3.
    发明专利
    未知

    公开(公告)号:AT172238T

    公开(公告)日:1998-10-15

    申请号:AT95902787

    申请日:1994-12-06

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/04057 Sec. 371 Date May 20, 1996 Sec. 102(e) Date May 20, 1996 PCT Filed Dec. 6, 1994 PCT Pub. No. WO95/16020 PCT Pub. Date Jun. 15, 1995The use of polyaspartic acid prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:0.05 to 1:10 at temperatures of at least 120 DEG C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, as additive to detergents and cleaners in amounts of from 0.1 to 10% by weight, and detergents and cleaners which contain polyaspartic acids prepared in the presence of phosphoric acid.

    4.
    发明专利
    未知

    公开(公告)号:DE59500859D1

    公开(公告)日:1997-11-27

    申请号:DE59500859

    申请日:1995-02-17

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00575 Sec. 371 Date Aug. 21, 1996 Sec. 102(e) Date Aug. 21, 1996 PCT Filed Feb. 17, 1995 PCT Pub. No. WO95/22569 PCT Pub. Date Aug. 24, 1995A process for preparing copolymers of vinyl esters and monoethylenically unsaturated carboxylic acids by free-radical copolymerization of (a) 20 to 80 mol % of vinyl esters of aliphatic monocarboxylic acids having at least 2 carbon atoms and (b) 80-20 mol % of monoethylenically unsaturated carboxylic acids, with or without (c) 0-30 mol % of other copolymerizable monoethylenically unsaturated monomers and/or (d) 0-10 mol % of monomers which contain at least two non-conjugated ethylenic double bonds in the molecule, in the presence of at least one sulfur, phosphorus and/or nitrogen compound with a reducing action and of 0.05-30% by weight, based on the monomers, of at least one surface-active agent in aqueous medium in the presence of initiators and in the presence or absence of regulators, and the use of the copolymers or of the copolymers which are obtainable therefrom by hydrolysis and/or oxidation and have vinyl alcohol units as additive to detergents and cleaners.

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