PARTIALLY DEHYDRATED REACTION PRODUCT, PROCESS FOR MAKING SAME, AND EMULSION CONTAINING SAME

    公开(公告)号:CA2398108C

    公开(公告)日:2008-12-23

    申请号:CA2398108

    申请日:2001-01-22

    Applicant: LUBRIZOL CORP

    Abstract: An emulsifier composition comprising a partially deyhdrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride wi th (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial ami de or mixture when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamin e, or a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of the acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating the first intermediate product to form a second intermediate product with water of reaction being formed, and separating a portion of the water of reaction from the second intermediate product, when (A) is the succinic anhydride the amount of water of reaction that is separated is from about 0.2 to about 0.9 equivalents of said water of reaction per equivalent of the succinic anhydride, when (A) is one succinic acid the amountof water of reaction that is separated is from about 1.2 to about 1.9 moles of said water of reaction per equivalent o f the succinic acid, the partially dehydrated product having a total acid number i n the range of about 20 to about 100 mg of KOH/g. The emulsifier composition can b e used for making emulsions, for example explosive emulsions, emulsion fertilizers, water-blended fuels and lubricants.

    Partially dehydrated reaction product, process for making same, and emulsion containing same

    公开(公告)号:AU782124B2

    公开(公告)日:2005-07-07

    申请号:AU3449701

    申请日:2001-01-22

    Applicant: LUBRIZOL CORP

    Abstract: The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermediate product with water of reaction being formed, and separating a portion of said water of reaction from said second intermediate product, when (A) is said succinic anhydride the amount of water of reaction that is separated is from about 0.2 to about 0.9 equivalents of said water of reaction per equivalent of said succinic anhydride, when (A) is said succinic acid the amount of water of reaction that is separated is from about 1.2 to about 1.9 moles of said water of reaction per equivalent of said succinic acid, said partially dehydrated product having a total acid number in the range of about 20 to about 100 mg of KOH/g. A process for making the foregoing partially dehydrated product is also disclosed. Emulsions comprising an organic phase, an aqueous phase, and an emulsifying amount of the foregoing partially dehydrated product are disclosed.

    44.
    发明专利
    未知

    公开(公告)号:BR0013192A

    公开(公告)日:2002-07-30

    申请号:BR0013192

    申请日:2000-07-06

    Applicant: LUBRIZOL CORP

    Abstract: A nitrogen-containing ester derived from a carboxy-containing interpolymer having a reduced specific viscosity (RSV) of from about 0.05 to about 2, said interpolymer being derived from at least two monomers, (i) one of said monomers being at least one of an aliphatic olefin containing from 2 to about 30 carbon atoms and a vinyl aromatic monomer and (ii) the other of said monomers being at least one alpha, beta-unsaturated acylating agent, said ester being characterized by the presence within its polymeric structure of each of the following groups which are derived from the carboxy groups of said interpolymer: (A) from about 20 to about 70 mole % based on moles of carboxyl groups in said interpolymer, of ester groups containing from about 13 to about 19 carbon atoms; (B) from about 80 to about 30 mole %, based on moles of carboxyl groups in said interpolymer, of ester groups containing from about 8 to about 12 carbon atoms, optionally; (C) up to about 20 mole %, based on moles of carboxyl groups in said interpolymer, of ester groups containing from 2 to 7 carbon atoms; wherein from about 93 to about 97% of the carboxy groups derived from the carboxy-containing interpolymer are ester groups, the balance of the carboxy groups comprising residual carboxylic acid or anhydride groups which are then (D) reacted with at least one amino compound having an average of from 1 to about 1.1 primary or secondary amino groups, to convert from about 5 up to less than 50% of the carboxylic acid or anhydride groups to carbonyl-amino groups, with the unreacted carboxylic acid or anhydride groups remaining as (E) residual carboxylic acid or anhydride groups. Additive concentrates and lubricating oil compositions are also disclosed.

    46.
    发明专利
    未知

    公开(公告)号:DE69705687D1

    公开(公告)日:2001-08-23

    申请号:DE69705687

    申请日:1997-09-25

    Applicant: LUBRIZOL CORP

    Abstract: A bis(substituted hydroxyaryl)amide of formula (I), where R is 4-120 C hydrocarbyl, each R' is H or 1-28 C alkyl, A is 2-10 C alkylene and x = 1-5, is prepared by mixing a lactone of formula (II) with a polyamine of formula R'(NHA)xNHR' (III) and an alcohol (IV) and heating the mixture to 60-180[deg]C. (IV) is a 2-10 C saturated aliphatic alcohol or a polyether alcohol of formula R"(OA')yOH, where R" is 1-30C hydrocarbyl, A' is 2-8 C alkylene and y = 1-30.

    48.
    发明专利
    未知

    公开(公告)号:DE69427160D1

    公开(公告)日:2001-06-07

    申请号:DE69427160

    申请日:1994-10-06

    Applicant: LUBRIZOL CORP

    Abstract: A compsn. comprising: (a) oil-soluble, olefin-based polymer(s); (b) oil-soluble polymer(s) having N functionality, (a) and (b) combined in a liq. nonpolar oleophilic medium exhibit incompatibility evidenced by phase separation; (c) sufficient hydrocarbyl substd. hydroxyaromatic material(s) contg. at least 24C to reduce the incompatibility of (a) and (b); and (d) a liq. nonpolar oleophilic medium. Also claimed are (1) A lubricant prepd. by mixing the above compsn., (d) being present in a concentrate-forming amt., with an oil of lubricating viscosity. (2) Improving the mutual compatibility of (a) and (b) comprising combining with a mixt. of (a) and (b) in a liq. nonpolar oleophilic medium sufficient hydrocarbyl substd. hydroxyaromatic material contg. at least 24C.

Patent Agency Ranking