公开(公告)号：KR800000622B1

公开(公告)日：1980-07-07

申请号：KR770002413

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE J ,  APPLEQUIST M ,  SHAW W

IPC: B01J27/18

Abstract: Metharylic acid (I) was prepd. from methacrolein(II) by oxidn. with mo1. 0 at 200-600≦̸C in the presence of a catalyst contg. an oxide of W,P,U,Mo, and Co, Rn, Cd, Sr. An aq. slurry of MoO3 86.2, 85 % H3Po4 7.7, V2O3 7.5, and NH4 paratungstate 10.8 was refluxed overnight, evapd., and dried overnight at 120≦̸C to prepare a catalyst giving 65.9 % conversion and 45.4 % selectivity in the oxidn. of II to I at 355≦̸C and contact time 4.8s.

公开(公告)号：KR790000774B1

公开(公告)日：1979-06-30

申请号：KR750000066

申请日：1975-05-07

Applicant: STANDARD OIL CO

Inventor： ROGAN J B

Abstract: Highly cryst. polypropylene or its copolymer with ethylene or C4-8α-olefins, were prepd. in the presence of catalyst contg. an organoaluminum [trialkylaluminum(I), I-alkylaluminum dichloride or-dibromide mixt., I-dialkylaluminum chloride or-bromide mixt. treated with 10 mole% H2S, TiCl3, and a trihydrocarbylphosphite or a sterically hindered tertiary amine or its oxide.

公开(公告)号：KR790000725B1

公开(公告)日：1979-06-28

申请号：KR750002495

申请日：1975-11-14

Applicant: STANDARD OIL CO OHIO

Inventor： CALLAHAN J L

Abstract: Sulfur was eliminated from thiodinitriles, e.g., thiodipropionitrile, to give the resp. dinitrile, e.g., adiponitrile, by heating the thiodinitrile at 200-700≦̸C; the elimination could be strictly a thermal reaction or a reaction conducted in the presence of other gases, liqs. pr solids. Optimum conditions (from 105 examples) were 555≦̸C with bonded Cu flake present; 91.6% adiponitrile was obtained with 62.1% conversion.

公开(公告)号：KR790000278B1

公开(公告)日：1979-04-16

申请号：KR730001456

申请日：1973-08-31

Applicant: STANDARD OIL CO

Inventor： GILKES A G

IPC: B01D61/38 ,  B01D71/56 ,  C07C7/152 ,  C07C7/156

Abstract: Unsatd. aliphatic hydrocarbons were sepd. from gaseous C2-8 hydrocarbon mixts. by contacting the gaseous mixts. with a liq. barrier consisting of complex-forming metal ions in aq. soln. and supported with water insoluble semipermeable membrane which is substantially solid and impermeable to liq. barrier. The partial pressure of gas-fed cell to evolve the unsatd. hydrocarbon from aq. barrier was higher than that of the other.

公开(公告)号：KR780000356B1

公开(公告)日：1978-09-16

申请号：KR730000169

申请日：1973-01-29

Applicant: STANDARD OIL CO

Inventor： LEE SAM SOO ,  NICHOLAS M KARAYANMIS

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/68 ,  C08F10/00

公开(公告)号：KR850000177B1

公开(公告)日：1985-03-04

申请号：KR810002308

申请日：1981-06-25

Applicant: STANDARD OIL CO OHIO

Inventor： WIGGINS WAYNE THOMAS ,  CAFFEY GERALD PAUL

IPC: C08L7/00 ,  C08L21/00 ,  C08L25/12 ,  C08L33/00 ,  C08L33/02 ,  C08L33/20 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L77/00 ,  C08L77/02

公开(公告)号：KR840000986B1

公开(公告)日：1984-07-13

申请号：KR810002828

申请日：1981-08-04

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  KUCH PHILIP LAWRENCE ,  PAPARIZOS CHRISTOS

IPC: C07C57/055 ,  B01J23/76 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/235 ,  C07C51/25 ,  C07C67/00

公开(公告)号：KR830000022A

公开(公告)日：1983-03-25

申请号：KR780002329

申请日：1978-07-28

Applicant: STANDARD OIL CO

Inventor： GUTTMANN ANDREW TYTUS ,  GRASSELLI ROBERT KARL

IPC: C07C47/20

Abstract: Unsaturated aldehydes and acids was prepared by the oxidation of olefins at 200-400≦̸C in the presence of catalyst, K0.1Ni2.5Co4.5Mo12Ox (X = the no. required to satisfy stoichiometry) and a promoter Fe2LZ0.5 (L = Cr, Sb, Ce, Pb, Ge, S Sn), or Mg7.5Fe3Z0.5 (Z = p,w). Using Fe2CrW0.5 as the promoter at 350≦̸C, conversion yield of acrolein and acrylic acid was 80.4 % and 77 %, resp.

公开(公告)号：KR820002027B1

公开(公告)日：1982-10-25

申请号：KR790001899

申请日：1979-06-11

Applicant: STANDARD OIL CO OHIO

Inventor： TALSMA H ,  BOND T ,  FELDMAN D

IPC: C08F291/00 ,  C08J3/00

Abstract: The color and impact strength of nitrile polymers, prepared by polymn. of an olefinically unsatd. nitrile with a monovinyl monomer in the presence of a rubber, were improved by heating the polymer to a plastic state in the absence of O and in presence of an inert gas. Thus, an acrylonitrile-rubber-vinyl compd. latex, coagulated and formed into strands was pelletized by screw extrusion in the presence of CO2. The product had Izod impact strength 2.57kg/cm2, yellowness index 28.

公开(公告)号：KR820000922B1

公开(公告)日：1982-05-26

申请号：KR780001318

申请日：1978-05-01

Applicant: STANDARD OIL CO

Inventor： GRASSELLI ROBERT K ,  BARTEK JOSEPH P

IPC: B01J21/02 ,  C07C15/46

Abstract: Catalysts for the title dehydrogenation had the formula AaMbMlcM"dBePyOx, where A = alkali metal and/or Tl; M = one or more of Ni, Co, Cu, Mn, Mg, An, Ca, Nb, Ta, Sn, Ba; M' = one or more of Fe, Cr, U, Th, V, Ti, La, rare earth; M" = one or more of An, B, Pb, Ge, Al, W, Mo; B = one or more of Bi, Te, As, Sb, Cd; a-y varied over a range, mostly from 0-20, were prepd. Data for 26 catalysts were given in terms of dehydrogenation of alkylaromatic compds. to alkenylaromatic compds.