54.
    发明专利
    未知

    公开(公告)号:DE19614859A1

    公开(公告)日:1997-10-23

    申请号:DE19614859

    申请日:1996-04-16

    Applicant: BASF AG

    Abstract: 4-benzoylisothiazoles have general formula (1), in which the substituents have the following meanings: X stands for oxygen or sulphur; R stands for hydrogen, alkyl, alkenyl, alkinyl, or for optionally substituted alkoxycarbonyl, aryl, heterocyclyl or hetaryl; R stands for hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkenyl, whereas these radicals may bear one or several halogen, alkyl, alkenyl or alkinyl groups, or R stands for aryl, hetaryl or heterocyclyl; and R stands for alkyl, cycloalkyl or a radical of general formula (2), in which the substituents have the meanings indicated in claim 1. Also disclosed are the salts commonly used in agriculture of the 4-benzoylisothiazoles of general formula (1), a process for preparing the same and their use as herbicides.

    56.
    发明专利
    未知

    公开(公告)号:ES2046538T3

    公开(公告)日:1995-04-01

    申请号:ES90100662

    申请日:1990-01-13

    Applicant: BASF AG

    Abstract: Ia Ib where R1 is hydrogen or fluorine, R2 is halogen, R3 is hydrogen, halogen or a C1-C4-alkyl, R4, R5 are hydrogen, C1-C8-alkyl, C2-C4-alkyl which carries a hydroxyl, C1-C4-alkoxy or C1-C4-alkylthio radical, C1-C6-alkoxy, C3-C6-alkenyl, C3-C6-alkynyl, C3-C6-alkenyloxy and/or C3-C6-alkynyloxy, or together with the nitorgen atom form a 5- or 6-membered aliphatic ring in which a methylene group may be replaced by an oxygen atom, and R6 is hydrogen, C1-C6-alkyl which is unsubstituted or substituted by one or two C1-C4-alkoxy groups, or is C3-C6-alkenyl, C3-C6-alkynyl or benzyl, processes for their manufacture, and their herbicidal use.

    57.
    发明专利
    未知

    公开(公告)号:DE58907484D1

    公开(公告)日:1994-05-26

    申请号:DE58907484

    申请日:1989-06-10

    Applicant: BASF AG

    Abstract: Salicylic acid derivatives and their sulphur analogues of the formula I … … in which the substituents have the following meaning: R is hydrogen, succinyliminooxy; substituted C1-C10-alkoxy; optionally substituted 5-membered heteroaryl; a radical -OR in which R denotes hydrogen; optionally substituted C1-C10-alkyl, C3-C6-alkenyl or C3-C6-alkynyl; or a radical ON=CR R in which R and R denote optionally substituted C1-C20-alkyl, phenyl or, together, optionally substituted C3-C12-alkylene; R and R are C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and/or C1-C4-alkylthio; X is an oxygen or sulphur Y and Z are nitrogen or =CH-; R is halogen, optionally substituted C1-C4-alkyl, C1-C4-alkoxy; C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl or C3-C6-alkynyloxy; C1-C4-alkylamino, C2-C8-dialkylamino, arylamino or N-C1-C4-alkyl-N- arylamino; R is hydrogen or one of the radicals R , with the proviso that R denotes C1-C4-haloalkyl or X denotes sulphur or Y denotes =CH- or R denotes optionally substituted C3-C6-alkenyl or C3-C6-haloalkenyloxy if R stands for hydrogen or -OR , and their environmentally tolerable salts, their use as herbicides, and growth-regulating salicylic acid derivatives of the general formula Ia … … in which the substituents have the following meaning: R is hydrogen, succinyliminooxy; substituted C1-C10-alkoxy; optionally substituted 5-membered heteroaryl; a radical -OR in which R denotes hydrogen; optionally substituted C1-C10-alkyl, C3-C6-alkenyl or C3-C6-alkynyl; or a radical ON=CR R in which R and R denote optionally substituted C1-C20-alkyl, phenyl or, together, optionally substituted C3-C12-alkylene; R and R are C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and/or C1-C4-alkylthio; X is oxygen; Y is nitrogen; Z is nitrogen or =CH-; R is halogen, optionally substituted C1-C4-alkyl, C1-C4-alkoxy; C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl or C3-C6-alkynyloxyl; C1-C4-alkylamino, C2-C8-dialkylamino, arylamino or N-C1-C4-alkyl-N- arylamino; n is 0, 1 or 2.

    New cyclohexene-di:carboxylic acid di:amide derivs. - used as selective herbicides, plant growth regulators, desiccants and defoliants

    公开(公告)号:DE4213715A1

    公开(公告)日:1993-10-28

    申请号:DE4213715

    申请日:1992-04-25

    Applicant: BASF AG

    Abstract: N-(Substd. phenyl)-cyclohexene -1,2-dicarboxylic acid diamide derivs. of formula (I) and their salts are new. In (I), R1, R2 = (i) H; (ii) alkyl, alkenyl or alkynyl all opt. substd. (iii) 3-8C cycloalkyl; or (iv) phenyl or heterocyclyl (contg. 1-4 heteroatoms selected from 1-4N, 1 or 2 O and 1 or 2 S), both opt. C-substd. by one or more of OH, halogen, CN, NO2, CF3, halogen and alkyl; if R1 = H or alkyl, then additionally: R2 = (v) OH, alkoxy, alkenyloxy, alkynyloxy, 3-7C cycloalkoxy, 5-7C cycloalkenyloxy, haloalkoxy, haloalkenyloxy, (3-7C) cycloalkyl-alkoxy, alkoxycarbonyl, cyanoalkoxy, hydroxyalkoxy, alkoxyalkoxy, alkoxycarbonylalkoxy, alkylthioalkoxy or mono- or dialkylamino-alkoxy; (vi) phenylalkoxy, phenylalkenyloxy or phenylalkynyloxy (in which 1 or 2 CH2 gps. of the aliphatic chain are opt. replaced by O, S and/or N (alkyl) and phenyl rings are opt. substd. by 1-3 of alkyl, 2-6C alkenyl, halogen, CN, NO2, haloalkyl alkoxy and alkoxycarbonyl), or (vii) NR7R8; or NR1R2 = non-aromatic heterocycle which can contain 1-3 N and/or one O or S and 1 or 2 CO gps. and is opt. mono-, di- or tri-alkyl substd.; R7, R8 = H, alkyl, alkenyl, alkynyl, 3-6C cycloalkyl, haloalkyl, alkylcarbonyl, alkoxycarbonyl, alkoxyalkyl or phenyl, opt. substd.; or NR7R8 = 4-7 membered heterocycle opt. contg. a further N, 0 or S heteroatom; R3 = H or alkyl; R4 = H or halogen; R5 = H, halogen, NO2, CN or CF3; R6 = e.g. heterocyclyl (contg. 1-4 heteroatoms selected from 1-4N, 1-2 O and 1-2 S, opt. with 1 or 2 CH2 gps. replaced by CO), opt. C-substd. etc. or R5 + R6 = satd. or partially or completely unsatd. 3-5 membered hydrocarbon chain (opt. contg. 1 or 2 O, S or N and/or one CO or alkoxyimino as chain member; and opt. substd. by 1 or 2 of CN, NO2, NH2, halogen, alkyl, haloalkyl, 2-6C alkenyl, 2-6C alkynyl, cyanoalkyl, alkoxycarbonylalkyl, phenylalkyl and heterocyclyl-alkyl (where heterocyclyl contains 1-4 heteroatoms selected from 1-4N, 1-2 O and 1-2 S)); unless otherwise specified, all alkyl moieties contain 1-6C, and alkenyl and alkynyl moieties 3-6C; and heterocycles are satd. or partially or completely unsatd. and have 3-8 members. Also claimed are certain new 3,4,5,6-tetrahydrophthalimide, 3,4,5,6-tetrahydro-phthalisoimide and tetrahydrophthalamic acid deriv. intermediates. USE/ADVANTAGE - (I) are herbicides (claimed), plant growth regulators, defoliants (claimed) and desiccants (claimed); the new intermediates have the same activities. As herbicides, the cpds. are esp. useful for combatting dicotyledonous weeds and are useful as selective herbicides in wheat, rice, maize, soya and cotton. (I) have good herbicidal activity and higher selectivity (better culture plant compatibility) than related known cpds. The cpds. are useful as desiccants/defoliant for defoliation of cotton or desiccating the ground parts of potatoes, sunflowers, soybeans and rape to facilitate mechanical harvesting. They also promote abscission of citrus fruits, olives and other fruits. The cpds. are applied pre- or post-emergence at 0.001-3 (pref. 0.01-1) kg/ha, or to seeds.

    59.
    发明专利
    未知

    公开(公告)号:DE59000510D1

    公开(公告)日:1993-01-14

    申请号:DE59000510

    申请日:1990-01-13

    Applicant: BASF AG

    Abstract: Ia Ib where R1 is hydrogen or fluorine, R2 is halogen, R3 is hydrogen, halogen or a C1-C4-alkyl, R4, R5 are hydrogen, C1-C8-alkyl, C2-C4-alkyl which carries a hydroxyl, C1-C4-alkoxy or C1-C4-alkylthio radical, C1-C6-alkoxy, C3-C6-alkenyl, C3-C6-alkynyl, C3-C6-alkenyloxy and/or C3-C6-alkynyloxy, or together with the nitorgen atom form a 5- or 6-membered aliphatic ring in which a methylene group may be replaced by an oxygen atom, and R6 is hydrogen, C1-C6-alkyl which is unsubstituted or substituted by one or two C1-C4-alkoxy groups, or is C3-C6-alkenyl, C3-C6-alkynyl or benzyl, processes for their manufacture, and their herbicidal use.

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