公开(公告)号：EA005202B1

公开(公告)日：2004-12-30

申请号：EA200300221

申请日：2001-08-16

Applicant: BASF AG

Inventor： ISAK HEINZ ,  SENDHOFF NORBERT ,  SCHUTZ FRANZ ,  THERRE JORG ,  DROGEMULLER MICHAEL ,  FRANKE DIRK ,  MUNZINGER MANFRED ,  WECK ALEXANDER ,  BURKART KIRSTEN

IPC: A01N25/12 ,  A01N43/88 ,  C07D285/34

Abstract: Визобретенииописываетсяспособполученияпорошковойкомпозициитетрагидро-3,5-диметил-1,3,5-тиадиазин-2-тиона, осуществляемыйпутемобъединениядвухводныхрастворов, одинизкоторыхсодержит N-метилдитиокарбаматметиламмония, адругойсодержитформальдегид, споследующимвыделениемобразовавшегосятвердогопродуктаи егосушкой. Такойспособотличаетсятем, чтопервыйи второйводныерастворыобъединяюттакимобразом, чтобысоотношениеконцентрацийфункциональныхгруппдитиокарбаматаи формальдегидав реакционнойсмесинапротяжениивсейреакцииоставалосьпрактическипостоянным.

公开(公告)号：HU0401278A2

公开(公告)日：2004-12-28

申请号：HU0401278

申请日：2002-08-29

Applicant: BASF AG

Inventor： KLOPP INGO ,  BOGENSTAETTER THOMAS ,  FRANKE DIRK ,  MUNZINGER MANFRED

IPC: B01J8/08 ,  B01J8/00 ,  B01J8/06 ,  B01J8/20 ,  B01J19/00 ,  B01J19/24 ,  C07F9/141 ,  C07F9/38 ,  C07F9/40

Abstract: A process for carrying out a liquid/solid reaction comprises a) preparing a reaction suspension in which a first reactant is present in suspended form and a second reactant is present in dissolved form in a suspension medium, where one of the reaction products is insoluble in the suspension medium, b) passing the reaction suspension through an elongated reaction zone so that the Reynolds number of the stream is less than 20,000 and c) separating off the insoluble reaction product formed. The process has the advantage that the insoluble reaction product is obtained in a readily filterable form.

公开(公告)号：DE50101522D1

公开(公告)日：2004-03-25

申请号：DE50101522

申请日：2001-08-16

Applicant: BASF AG

Inventor： ISAK HEINZ ,  SENDHOFF NORBERT ,  SCHUETZ FRANZ ,  THERRE JOERG ,  DROEGEMUELLER MICHAEL ,  FRANKE DIRK ,  MUNZINGER MANFRED ,  WECK ALEXANDER ,  BURKART KIRSTEN

IPC: A01N25/12 ,  A01N43/88 ,  C07D285/34

Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.

公开(公告)号：ZA200302068B

公开(公告)日：2004-03-15

申请号：ZA200302068

申请日：2003-03-14

Applicant: BASF AG

Inventor： BURKART KIRSTEN ,  DROEGEMUELLER MICHAEL ,  FRANKE DIRK ,  ISAK HEINZ ,  MUNZINGER MANFRED ,  SCHUETZ FRANZ ,  SENDHOFF NORBERT ,  THERRE JOERG ,  WECK ALEXANDER

IPC: A01N25/12 ,  A01N43/88 ,  C07D285/34 ,  C07D ,  A01N

Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.

公开(公告)号：HU0300766A2

公开(公告)日：2003-09-29

申请号：HU0300766

申请日：2001-08-16

Applicant: BASF AG

Inventor： BURKART KIRSTEN ,  DROEGEMUELLER MICHAEL ,  FRANKE DIRK ,  ISAK HEINZ ,  MUNZINGER MANFRED ,  SCHUETZ FRANZ ,  SENDHOFF NORBERT ,  THERRE JOERG ,  WECK ALEXANDER

IPC: A01N25/12 ,  A01N43/88 ,  C07D285/34

Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.

公开(公告)号：SK1922003A3

公开(公告)日：2003-08-05

申请号：SK1922003

申请日：2001-08-16

Applicant: BASF AG

Inventor： ISAK HEINZ ,  SENDHOFF NORBERT ,  SCHUTZ FRANZ ,  THERRE JORG ,  DROGEMULLER MICHAEL ,  FRANKE DIRK ,  MUNZINGER MANFRED ,  WECK ALEXANDER ,  BURKART KIRSTEN

IPC: A01N25/12 ,  A01N43/88 ,  C07D285/34

Abstract: Described is a process for the preparation of a particulate tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione product by combining a first aqueous solution comprising methylammonium N-methyldithiocarbamate with a second aqueous solution comprising formaldehyde, followed by separation and drying of the resulting solid, which comprises combining the first and the second aqueous solutions in such a way that the ratio between the concentrations of dithiocarbamate functions and of formaldehyde is essentially constant in the reaction mixture over time during the duration of the reaction.

公开(公告)号：CA2458812A1

公开(公告)日：2003-03-13

申请号：CA2458812

申请日：2002-08-29

Applicant: BASF AG

Inventor： FRANKE DIRK ,  MUNZINGER MANFRED ,  BOGENSTAETTER THOMAS ,  KLOPP INGO

IPC: B01J8/08 ,  B01J8/00 ,  B01J8/06 ,  B01J8/20 ,  B01J19/00 ,  B01J19/24 ,  C07F9/141 ,  C07F9/38 ,  C07F9/40

Abstract: The invention relates to a method for carrying out a solid-liquid reaction, according to which a) a reaction suspension is prepared, containing a first reactant which is suspended in a suspension medium and a second reactant whi ch is dissolved in the same, one of the reaction products being insoluble in th e suspension medium, b) the reaction suspension is guided through a longish reaction zone, the Reynolds number of the flow being less than 20,000, and c ) the insoluble reaction product formed is separated. The method is advantageo us in that the insoluble reaction product is obtained in a form which is easy t o filter.

公开(公告)号：CA2418972A1

公开(公告)日：2003-02-11

申请号：CA2418972

申请日：2001-08-16

Applicant: BASF AG

Inventor： BURKART KIRSTEN ,  WECK ALEXANDER ,  ISAK HEINZ ,  SENDHOFF NORBERT ,  FRANKE DIRK ,  MUNZINGER MANFRED ,  THERRE JORG ,  DROGEMULLER MICHAEL ,  SCHUTZ FRANZ

IPC: A01N25/12 ,  A01N43/88 ,  C07D285/34

Abstract: A method for the production of a particle-containing preparation of tetrahyd ro- 3,5-dimethyl-1,3,5-thiadiazin-2-thione, by combination of a first aqueous solution containing methylammonium-N-methyldithiocarbamate with a second solution containing formaldehyde and separation and drying of the solid form ed is disclosed. The invention is characterised in that the first and second solutions are combined such that over the duration of the reaction the ratio of the concentration of dithiocarbamate functions and formaldehyde in the reaction mixture remains essentially constant over time.

公开(公告)号：CA2401602A1

公开(公告)日：2001-09-07

申请号：CA2401602

申请日：2001-02-20

Applicant: BASF AG

Inventor： STOSSER MICHAEL ,  FRANKE DIRK ,  GROSCH GEORG HEINRICH ,  HARRE KATHRIN ,  BAUM EVA ,  MUNZINGER MANFRED

IPC: C01C3/08 ,  B01J27/26 ,  C08G65/02 ,  C08G65/26

Abstract: The invention relates to a method for producing multimetal cyanide compounds by converting a metallic salt with a cyanometallate compound. The inventive method comprises the steps: a) precipitating the multimetal cyanide compound by converting a metallic salt with a cyanometallate compound and b) recrystallising the multimetal cyanide compound precipitated in step a).

公开(公告)号：PL335406A1

公开(公告)日：2000-04-25

申请号：PL33540698

申请日：1998-02-09

Applicant: BASF AG

Inventor： MERKLE HANS RUPERT ,  EVA RONALD R ,  FRANKE DIRK ,  JONES SIMON A ,  MATTMANN WOLFGANG ,  MUNZINGER MANFRED

IPC: C07C51/48 ,  C07C51/02 ,  C07C65/03 ,  C07C65/21 ,  C07C65/24

Abstract: PCT No. PCT/EP98/00705 Sec. 371 Date Jul. 28, 1999 Sec. 102(e) Date Jul. 28, 1999 PCT Filed Feb. 9, 1998 PCT Pub. No. WO98/37054 PCT Pub. Date Aug. 27, 1998A process for the isolation of 3-[2-chloro-4-(trifluoromethyl)phenoxy]benzoic acid of the formula I from an aqueous solution of its metal salt comprises a) reacting the metal salt of 3-[2-chloro-4-(trifluoromethyl)phenoxy]benzoic acid with an organic or inorganic acid; b) heating the reaction mixture until a liquid two-phase system of organic and aqueous phase has formed; and c) separating the organic phase from the aqueous phase.