51.
    发明专利
    未知

    公开(公告)号:DE59700471D1

    公开(公告)日:1999-10-28

    申请号:DE59700471

    申请日:1997-02-19

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP97/00768 Sec. 371 Date Aug. 21, 1998 Sec. 102(e) Date Aug. 21, 1998 PCT Filed Feb. 19, 1997 PCT Pub. No. WO97/31059 PCT Pub. Date Aug. 28, 1997A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50 DEG C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130 DEG C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.

    53.
    发明专利
    未知

    公开(公告)号:ES2123954T3

    公开(公告)日:1999-01-16

    申请号:ES95906950

    申请日:1995-01-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00144 Sec. 371 Date Jul. 25, 1996 Sec. 102(e) Date Jul. 25, 1996 PCT Filed Jan. 16, 1995 PCT Pub. No. WO95/20056 PCT Pub. Date Jul. 27, 1995Aqueous solution or aqueous dispersion of copolymers suitable for the fatliquoring and filling of leather and fur skins are obtained by free-radical copolymerization of A1) C6-C40-monoolefins or C6-C40-alkyl vinyl ethers or mixtures thereof with B1) monoethylenically unsaturated C4-C8-dicarboxylic anhydrides or by free-radical copolymerization of A2) C6-C40-alkyl acrylates or methacrylates or vinyl esters of C6-C40-carboxylic acids or mixtures thereof with B2) monoethylenically unsaturated C3-C12-carboxylic acids, monoethylenically unsaturated C4-C12-dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C4-C12-dicarboxylic acids, amides of monoethylenically unsaturated C3-C12-carboxylic acids or mixtures thereof to give copolymers with molecular weights of 500 to 30,000, where the carboxyl groups which are present in aqueous medium are at least partially neutralized, and some of the carboxylic groups can be in amidated form, containing 0.5-40% by weight, based on the amount of copolymer, of defined emulsifiers.

    54.
    发明专利
    未知

    公开(公告)号:DE59504442D1

    公开(公告)日:1999-01-14

    申请号:DE59504442

    申请日:1995-09-23

    Applicant: BASF AG

    Abstract: Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers containing ammonium carboxylate groups are prepared by azeotropic removal of water from water-in-oil emulsions of the water-soluble or water-swellable polymers which contain ammonium carboxylate groups in the presence of from 0:1 to 40% by weight, based on the polymers, of polyalkylene glycols which have an agglomerating effect and which are obtainable by an addition reaction of C2-C4-alkylene-oxides with alcohols, phenols, amines or carboxylic acids and contain at least two polymerized alkylene oxide units and additionally of from 0.1 to 20% by weight, based on the polymers, of protective colloids which are obtainable by free radical copolymerization of C8-C40-monoolefins with monoethylenically unsaturated C4-C6-dicarboxylic anhydrides by a mass polymerization method at from 80 to 300° C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, and said agglomerated polymer particles are used as thickeners for textile pigment print pastes.

    55.
    发明专利
    未知

    公开(公告)号:ES2108575T3

    公开(公告)日:1997-12-16

    申请号:ES95911239

    申请日:1995-02-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00575 Sec. 371 Date Aug. 21, 1996 Sec. 102(e) Date Aug. 21, 1996 PCT Filed Feb. 17, 1995 PCT Pub. No. WO95/22569 PCT Pub. Date Aug. 24, 1995A process for preparing copolymers of vinyl esters and monoethylenically unsaturated carboxylic acids by free-radical copolymerization of (a) 20 to 80 mol % of vinyl esters of aliphatic monocarboxylic acids having at least 2 carbon atoms and (b) 80-20 mol % of monoethylenically unsaturated carboxylic acids, with or without (c) 0-30 mol % of other copolymerizable monoethylenically unsaturated monomers and/or (d) 0-10 mol % of monomers which contain at least two non-conjugated ethylenic double bonds in the molecule, in the presence of at least one sulfur, phosphorus and/or nitrogen compound with a reducing action and of 0.05-30% by weight, based on the monomers, of at least one surface-active agent in aqueous medium in the presence of initiators and in the presence or absence of regulators, and the use of the copolymers or of the copolymers which are obtainable therefrom by hydrolysis and/or oxidation and have vinyl alcohol units as additive to detergents and cleaners.

    56.
    发明专利
    未知

    公开(公告)号:DE59500859D1

    公开(公告)日:1997-11-27

    申请号:DE59500859

    申请日:1995-02-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00575 Sec. 371 Date Aug. 21, 1996 Sec. 102(e) Date Aug. 21, 1996 PCT Filed Feb. 17, 1995 PCT Pub. No. WO95/22569 PCT Pub. Date Aug. 24, 1995A process for preparing copolymers of vinyl esters and monoethylenically unsaturated carboxylic acids by free-radical copolymerization of (a) 20 to 80 mol % of vinyl esters of aliphatic monocarboxylic acids having at least 2 carbon atoms and (b) 80-20 mol % of monoethylenically unsaturated carboxylic acids, with or without (c) 0-30 mol % of other copolymerizable monoethylenically unsaturated monomers and/or (d) 0-10 mol % of monomers which contain at least two non-conjugated ethylenic double bonds in the molecule, in the presence of at least one sulfur, phosphorus and/or nitrogen compound with a reducing action and of 0.05-30% by weight, based on the monomers, of at least one surface-active agent in aqueous medium in the presence of initiators and in the presence or absence of regulators, and the use of the copolymers or of the copolymers which are obtainable therefrom by hydrolysis and/or oxidation and have vinyl alcohol units as additive to detergents and cleaners.

    Aqueous solutions or dispersions of copolymers

    公开(公告)号:AU1534295A

    公开(公告)日:1995-08-08

    申请号:AU1534295

    申请日:1995-01-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00144 Sec. 371 Date Jul. 25, 1996 Sec. 102(e) Date Jul. 25, 1996 PCT Filed Jan. 16, 1995 PCT Pub. No. WO95/20056 PCT Pub. Date Jul. 27, 1995Aqueous solution or aqueous dispersion of copolymers suitable for the fatliquoring and filling of leather and fur skins are obtained by free-radical copolymerization of A1) C6-C40-monoolefins or C6-C40-alkyl vinyl ethers or mixtures thereof with B1) monoethylenically unsaturated C4-C8-dicarboxylic anhydrides or by free-radical copolymerization of A2) C6-C40-alkyl acrylates or methacrylates or vinyl esters of C6-C40-carboxylic acids or mixtures thereof with B2) monoethylenically unsaturated C3-C12-carboxylic acids, monoethylenically unsaturated C4-C12-dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C4-C12-dicarboxylic acids, amides of monoethylenically unsaturated C3-C12-carboxylic acids or mixtures thereof to give copolymers with molecular weights of 500 to 30,000, where the carboxyl groups which are present in aqueous medium are at least partially neutralized, and some of the carboxylic groups can be in amidated form, containing 0.5-40% by weight, based on the amount of copolymer, of defined emulsifiers.

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