公开(公告)号：DE10261195A1

公开(公告)日：2004-07-01

申请号：DE10261195

申请日：2002-12-20

Applicant: BASF AG

Inventor： GERLACH TILL ,  FUNKE FRANK ,  BENISCH CHRISTOPH ,  MELDER JOHANN-PETER

IPC: C07C209/64 ,  C07C211/14 ,  C07B43/04 ,  C07C209/00

公开(公告)号：CZ20032468A3

公开(公告)日：2004-03-17

申请号：CZ20032468

申请日：2002-03-15

Applicant: BASF AG

Inventor： HENNINGSEN MICHAEL ,  KUSCHE ANDREAS ,  HULLMANN MICHAEL ,  RUB LOTHAR ,  KASHAMMER STEFAN ,  GERLACH TILL

IPC: C07D265/30 ,  C07B61/00 ,  C07D295/02 ,  C07D295/023 ,  C07D295/03 ,  C07D295/033 ,  A01N43/84

Abstract: The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R 1 and R 2 , independently of one another, are hydrogen, alkyl or cycloalkyl, or R 1 and R 2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R 3 and R 4 , independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R 1 and R 2 have the meanings given above, with at least one morpholine of the formula III in which R 3 and R 4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.

公开(公告)号：AU2003215639A8

公开(公告)日：2003-09-22

申请号：AU2003215639

申请日：2003-03-07

Applicant: BASF AG

Inventor： HULLMANN MICHAEL ,  ISELBORN STEFAN ,  GERLACH TILL ,  FUNKE FRANK ,  RUDLOFF MARTIN ,  MELDER JOHANN-PETER

IPC: C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO 2 , 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：CA2478858A1

公开(公告)日：2003-09-18

申请号：CA2478858

申请日：2003-03-07

Applicant: BASF AG

Inventor： GERLACH TILL ,  FUNKE FRANK ,  ISELBORN STEFAN ,  HUELLMANN MICHAEL ,  MELDER JOHANN-PETER ,  RUDLOFF MARTIN

IPC: C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper bein g greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydroge n. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：CA2440518A1

公开(公告)日：2002-09-26

申请号：CA2440518

申请日：2002-03-15

Applicant: BASF AG

Inventor： KUSCHE ANDREAS ,  GERLACH TILL ,  HULLMANN MICHAEL ,  HENNINGSEN MICHAEL ,  RUB LOTHAR ,  KASHAMMER STEFAN

IPC: C07D265/30 ,  C07B61/00 ,  C07D295/02 ,  C07D295/023 ,  C07D295/03 ,  C07D295/033 ,  A01N43/84

Abstract: The invention relates to a method of producing the N-substituted 2,6-dialkyl morpholines of general formula (I), wherein R1 and R2 independently represen t hydrogen, alkyl or cycloalkyl, or R1 and R2, together with the carbon atom t o which they are bound, represent a 5 to 14 membered carbocyclic compound, and R3 and R4 independently represent alkyl or cycloalkyl. The inventive substances are produced by reacting at least one carbonyl compound of genera l formula (II), wherein R1 and R2 are defined as above, with at least one morpholine of general formula (III), wherein R3 and R4 are defined as above, in the presence of hydrogen and at least one metal-containing catalyst, the active component of said catalyst substantially consisting of platinum group metals.

公开(公告)号：CZ304041B6

公开(公告)日：2013-09-04

申请号：CZ20032468

申请日：2002-03-15

Applicant: BASF AG

Inventor： HENNINGSEN MICHAEL ,  KUSCHE ANDREAS ,  HUELLMANN MICHAEL ,  RUEB LOTHAR ,  KOSHAMMER STEFAN ,  GERLACH TILL

IPC: C07D265/30 ,  C07D295/023 ,  A01N43/84 ,  C07B61/00 ,  C07D295/02 ,  C07D295/027 ,  C07D295/03 ,  C07D295/033

Abstract: Zpusob prípravy N-substituovaných 2,6-dialkylmorfolinu obecného vzorce I, ve kterém R.sup.1.n., R.sup.2.n., R.sup.3.n. a R.sup.4.n. mají význam vysvetlený v popise, reakcí nejméne jedné karbonylové slouceniny obecného vzorce II s nejméne jedním morfolinem obecného vzorce III za prítomnosti vodíku a katalyzátoru obsahujícího nejméne jeden kov, ve kterém se aktivní slozka katalyzátoru skládá hlavne z kovu skupiny platiny.

公开(公告)号：CA2492261C

公开(公告)日：2010-09-28

申请号：CA2492261

申请日：2003-07-14

Applicant: BASF AG

Inventor： GOEBBEL HANS-GEORG ,  GERLACH TILL ,  WEGNER GUENTER ,  FUCHS HARTWIG ,  UNVERRICHT SIGNE ,  SALDEN AXEL

IPC: C07C29/141 ,  C07B61/00 ,  C07C33/025

Abstract: Disclosed is a method for selective hydrogenation of citronellal to form citronellol, wherein a liquid phase in which the citronellal is dissolved and in which particles of a catalyst are suspended, said catatalyst resulting in preferential hydrogenation of carbon-oxygen double bonds in relation to carbon carbon bonds, is guided in the presence of a gas containing hydrogen through a device which inhibits the transport of the catalyst particles.

公开(公告)号：AT384034T

公开(公告)日：2008-02-15

申请号：AT03763837

申请日：2003-07-14

Applicant: BASF AG

Inventor： GOEBBEL HANS-GEORG ,  GERLACH TILL ,  WEGNER GUENTER ,  FUCHS HARTWIG ,  UNVERRICHT SIGNE ,  SALDEN AXEL

IPC: C07C29/141 ,  C07B61/00 ,  C07C33/025

Abstract: A process is described for selectively hydrogenating citronellal to citronellol in which a liquid phase, in which the citronellal is dissolved and particles of a catalyst are suspended which is capable of preferentially hydrogenating carbon-oxygen double bonds over carbon-carbon double bonds, is conducted through a device which inhibits the transport of the catalyst particles in the presence of a hydrogen-containing gas.

公开(公告)号：AU2002310949B2

公开(公告)日：2008-01-31

申请号：AU2002310949

申请日：2002-03-15

Applicant: BASF AG

Inventor： KUSCHE ANDREAS ,  GERLACH TILL ,  KASHAMMER STEFAN ,  HULLMANN MICHAEL ,  HENNINGSEN MICHAEL ,  RUB LOTHAR

IPC: C07D265/30 ,  C07B61/00 ,  C07D295/02 ,  C07D295/023 ,  C07D295/03 ,  C07D295/033

Abstract: The present invention relates to a process for the preparation of N-substituted 2,6-dialkylmorpholines of the formula I in which R 1 and R 2 , independently of one another, are hydrogen, alkyl or cycloalkyl, or R 1 and R 2 together with the carbon atom to which they are bonded are a 5- to 14-membered carbocycle, and R 3 and R 4 , independently of one another, are alkyl or cycloalkyl, by reacting at least one carbonyl compound of the formula II in which R 1 and R 2 have the meanings given above, with at least one morpholine of the formula III in which R 3 and R 4 have the meanings given above, in the presence of hydrogen and at least one metal-containing catalyst, wherein the active component of the catalyst consists essentially of platinum group metals.

公开(公告)号：AT378107T

公开(公告)日：2007-11-15

申请号：AT02027073

申请日：2002-12-03

Applicant: BASF AG

Inventor： GERLACH TILL ,  GOEBBEL HANS-GEORG ,  FUNKE FRANK ,  EBEL KLAUS ,  SCHWAB EKKEHARD ,  UNVERRICHT SIGNE ,  KOERNER REINHARD ,  LOBREE LISA

IPC: B01J23/89 ,  B01J21/18 ,  B01J33/00 ,  B01J37/03 ,  C07B61/00 ,  C07C29/141 ,  C07C29/145 ,  C07C29/17 ,  C07C33/02 ,  C07C33/025