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公开(公告)号：FR2673950B1
公开(公告)日：1993-12-03
申请号：FR9202913
申请日：1992-03-11
Applicant: KAO CORP
Inventor： TAMURA HIROYUKI , HATTORI YASUYUKI , HASHIBA KUNIZO , TABATA OSAMU , TSUKADA KIYOSHI , FUKUOKA NORIAKI
IPC: C11B3/02 , C07C29/149 , C07C31/02 , C07C67/60
Abstract: L'invention a notamment pour objet un procédé pour produire des alcools par réduction catalytique de graisses et d'huiles ou d'esters d'acides gras par l'hydrogène en présence d'un catalyseur pour la réduction des esters. Selon l'invention, lesdites graisses et huiles ou lesdits esters d'acides gras sont préalablement traités dans une atmosphère d'hydrogène ou d'un mélange d'hydrogène et d'un gaz inerte à une température de 100 à 350degré C pour donner une teneur en soufre des graisses et huiles ou des esters d'acides gras de 0,6 ppm ou moins, en présence d'un catalyseur représenté par la formule (I) suivante: (CF DESSIN DANS BOPI) dans laquelle X représente un élément choisi parmi Fe, Zn et Cr; Y représente un élément choisi parmi Al, Si et Ti; x et y représentent chacun une proportion atomique rapportée à la proportion de Cu prise égale à 1, pourvu que x ait une valeur de 0,02 à 2,4 et y une valeur de 0 à 2,0; et z est la proportion d'oxygène satisfaisant les conditions de valences des éléments représentés par X et Y. Applications: fabrication d'alcools de haute pureté avec un bon rendement par réduction.
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公开(公告)号：DE4217839A1
公开(公告)日：1992-12-10
申请号：DE4217839
申请日：1992-05-29
Applicant: KAO CORP
Inventor： HATTORI YASUYUKI , TAMURA HIROYUKI , KADOWAKI HIDETOSHI , TSUKADA KIYOSHI
IPC: B01J23/755 , C07C27/26 , C07C29/149 , C07C67/60 , C07C69/587 , C11B3/02
Abstract: A process for producing desulfurized fats and oils or fatty acid esters, which are highly suitable as a starting material for producing alcohols via hydrogenation, at a high yield is disclosed. Desulfurized fats and oils or fatty acid esters are obtained by contacting fats and oils or fatty acid esters with a catalyst represented by the following formula (I) under a hydrogen atmosphere or a mixture of hydrogen with an inert gas: Ni.CuxOy(I) wherein x represents an atomic ratio of Cu determined by referring Ni as 1 and a value of from 0.02 to 8; and y is an atomic ratio of oxygen satisfying the valence requirements of Ni and Cu. A process for producing alcohols using the desulfurized fats and oils or fatty acid esters is also disclosed. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.
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公开(公告)号：JP2001079413A
公开(公告)日：2001-03-27
申请号：JP2000184173
申请日：2000-06-20
Applicant: KAO CORP
Inventor： MIMURA HIROSHI , KAITA JUN , FUKUOKA NORIAKI , HATTORI YASUYUKI
Abstract: PROBLEM TO BE SOLVED: To very efficiently produce a high-quality ester from a fatty acid and an alcohol by preparing a heterogeneous system catalyst which contains aluminum orthophosphate, and has a specified volume of pores of a specified diameter and a specific amount of an acid. SOLUTION: This heterogeneous system catalyst which is used for esterification reaction of a fatty acid and an alcohol is prepared in such a way that aluminum orthophosphate is contained and that a pore is 6-100 nm in diameter and 0.46 ml or more in volume and that acid volume is 0.40 mmol/g or more. A method for preparing the catalyst is preferably sedimentation which is performed by dropping an alkali such as an ammonia solution to an aqueous solution of aluminum salt mixed with orthophosphoric acid, and the desired catalyst is obtained in such a manner that the resulting sediment is treated by filtering, washing with wafer, drying, baking, and the like thereof. The composition of the catalyst is preferably within a range of 1:3-1:0.1 of the atomic ratio of aluminum atom to phosphorus atom.
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公开(公告)号：JPH1081640A
公开(公告)日：1998-03-31
申请号：JP23621996
申请日：1996-09-06
Applicant: KAO CORP
Inventor： TAMURA HIROYUKI , TAWARA HIDEO , MITSUDA YOSHINORI , HATTORI YASUYUKI
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing an unsaturated alcohol in high yield and high selectivity, while keeping the catalyst activities and double bond retaining properties for a long time and suppressing the side reaction. SOLUTION: The objective unsaturated alcohol is obtained by hydrogenating an alkyl or alkenyl ester of an unsaturated fatty acid, or a triglyceride having a long chain aliphatic unsaturated hydrocarbon group in the presence of a catalyst composition of a complex metal oxide comprising (a) zinc oxide and (b) one oxide of at least one metal selected from the group III A in the periodic table and having (1/0.01) to (1/1.2) weight ratio of (a)/(b) in the method for producing the unsaturated alcohol.
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公开(公告)号：JP2001062308A
公开(公告)日：2001-03-13
申请号：JP2000184236
申请日：2000-06-20
Applicant: KAO CORP
Inventor： MIMURA HIROSHI , KAITA JUN , FUKUOKA NORIAKI , HATTORI YASUYUKI
IPC: B01J31/14 , B01J31/26 , B01J31/28 , C07B61/00 , C07C41/50 , C07C43/315 , C07C67/03 , C07C67/08 , C07C69/26
Abstract: PROBLEM TO BE SOLVED: To obtain higher activity and durability by using a catalyst composition having a structure removing a hydrogen atom from at least one OH group in an inorganic phosphoric acid and a structure removing a hydrogen atom from at least one OH group in an organic phosphoric acid represented by a specific formula, and containing a specific metal atom such as aluminum. SOLUTION: This solid acid catalyst has structures (A) and (B), and a metal atom (C); (A): a structure obtained by removing a hydrogen atom from at least one OH group in an inorganic phosphoric acid; (B): a structure obtained by removing a hydrogen atom from at least one OH group in an organic phosphoric acid represented by formula I or formula II (wherein -R1 and -R2 are independently selected from -R, -OR, -OH and -H, and at least one of -R1 and -R2 is -R or -OR, provided that -R is a 1-22C organic group.); and (C): one or more metal atoms selected from among aluminum, gallium and iron. As a result, the catalyst exhibits higher activity and durability.
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Patent Agency Ranking
公开(公告)号：JP2989704B2
公开(公告)日：1999-12-13
申请号：JP30320291
申请日：1991-11-19
Applicant: KAO CORP
Inventor： TAMURA HIROYUKI , FUKUOKA NORIAKI , HATTORI YASUYUKI , TSUKADA KIYOSHI
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公开(公告)号：JPH11244710A
公开(公告)日：1999-09-14
申请号：JP5163098
申请日：1998-03-04
Applicant: KAO CORP
Inventor： IITAKA KAZUHIRO , TAMURA HIROYUKI , HORIO MASAMITSU , MITSUTA YOSHINORI , HATTORI YASUYUKI
Abstract: PROBLEM TO BE SOLVED: To provide a catalyst keeping a high yield and high selectivity in continuous reaction and a method for producing unsaturated alcohol using this catalyst. SOLUTION: A powdery catalyst precursor comprising a mixture of a zinc compd. and a compd. of at least one kind of element selected froup group 3A elements or the Periodic Table is produced to be baked and molded and this molded object is further baked to produce a catalyst compsn. consisting of (a) zinc oxide and (b) metal oxide comprising oxide of at least one kind of a metal selected from group 3A metal elements in the same and characterized in that at wt. ratio (a)/(b)=1/0.01-1/1.2 and this catalyst is used to produce unsaturated alcohol.
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48.发明专利
公开(公告)号：JPH0663406A
公开(公告)日：1994-03-08
申请号：JP22384392
申请日：1992-08-24
Applicant: KAO CORP
Inventor： HATTORI YASUYUKI , MIMURA HIROSHI , TSUKADA KIYOSHI
IPC: B01J23/80 , B01J23/94 , C07B61/00 , C07C29/149
Abstract: PURPOSE:To regenerate a catalyst, which is deteriorated at the time of producing an alcohol efficiency at a low cost by oxidizing the catalyst at a prescribed temperature in a stream of gas and activating it by reducing treatment and to produce an alcohol in high yield and highly selectively using the regenerated catalyst. CONSTITUTION:A catalyst whose activity is deteriorated due to its use for producing an alcohol by catalytic reduction of an organic carboxylic acid ester with hydrogen is treated at 20-300 deg.C in a mixed gas flow wherein the mixed gas consisting of hydrogen and an inert gas and afterward the catalyst is reduced and activated to be regenerated for producing an alcohol. The composition of the catalyst precursor is a catalyst prepared by carrying an active component on a carrier component or mixing them and the active component has a composition with weight ratio, copper oxide : zinc oxide : a specified oxide = 1:(0-0.25):(0-0.25) and the carrier component has a weight ratio, titanium oxide and/or titanium hydroxide : silicon oxide and/or silicon hydroxide = (100:0)-(85:15) when calculated as TiO2 and SiO2 respectively.
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公开(公告)号：JPH0657286A
公开(公告)日：1994-03-01
申请号：JP24568391
申请日：1991-09-25
Applicant: KAO CORP
Inventor： HATTORI YASUYUKI , TAMURA HIROYUKI , KADOWAKI HIDETOSHI , TSUKADA KIYOSHI
IPC: B01J23/755 , C07C27/26 , C07C29/149 , C07C67/60 , C07C69/587 , C11B3/02 , B01J23/74
Abstract: PURPOSE:To produce, in a high yield, desulfurized oils or fats or a desulfurized fatty acid ester which is very suitable as a raw material for producing an alcohol by hydrogenation. CONSTITUTION:Oils or fats or a fatty acid ester is brought into contact with a catalyst represented by the formula: Ni.CuxOy in hydrogen or in a mixture of hydrogen with an inert gas, giving desulfurized oils or fats or a desulfurized fatty acid ester. In the formula, x is an atomic ratio of Cu to Ni and is 0.02-8; and y is an atomic ratio of oxygen and satisfies the requirements of the valences of Ni and Cu.
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50.发明专利
公开(公告)号：JPH05177140A
公开(公告)日：1993-07-20
申请号：JP6331792
申请日：1992-03-19
Applicant: KAO CORP
Inventor： HATTORI YASUYUKI , MORI ATSUTO , FUKUOKA NORIAKI , TSUKADA KIYOSHI
IPC: B01J21/06 , B01J23/80 , B01J32/00 , C07B61/00 , C07C29/149
Abstract: PURPOSE:To obtain a highly active and highly selective precursor of catalyst for hydrogenation reaction at a low production cost by coating titanium oxide as a substrate with a titanium oxide produced due to the hydrolysis of titanium alkoxyd and allowing to bear a catalytic metal on the coated substrate. CONSTITUTION:The outer surface of titanium oxide and/or titanium hydroxide with an outer surface area of 15m /g is coated with titanium oxide and/or titanium hydroxide produced by hydrolyzing a titanium alkoxyd represented by the formula Ti(OR)4 [R is a 1 to 18C alkyl group and aryl group]. Next, this carrier is baked, if necessary, and is allowed to carry a metal oxide having a composition of the elements of the IIa group and IIIb group of the periodic table of CuO/ZnO=100/(0 to 25)/(0 to 25) at a ratio of the metal oxide/carrier (weight ratio)=15/85 to 65/35. Thus, a highly active and highly selective catalyst precursor can be obtained at low cost.
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