Multilayer lignocellulose-containing moldings having low formaldehyde emission

    公开(公告)号:NZ607832A

    公开(公告)日:2014-06-27

    申请号:NZ60783211

    申请日:2011-08-29

    Applicant: BASF SE

    Abstract: Disclosed herein is a multilayer lignocellulose-containing molding comprising A) a middle layer or a plurality of middle layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (a) and B) a covering layer or a plurality of covering layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (b), the binder (a) being selected from the group consisting of (a1) formaldehyde resins and (a2) an organic isocyanate having at least two isocyanate groups; the binder (b) comprising the following components: an aqueous component (I) comprising (i) a polymer A which is composed of the following monomers: a) from 70 to 100% by weight of at least one ethylenically unsaturated mono- and/or dicarboxylic acid (monomer(s) A1) and b) from 0 to 30% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers A1 (monomer(s) A2) optionally (ii) a low molecular weight crosslinking agent having at least two functional groups which are selected from the group consisting of hydroxyl, carboxyl and derivatives thereof, primary, secondary and tertiary amine, epoxy, aldehyde, an organic isocyanate having at least two isocyanate groups as component (II) and, optionally, a component (III), as an aqueous dispersion, comprising one or more polymer(s) M which is/are composed of the following monomers: a) from 0 to 50% by weight of at least one ethylenically unsaturated monomer which comprises at least one epoxide and/or at least one hydroxyalkyl group (monomer(s) M1) and b) from 50 to 100% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers M1 (monomer(s) M2) and, optionally, customary additives as component (IV), and the binder (b) optionally comprises a formaldehyde scavenger.

    Multi-layer molded body containing lignocellulose and having low formaldehyde emission

    公开(公告)号:AU2011343336A1

    公开(公告)日:2013-07-11

    申请号:AU2011343336

    申请日:2011-12-14

    Applicant: BASF SE

    Abstract: The invention relates to a multi-layer molded body that contains lignocellulose, comprising A) a middle layer or a plurality of middle layers, which contain(s) particles that contain lignocellulose and which can be obtained by using a binder (a), and B) an outer layer or a plurality of outer layers, which contain(s) particles that contain lignocellulose and which can be obtained by using a binder (b), wherein the binder (a) is selected from the group comprising (a1) formaldehyde resins and (a2) an organic isocyanate having at least two isocyanate groups; wherein the binder (b) contains the following components: an aqueous component (I) containing (i) a polymer A, which is constructed from the following monomers: a) 70 to 100 wt % of at least one ethylenically unsaturated monocarboxylic acid and/or dicarboxylic acid (monomer(s) A1) and b) 0 to 30 wt % of at least one additional ethylenically unsaturated monomer that differs from the monomers A1 (monomer(s) A2), possibly (ii) a low-molecular-weight cross-linking agent having at least two functional groups, which are selected from the group comprising hydroxy, carboxylic acid and derivatives thereof, primary, secondary, and tertiary amine, epoxy, and aldehyde, an organic isocyanate having at least two isocyanate groups as component (II), and possibly a component (III) as an aqueous dispersion containing one or more polymers M, which are constructed from the following monomers: a) 0 to 50 wt % of at least one ethylenically unsaturated monomer that contains at least one epoxide group and/or at least one hydroxyalkyl group (monomer(s) M1), and b) 50 to 100 wt % of at least one additional ethylenically unsaturated monomer that differs from the monomers M1 (monomer(s) M2), and possibly common additives as component (IV), and wherein at least one middle layer (A) contains expanded plastic particles and possibly at least one outer layer B) contains expanded plastic particles, and the binder (b) possibly contains a formaldehyde scavenger.

    MULTI-LAYERED LIGNOCELLULOSIC MOLDED BODIES WITH LOW FORMALDEHYDE EMISSIONS

    公开(公告)号:RS52659B

    公开(公告)日:2013-06-28

    申请号:RSP20130012

    申请日:2009-09-09

    Applicant: BASF SE

    Abstract: The multi-layered lignocellulosic molded bodies comprise middle layer containing lignocellulosic particles and obtained through the use of binder (a), and two cover layers containing lignocellulosic particles and obtained through the use of binder (b). The binder (a) is formaldehyde resins (a1) and an organic isocyanate (a2) with two isocyanate groups. The binder (b) contains aqueous component (I) comprising polymer (A) constructed of monomers (A1) having 70-100 wt.% of ethylenically unsaturated mono- and/or dicarboxylic acids and 0-30 wt.% of other ethylenically unsaturated monomers (A2). The multi-layered lignocellulosic molded bodies comprise a middle layer containing lignocellulosic particles and obtained through the use of a binder (a), and two cover layers containing lignocellulosic particles and obtained through the use of a binder (b). The binder (a) is formaldehyde resins (a1) and an organic isocyanate (a2) with two isocyanate groups. The binder (b) contains an aqueous component (I) comprising a polymer (A) constructed of monomers (A1) having 70-100 wt.% of ethylenically unsaturated mono- and/or dicarboxylic acids and 0-30 wt.% of other ethylenically unsaturated monomers (A2) that differ from the monomers (A1), and optionally a low molecular weight cross-linking agent comprising two functional groups of hydroxy, carboxylic acid and its derivatives, primary, secondary and tertiary amine, epoxy and aldehyde, and optionally a component (II) as an aqueous dispersion comprising polymers (M) constructed from the monomers having 0-50 wt.% of ethylenically unsaturated monomer (M1) containing an epoxide group and/or hydroxyalkyl group, and 50-100 wt.% of other ethylenically unsaturated monomer (M2) that differs from the first monomer (M1), and optionally conventional additives as component (III), where the binder (b) contains formaldehyde traps and formaldehyde resin. The binder (b) consists of low molecular cross-linker as the component (II). The binder (a) consists of 70-99.9 wt.% of component (a1) and 0.1-30 wt.% of component (a2) related to the total (a1) and (a2) of the pure undiluted substances. The molded bodies are formed in the form of plate. An independent claim is included for a method for the production of multi-layered lignocellulosic molded bodies.

    MULTI-LAYERED LIGNOCELLULOSIC MOLDED BODIES WITH LOW FORMALDEHYDE EMISSIONS

    公开(公告)号:NZ591751A

    公开(公告)日:2012-09-28

    申请号:NZ59175109

    申请日:2009-09-09

    Applicant: BASF SE

    Abstract: Disclosed herein is a multilayer lignocellulose-containing molding comprising: a middle layer or a plurality of middle layers comprising lignocellulose containing particles obtained by using a binder (a) and a covering layer or a plurality of covering layers comprising lignocellulose containing particles obtained by using a binder (b), the binder (a) being selected from the group consisting of (a1) formaldehyde resins and/or (a2) an organic isocyanate having at least two isocyanate groups; the binder (b) comprising the following components: an aqueous component (I) comprising a polymer A which is composed of the following monomers: a) from 70 to 100% by weight of at least one ethylenically unsaturated mono- and/or dicarboxylic acid (monomer(s) A1) and b) from 0 to 30% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers A1 (monomer(s) A2) and, optionally, a low molecular weight crosslinker having at least two functional groups which are selected from the group consisting of hydroxyl, carboxyl and derivatives thereof, primary, secondary and tertiary amine, epoxy and aldehyde and, optionally, a component (II) as an aqueous dispersion, comprising one or more polymer(s) M which is composed of the following monomers: from 0 to 50% by weight of at least one ethylenically unsaturated monomer which comprises at least one epoxide and/or at least one hydroxyalkyl group (monomer(s) M1) and from 50 to 100% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers M1 (monomer(s) M2) and, optionally, customary additives as component (III), and, where the binder (a) comprises a formaldehyde resin, the binder (b) comprising formaldehyde scavengers.

    СПОСОБ ОБРАБОТКИ ДРЕВЕСНЫХ МАТЕРИАЛОВ

    公开(公告)号:UA95792C2

    公开(公告)日:2011-09-12

    申请号:UAA200810446

    申请日:2007-01-12

    Applicant: BASF SE

    Abstract: Данноеизобретениекасаетсяобработкидревесныхматериаловпутемнанесения, покрайнеймере, одногополиамина, приэтом (и) надревесныйматериалнаносятсмесь, содержащую, покрайнеймере, одинполиамини, вслучаенеобходимости, до 20 мас. %, впересчетенасмесь, карбамида; (ii) наилив неформованнуюмассуопилокиливолоконнаносятполиамин; (iii) насубстратпокрытия, которыйиспользуютдляобработкиповерхности, наносятполиамини/или (iv) наоткрытыеместананосятполиамин; причеммолекулярнаямассаполиаминасоставляетменее 500 г/моль, ионсодержит, покрайнеймере, 6 первичныхиливторичныхаминогрупп.

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