52.
    发明专利
    未知

    公开(公告)号:ES2101517T3

    公开(公告)日:1997-07-01

    申请号:ES94909115

    申请日:1994-03-05

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/00660 Sec. 371 Date Sep. 13, 1995 Sec. 102(e) Date Sep. 13, 1995 PCT Filed Mar. 5, 1994 PCT Pub. No. WO94/21695 PCT Pub. Date Sep. 29, 1994Polycocondensates based on aspartic acid which are obtainable by condensing aspartic acid in the presence of polymers containing carboxyl groups, which contain at least 10 mol % of a monoethylenically unsaturated carboxylic acid in copolymerized form and have a molecular weight of at least 300, in the weight ratio from 1,000:1 to 2:1, processes for preparing the polycocondensates and use of the polycocondensates in the form of the free acid groups or in a form neutralized with ammonia, amines, alkali metal or alkaline earth metal bases as an additive to detergents and cleaners, as scale inhibitors or as dispersants for finely divided solids are described.

    53.
    发明专利
    未知

    公开(公告)号:AT153347T

    公开(公告)日:1997-06-15

    申请号:AT94909115

    申请日:1994-03-05

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP94/00660 Sec. 371 Date Sep. 13, 1995 Sec. 102(e) Date Sep. 13, 1995 PCT Filed Mar. 5, 1994 PCT Pub. No. WO94/21695 PCT Pub. Date Sep. 29, 1994Polycocondensates based on aspartic acid which are obtainable by condensing aspartic acid in the presence of polymers containing carboxyl groups, which contain at least 10 mol % of a monoethylenically unsaturated carboxylic acid in copolymerized form and have a molecular weight of at least 300, in the weight ratio from 1,000:1 to 2:1, processes for preparing the polycocondensates and use of the polycocondensates in the form of the free acid groups or in a form neutralized with ammonia, amines, alkali metal or alkaline earth metal bases as an additive to detergents and cleaners, as scale inhibitors or as dispersants for finely divided solids are described.

    55.
    发明专利
    未知

    公开(公告)号:DE59305089D1

    公开(公告)日:1997-02-20

    申请号:DE59305089

    申请日:1993-08-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP93/02176 Sec. 371 Date Feb. 2, 1995 Sec. 102(e) Date Feb. 2, 1995 PCT Filed Aug. 16, 1993 PCT Pub. No. WO94/04585 PCT Pub. Date Mar. 3, 1994.A process for preparing polyacetals by copolymerization of glyoxylic esters with other copolymerizable monomers in the presence of anionic or cationic polymerization initiators, with or without the introduction of stable end groups and with or without hydrolysis of the copolymerized units of glyoxylic ester present in the copolymer comprises using as monomers cyclic formals derived from diols, homopolymers of formaldehyde, trioxepane or mixtures thereof, although up to 50% by weight of this group of monomers may be replaced by other customary copolymerizable monomers, and the poly(acetal-carboxylate)s thus obtainable are useful as additives in reduced-phosphate and phosphate-free detergents and cleaners, as water treatment agents and as dispersants for finely divided substances.

    COPOLYMERS CONTAINING VINYL FORMATE UNITS, METHOD OF PRODUCING THEM AND THEIR USE IN WASHING AND CLEANING AGENTS

    公开(公告)号:CA2193126A1

    公开(公告)日:1995-12-21

    申请号:CA2193126

    申请日:1995-05-31

    Applicant: BASF AG

    Abstract: Vinyl formate copolymers, preparation thereof, and use thereof in detergents and cleaners Copolymers containing (a) from 5 to 90 mol% of vinyl formate units, (b) from 10 to 95 mol% of units of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol% of units of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol% of units of other monoethylenically unsaturated monomers in copolymerized form and having K values of at least 8 (determined by the method of H. Fikentscher in 1% strength by weight aqueous solution on the sodium salt of the copolymers at pH 7 and 25 C), processes for their preparation by copolymerizing monomer mixtures of (a) from 5 to 90 mol% of vinyl formate, (b) from 10 to 95 mol% of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol% of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol% of other monoethylenically unsaturated monomers in an aqueous medium or in an organic solvent in the presence of free-radical polymerization initiators and use of the vinyl formate copolymers and of the vinyl alcohol copolymers obtainable therefrom by hydrolysis and/or oxidation as detergent and cleaner additives.

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