G18/83 ,  C09D175/04 ,  C14C11/00 ,  C08G18/65 ,  C09D11/10

Abstract: The invention concerns aqueous dispersions containing a polyurethane (A), containing structural units derived from compounds of formula (I), in which the substituents have the following meanings: R1, R2, R3 each designate hydrogen, C1-C24 alkyl or C6 - C24 alkenyl; R4 designates hydrogen; R5, R6 a) together designate C4-C10 alkane-diyl, b) each designate C2-C10 alkyl, C5-C8 cycloalkyl or C7-C20 aralkyl, c) each designate a hydroxyl-terminated poly(C2C4 alkylene oxide), or d) designate an R5 or R6 group with the meaning given in (a) to (c) and the other group designating hydrogen or a group of formula (II), in which X designates C2-C6 alkane-diyl; and R7 has the same meaning as R5 or R6 with the exception that R7 is not a group of formula II, R5 and R6 carrying a total of between 2 and 5 hydroxyl groups bonded to aliphatic carbon atoms; and R5 and/or R6 optionally carrying 1 or 2 aromatically bonded hydroxyl groups or 1 nitrile, tertiary amino, carboxylic acid or sulphonic acid group which are optionally present in the form of their salts.

公开(公告)号：FI961679A0

公开(公告)日：1996-04-17

申请号：FI961679

申请日：1996-04-17

Applicant: BASF AG

Inventor： WIRTH THOMAS ,  NISSLER HARALD ,  STURM BERTHOLD ,  LAWRENZ DIRK ,  SCHULER BERNHARD

IPC: C09D109/00 ,  C09D109/10 ,  C09D113/02 ,  C09D121/00 ,  C09D133/04 ,  C09D133/06 ,  D21H19/44 ,  D21H19/58 ,  D21H ,  C08L

Abstract: PCT No. PCT/EP94/02034 Sec. 371 Date Mar. 29, 1996 Sec. 102(e) Date Mar. 29, 1996 PCT Filed Jun. 22, 1994 PCT Pub. No. WO95/11342 PCT Pub. Date Apr. 27, 1995Papers which are coated with a paper coating slip based on a binder containing A) from 1 to 49% by weight of polymers based on esters of acrylic acid or of methacrylic acid with a C4-C12-alkanol, having a glass transition temperature of from -80 DEG to +25 DEG C., and B) from 51 to 99% by weight of polymers based on butadiene, the stated weights being based on the sum A)+B), are used for offset printing.

公开(公告)号：CA2461947C

公开(公告)日：2011-05-24

申请号：CA2461947

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F2/22 ,  C08F212/08 ,  C08F2/38 ,  C08F212/00 ,  C08F236/00 ,  C08F236/06 ,  C08F236/10 ,  C08F291/00

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by the radical aqueous emulsion-polymerisation of a monomer mixture M, containing: between 40 and 80 wt. % styrene as monomer M1; between 20 and 60 wt. % butadiene as monomer M2 and between 0 and 40 wt. %, (in relation to l00 wt. % monomers), of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene, according to a monomer feed process in the presence of between 0.05 and 0.5 wt. %, (in relation to l00 wt. % monomers), of at least one hydrocarbon KW comprising between 6 and 20 C atoms, selected from compounds, which form a pentadienyl or a 1-phenylallyl radical during the abstraction of a hydrogen atom, or from .alpha.-methylstyrene dimers. Said method is characterised in that at least 30 % of the hydrocarbon KW is already present in the polymerisation vessel and the residual quantity of the hydrocarbon KW is fed to the polymerisation reaction during the course of the latter.

公开(公告)号：CA2461675C

公开(公告)日：2010-09-21

申请号：CA2461675

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  KROENER HUBERTUS

IPC: C08F2/22 ,  C08F212/08 ,  C08F2/16 ,  C08F2/38 ,  C08F212/00 ,  C08F236/00 ,  C08F236/10

Abstract: The invention relates to a method for producing an aqueous styrene-butadiene polymer dispersion by the radical aqueous emulsion-polymerisation of a monomer mixture M, containing: between 40 and 80 wt. % styrene as monomer M1; between 20 and 60 wt. % butadiene as monomer M2 and between 0 and 40 wt. %, (in relation to l00 wt. % monomers), of ethylenically unsaturated comonomers M3 that differ from styrene and butadiene, according to a monomer feed process in the presence of between 0.05 and 0.5 wt. %, (in relation to l00 wt. % monomers), of at least one hydrocarbon KW comprising between 6 and 20 C atoms, selected from compounds, which form a pentadienyl or a 1-phenylallyl radical during the abstraction of a hydrogen atom, or from .alpha.-methylstyrene dimers. Said method is characterised in that the concentration of the butadiene in the monomer feed is increased by at least 10 wt. % in relation to the monomers in the feed process, for a period of at least 1 % of the entire feed duration, when at least 70 % of the monomers to be polymerised have been fed to the polymerisation reaction.

公开(公告)号：DE50207217D1

公开(公告)日：2006-07-27

申请号：DE50207217

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F212/08 ,  C08F2/38 ,  C08F220/04 ,  C08F220/44 ,  C08F236/06 ,  C08F236/10 ,  C08F291/00 ,  C09D5/02 ,  C09D109/06 ,  C09D109/08 ,  C09D125/10 ,  D21H17/35 ,  D21H19/58

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising styrene, butadiene, and if desired up to 30% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene; in a polymerization vessel by a monomer feed technique in the presence of a regulator system containing, based on 100% by weight of monomers, from 0.02 to 0.5% by weight of at least one hydrocarbon HC having from 6 to 20 carbon atoms, selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or 1-phenylallyl radical, and alpha-methylstyrene dimer, and from 0.3 to 2% by weight of an organic compound S containing at least one SH group wherein at least 30%, preferably at least 50%, in particular at least 80%, and with particular preference the entirety (or >95%) of hydrocarbon HC is included in the initial charge to the polymerization vessel.

公开(公告)号：AT329945T

公开(公告)日：2006-07-15

申请号：AT02779444

申请日：2002-09-30

Applicant: BASF AG

Inventor： GASCHLER WOLFGANG ,  SCHAEDLER VOLKER ,  MANDERS LAMBERTUS ,  WIRTH THOMAS ,  KROENER HUBERTUS

IPC: C08F2/38 ,  C08F212/08 ,  C08F220/04 ,  C08F220/44 ,  C08F236/06 ,  C08F236/10 ,  C09D5/02 ,  C09D109/06 ,  C09D109/08 ,  C09D125/10 ,  D21H19/58 ,  C08F291/00 ,  D21H17/35

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M comprising styrene, butadiene, and if desired up to 30% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers other than styrene and butadiene; in a polymerization vessel by a monomer feed technique in the presence of a regulator system containing, based on 100% by weight of monomers, from 0.02 to 0.5% by weight of at least one hydrocarbon HC having from 6 to 20 carbon atoms, selected from compounds which on abstraction of a hydrogen atom form a pentadienyl radical or 1-phenylallyl radical, and alpha-methylstyrene dimer, and from 0.3 to 2% by weight of an organic compound S containing at least one SH group wherein at least 30%, preferably at least 50%, in particular at least 80%, and with particular preference the entirety (or >95%) of hydrocarbon HC is included in the initial charge to the polymerization vessel.

公开(公告)号：BR0212879A

公开(公告)日：2004-10-13

申请号：BR0212879

申请日：2002-09-30

Applicant: BASF AG

Inventor： MANDERS LAMBERTUS ,  WIRTH THOMAS ,  GASCHLER WOLFGANG ,  NER HUBERTUS KR

IPC: C08F2/38 ,  C08F212/08 ,  C08F236/06

Abstract: A process for preparing an aqueous styrene-butadiene polymer dispersion by free-radical aqueous emulsion polymerization of a monomer mixture M containing from 40 to 80% by weight of styrene as monomer M1, from 20 to 60% by weight of butadiene as monomer M2, and from 0 to 40% by weight, based on 100% by weight of monomers, of ethylenically unsaturated comonomers M3 other than styrene and butadiene by a monomer feed technique in the presence of from 0.05 to 0.5% by weight, based on 100% by weight of monomers, of at least one hydrocarbon HC selected from compounds having 6 to 20 carbon atoms which on abstraction of a hydrogen atom form a pentadienyl radical or a 1-phenylallyl radical and from alpha-methylstyrene dimer comprises supplying the monomers to be polymerized to the polymerization reaction over the course of 3 hours.