公开(公告)号：DK0923590T3

公开(公告)日：2002-01-28

申请号：DK97934335

申请日：1997-07-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： WEINBERG W HENRY ,  MCFARLAND ERIC ,  GOLDWASSER ISY ,  BOUSSIE THOMAS ,  TURNER HOWARD ,  BEEK JOHANNES A M VAN ,  MURPHY VINCE ,  POWERS TIMOTHY

IPC: B01J23/22 ,  B01J19/00 ,  B01J31/16 ,  B01J31/22 ,  B01J37/00 ,  C07B61/00 ,  C07C249/02 ,  C07C251/08 ,  C07C251/16 ,  C07D213/53 ,  C07F15/00 ,  C07F15/04 ,  C07F17/00 ,  C07F19/00 ,  C08F4/00 ,  C08F4/60 ,  C08F4/70 ,  C08F10/00 ,  C08F110/02 ,  C40B40/04 ,  C40B40/18 ,  C40B50/00 ,  C40B60/14 ,  G01N1/10 ,  G01N21/64 ,  G01N29/24 ,  G01N29/34 ,  G01N29/44

Abstract: Methodologies for the synthesis, screening and characterisation of organometallic compounds and catalysts (eg homogenous catalysts), including combinatorial synthesis, screening and characterisation of libraries of supported and unsupported organometallic compounds and catalysts (eg homogenous catalysts). The methods can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (eg homogeneous catalysts), but also as additives and therapeutic agents.

公开(公告)号：DE69708928D1

公开(公告)日：2002-01-17

申请号：DE69708928

申请日：1997-07-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： WEINBERG HENRY W ,  MCFARLAND ERIC ,  GOLDWASSER ISY ,  BOUSSIE THOMAS ,  TURNER HOWARD ,  BEEK JOHANNES A M VAN ,  MURPHY VINCE ,  POWERS TIMOTHY

IPC: B01J23/22 ,  B01J19/00 ,  B01J31/16 ,  B01J31/22 ,  B01J37/00 ,  C07B61/00 ,  C07C249/02 ,  C07C251/08 ,  C07C251/16 ,  C07D213/53 ,  C07F15/00 ,  C07F15/04 ,  C07F17/00 ,  C07F19/00 ,  C08F4/00 ,  C08F4/60 ,  C08F4/70 ,  C08F10/00 ,  C08F110/02 ,  C40B40/04 ,  C40B40/18 ,  C40B50/00 ,  C40B60/14 ,  G01N1/10 ,  G01N21/64 ,  G01N29/24 ,  G01N29/34 ,  G01N29/44

Abstract: Methodologies for the synthesis, screening and characterisation of organometallic compounds and catalysts (eg homogenous catalysts), including combinatorial synthesis, screening and characterisation of libraries of supported and unsupported organometallic compounds and catalysts (eg homogenous catalysts). The methods can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (eg homogeneous catalysts), but also as additives and therapeutic agents.

公开(公告)号：CA2379490A1

公开(公告)日：2001-12-27

申请号：CA2379490

申请日：2001-06-18

Applicant: SYMYX TECHNOLOGIES INC

Inventor： DIAMOND GARY M ,  MURPHY VINCE ,  LECLERC MARGARETE K ,  GOH CHRISTOPHER ,  TURNER HOWARD W

IPC: C07B61/00 ,  C08F4/60 ,  C08F4/659 ,  C08F110/14 ,  C08F210/16 ,  G01N37/00 ,  C08F4/00 ,  C08F10/00 ,  G01N30/02 ,  G01N33/26

Abstract: A method is disclosed for screening potential catalysts for polymerization performance. The method includes the steps of reacting a potential catalyst with at least a first monomer under polymerization conditions, determining t he polymerization performance of the catalyst with the at least first monomer, and using the determination as a predictor for the polymerization performanc e of the catalyst for at least a second monomer, wherein the first and second monomers are different from each other and the first monomer is an olefin other than ethylene. The method provides a useful, concrete and tangible result that has particular value for identifying appropriate catalysts for olefin polymerization and copolymerization.

公开(公告)号：AU4987101A

公开(公告)日：2001-10-15

申请号：AU4987101

申请日：2001-04-04

Applicant: SYMYX TECHNOLOGIES INC

Inventor： GOH CHRISTOPHER ,  DIAMOND GARY M ,  MURPHY VINCE ,  LECLERC MARGARETE K ,  HALL KEITH ,  LAPOINTE ANNE M ,  BOUSSIE THOMAS R ,  LUND CHERYL ,  UNO TETSUO

IPC: C07B61/00 ,  C07C217/92 ,  C07D213/38 ,  C07D263/10 ,  C07D307/14 ,  C07D307/52 ,  C07D317/28 ,  C07D333/20 ,  C07F7/00 ,  C07F7/08 ,  C07F7/28 ,  C08F4/00 ,  C08F4/06 ,  C08F4/60 ,  C08F4/645 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16

Abstract: The inventions disclosed herein are new complexes and catalysts comprising metal-ligand complexes or compositions of metal precursors and ligands (and optionally activators) that catalyze polymerization and copolymerization reactions, particularly with monomers that are olefins, diolefins or acetylenically unsaturated. These compositions can also polymerize monomers that have polar functionalities in homopolymerizations or copolymerizations. Also, diolefins in combination with ethylene or alpha-olefins or 1,1-disubstituted olefins may be co-polymerized. The new catalyst compositions can be prepared by combining a metal precursor with a suitable ligand and, optionally, an activator or combination of activators. The main feature of this invention is the use of new metal ligand complexes to provide the active polymerization catalysts.

公开(公告)号：AT206714T

公开(公告)日：2001-10-15

申请号：AT97934335

申请日：1997-07-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： WEINBERG W HENRY ,  MCFARLAND ERIC ,  GOLDWASSER ISY ,  BOUSSIE THOMAS ,  TURNER HOWARD ,  BEEK JOHANNES A M VAN ,  MURPHY VINCE ,  POWERS TIMOTHY

IPC: B01J23/22 ,  B01J19/00 ,  B01J31/16 ,  B01J31/22 ,  B01J37/00 ,  C07B61/00 ,  C07C249/02 ,  C07C251/08 ,  C07C251/16 ,  C07D213/53 ,  C07F15/00 ,  C07F15/04 ,  C07F17/00 ,  C07F19/00 ,  C08F4/00 ,  C08F4/60 ,  C08F4/70 ,  C08F10/00 ,  C08F110/02 ,  C40B40/04 ,  C40B40/18 ,  C40B50/00 ,  C40B60/14 ,  G01N1/10 ,  G01N21/64 ,  G01N29/24 ,  G01N29/34 ,  G01N29/44

Abstract: Methodologies for the synthesis, screening and characterisation of organometallic compounds and catalysts (eg homogenous catalysts), including combinatorial synthesis, screening and characterisation of libraries of supported and unsupported organometallic compounds and catalysts (eg homogenous catalysts). The methods can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (eg homogeneous catalysts), but also as additives and therapeutic agents.

公开(公告)号：AU4186500A

公开(公告)日：2000-10-23

申请号：AU4186500

申请日：2000-03-31

Applicant: SYMYX TECHNOLOGIES INC

Inventor： LUND CHERYL ,  HALL KEITH ,  BOUSSIE THOMAS ,  MURPHY VINCE ,  HILLHOUSE GREG

IPC: C07D333/20 ,  C07F9/50 ,  C07F9/74 ,  C07F9/92 ,  C07F11/00 ,  C07F15/00 ,  C07F15/02 ,  C07F15/04 ,  C08F4/60 ,  C08F4/619 ,  C08F4/69 ,  C08F4/70 ,  C08F10/02 ,  C08G75/00

公开(公告)号：CA2353493A1

公开(公告)日：2000-06-08

申请号：CA2353493

申请日：1999-12-03

Applicant: SYMYX TECHNOLOGIES INC ,  BAYER AG

Inventor： MURPHY VINCE

IPC: C08F4/14 ,  C08F4/44 ,  C08F10/10 ,  C08F210/08

Abstract: Ionic liquids function as the initiator or as a co-solvent for the productio n of very high molecular weight polyisobutylenes, e.g., having a weight-averag e molecular weight over 100,000. These ionic liquids may be characterized by t he general formula A+B- where A+ represents any stable inorganic or organic cation and B- represents any stable organic or inorganic anion.

公开(公告)号：CA2261305A1

公开(公告)日：1998-01-29

申请号：CA2261305

申请日：1997-07-22

Applicant: SYMYX TECHNOLOGIES INC

Inventor： POWERS TIMOTHY ,  WEINBERG W HENRY ,  MCFARLAND ERIC ,  GOLDWASSER ISY ,  MURPHY VINCE ,  TURNER HOWARD ,  BEEK JOHANNES A M VAN ,  BOUSSIE THOMAS

IPC: B01J23/22 ,  B01J19/00 ,  B01J31/16 ,  B01J31/22 ,  B01J37/00 ,  C07B61/00 ,  C07C249/02 ,  C07C251/08 ,  C07C251/16 ,  C07D213/53 ,  C07F15/00 ,  C07F15/04 ,  C07F17/00 ,  C07F19/00 ,  C08F4/00 ,  C08F4/60 ,  C08F4/70 ,  C08F10/00 ,  C08F110/02 ,  C40B40/04 ,  C40B40/18 ,  C40B50/00 ,  C40B60/14 ,  G01N1/10 ,  G01N21/64 ,  G01N29/24 ,  G01N29/34 ,  G01N29/44

Abstract: The present invention relates, inter alia, to methodologies for the synthesis, screening and characterization of organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention provide for the combinatorial synthesis, screening and characterization of libraries of supported and unsupported organometallic compounds and catalysts (e.g., homogeneous catalysts). The methods of the present invention can be applied to the preparation and screening of large numbers of organometallic compounds which can be used not only as catalysts (e.g., homogeneous catalysts), but also as additives and therapeutic agents.

公开(公告)号：WO0246249A9

公开(公告)日：2003-05-01

申请号：PCT/US0144147

申请日：2001-11-06

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  DIAMOND GARY M ,  GOH CHRISTOPHER ,  HALL KEITH A ,  POINTE ANNE M LA ,  LECLERC MARGARETE K ,  LUND CHERYL ,  MURPHY VINCE

IPC: C07B61/00 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F7/00 ,  C07F9/58 ,  C08F4/64 ,  C08F4/642 ,  C08F4/643 ,  C08F4/646 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C07D213/16

CPC classification number: C07D213/74 ,  B01J2219/00722 ,  C07B2200/11 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07F7/00 ,  C07F7/006 ,  C07F9/582 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C08F4/659 ,  C08F4/65904 ,  C08F2500/15 ,  C08F2500/02 ,  C08F210/10 ,  C08F212/08 ,  C08F210/14 ,  C08F4/64144 ,  C08F4/64113 ,  C08F4/64044

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, l-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

Abstract translation: 公开了新的配体，组合物，金属 - 配体络合物和具有吡啶胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。

公开(公告)号：WO0246249A2

公开(公告)日：2002-06-13

申请号：PCT/US0144147

申请日：2001-11-06

Applicant: SYMYX TECHNOLOGIES INC

Inventor： BOUSSIE THOMAS R ,  DIAMOND GARY M ,  GOH CHRISTOPHER ,  HALL KEITH A ,  POINTE ANNE M LA ,  LECLERC MARGARETE K ,  LUND CHERYL ,  MURPHY VINCE

IPC: C07B61/00 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F7/00 ,  C07F9/58 ,  C08F4/64 ,  C08F4/642 ,  C08F4/643 ,  C08F4/646 ,  C08F4/659 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C08F10/02

CPC classification number: C07D213/74 ,  B01J2219/00722 ,  C07B2200/11 ,  C07D213/38 ,  C07D213/61 ,  C07D213/68 ,  C07F7/00 ,  C07F7/006 ,  C07F9/582 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  C40B40/14 ,  C08F4/659 ,  C08F4/65904 ,  C08F2500/15 ,  C08F2500/02 ,  C08F210/10 ,  C08F212/08 ,  C08F210/14 ,  C08F4/64144 ,  C08F4/64113 ,  C08F4/64044

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, l-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

Abstract translation: 公开了新的配体，组合物，金属 - 配体络合物和具有吡啶胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。